Cathode current collector material for solid cathode cell

• US 5,114,810 A
• Filed: 02/05/1990
• Issued: 05/19/1992
• Est. Priority Date: 02/05/1990
• Status: Expired due to Term

• Current Assignee: Greatbatch Limited (Greatbatch Incorporated)
• Original Assignee: Wilson Greatbatch Technologies, Inc.
• Inventors: Frysz, Christine A., Brown, W. Richard
• Primary Examiner(s): Hearn, Brian E.
• Assistant Examiner(s): Nuzzolillo, Maria
• Application Number:
  US07/475,261
• Time in Patent Office: 834 Days
• Field of Search: 429/194, 429/245
• US Class Current: 429/219
• CPC Class Codes: C22C 38/44 with molybdenum or tungsten
• CPC Class Codes: H01M 4/669 Steels
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A highly alloyed nickel-containing ferritic stainless steel material for use as a cathode current collector for lithium solid cathode cells is provided. The material does not require costly melting practices and provides high corrosion resistance particularly where elevated temperature, 72° C. or higher, storage and performance is required relative to other cathode current collector materials thereby increasing cell longevity.

Claims

1. In an electrochemical cell comprising a lithium anode, a solid cathode material used in conjunction with a metal cathode current collector, and an ionically conductive electrolyte solution operatively associated with said anode and cathode, wherein the improvement comprises a cathode current collector of a highly alloyed nickel-containing ferritic stainless steel material, said material providing high corrosion resistance particularly where elevated temperature storage and performance is required thereby increasing cell longevity, said material comprising, by weight:

from about 27.0 percent to about 29.0 percent chromium;

from about 2.0 percent to about 3.0 percent molybdenum;

from about 3.0 percent to about 4.5 percent nickel;

the sum of carbon plus nitrogen in an amount less than or equal to 0.045 percent;

the sum of niobium plus zirconium in an amount of at least ten times the percent of carbon plus nitrogen; and

the remainder being iron.

2. The cell of claim 1, wherein said highly alloyed nickel-containing ferritic stainless steel material further comprises, by weight, small amounts of trace elements.

3. The cell of claim 2, wherein said trace elements are selected from the group consisting of copper, magnesium, phosphorous, sulfur and silicon.

7. The cell of claim 1, wherein said solid cathode material is selected from the group consisting of metal oxide bronze, fluorinated carbon and metal oxide.

8. The cell of claim 7, wherein said metal oxide bronze is silver vanadium oxide.

9. The cell of claim 7, wherein said fluorinated carbon is polycarbon monofluoride (CF_x) wherein x ranges from about 0.5 to about 1.2.

10. The cell of claim 1, wherein said cathode current collector material is in the form of a sheet.

11. The cell of claim 1, wherein said cathode current collector material is in the form of a screen.

4. In an electrochemical cell comprising a lithium anode, a solid cathode material used in conjunction with a metal cathode current collector, and an ionically conductive electrolyte solution operatively associated with said anode and cathode, wherein the improvement comprises a cathode current collector of a highly alloyed nickel-containing ferritic stainless steel material, said material providing high corrosion resistance particularly where elevated temperature storage and performance is required thereby increasing cell longevity, said material comprising, by weight:

from about 28.0 percent to about 30.0 percent chromium;

from about 3.5 percent to about 4.2 percent molybdenum;

from about 2.0 percent to about 2.5 percent nickel;

the sum of carbon plus nitrogen in an amount less than or equal to 0.025 percent; and

the remainder being iron.

5. The cell of claim 4, wherein said highly alloyed nickel-containing ferritic stainless steel material further comprises, by weight, small amounts of trace elements.

6. The cell of claim 5, wherein said trace elements are selected from the group consisting of copper, magnesium, phosphorous, sulfur and silicon.