Phosphorescent marking material

• US 5,116,533 A
• Filed: 06/11/1991
• Issued: 05/26/1992
• Est. Priority Date: 04/05/1990
• Status: Expired due to Term

• Current Assignee: Playstation, Inc. (Sony Group Corp.)
• Original Assignee: Playstation, Inc. (Sony Group Corp.)
• Inventors: Rendino, Paula, Grandmont, William
• Primary Examiner(s): Willis, Jr., Prince
• Assistant Examiner(s): Johnson, Jerry D.
• Application Number:
  US07/713,622
• Time in Patent Office: 350 Days
• Field of Search: 252/301.36, 106/19, 401/49
• US Class Current: 252/301.36
• CPC Class Codes: B43K 19/00 Non-propelling pencils; Styles; Crayons; Chalks batik pencils, cord-line chalkers B44D3/00; writing-core compositions for pencils, crayon compositions, chalk compositions C09D13/00
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/025 non-luminescent particle coatings or suspension media
• CPC Class Codes: C09K 11/08 containing inorganic luminescent materials

Abstract

A non-toxic moldable phosphorescent marker has phosphorescent pigment particles that are suspended in a milled mixture of an inert filler and a wax blend base. The phosphorescent pigment particles, which impart luminescent properties to the marker, are excited by light. The composition of the marker is such that it leaves a strip of phosphorescent marking material on a surface against which the marker is rubbed. The deposited material contains the suspended phosphorescent particles, which luminesces when excited by light.

Claims

1. A phosphorescent marking material comprising a wax base vehicle, filler particles, and phosphorescent particles, said phosphorescent particles being suspended in a mixture of said wax base vehicle and said filler particles, said mixture comprising a range of 10 percent to 30 percent by weight of said filler particles and a range of 10 to 50 percent by weight of said phosphorescent particles, said phosphorescent particles having a particle size in the size range of 5 to 20 microns, said filler particles being at least partially transparent to actimic radiation.

2. The marking material as claimed in claim 1 wherein said phosphorescent particles by percent of total weight is in the range of 20% to 50%.

3. A method of suspending pigment particles in a wax medium to allow molding and extrusion, said method comprising the steps of:

(a) preparing a blend of waxes;

(b) melting said wax blend;

(c) mixing an inert filler material with said wax blend to form a wax/filler mixture;

(d) milling said wax/filler mixture to form a uniform suspension to said inert filler material in said wax blend;

(e) mixing pigment particles having a particle size in the size range of 5 to 20 microns into said milled wax/filler mixture to form a final blend, said final blend being a continuous, non-settling suspension of said pigment particles in said mixture of said filler material and said wax blend and having in the range of 10 percent to 30 percent by weight of said filler particles and a range of 10 to 50 percent by weight of said pigment particles; and

(f) whipping said final blend.

4. The method as claimed in claim 3 wherein said wax/filler mixture is milled in a colloid mill.

5. The method as claimed in claim 3 wherein the quantity of said inert filler by total weight is in the range of 13% to 20%.

6. The method as claimed in claim 3 wherein said inert filler material is inert filler particles having a particle size in the range of 8 to 10 microns.

7. The method as claimed in claim 3 wherein said filler material is at least partially transparent to actinic radiation.

8. The method of claim 3 wherein said pigment particles comprise phosphorescent particles.

9. The method of claim 8 wherein the percent by weight of said phosphorescent particles is in the range of 20% to 50%.

10. The method as claimed in claim 9 wherein the quantity of said phosphorescent particles by total weight is in the range of 25% to 35%.

11. A method of making a phosphorescent marker having a wax blend base comprising the steps of:

(a) melting a wax blend;

(b) adding a filler material to the melted wax blend;

(c) milling said filler material and melted wax blend to form a uniform suspension of said filler material in said wax blend;

(d) adding phosphorescent pigment particles in the size range of 5 to 20 microns to said milled filler and melted wax blend;

(e) whipping said phosphorescent pigment particles and milled filler and melted wax blend to form a continuous, non-settling suspension of said phosphorescent pigment particles in said milled filler material and melted wax blend, said suspension having in the range of 10 to 30 percent by weight filler material and in the range of 10 to 50 percent by weight of said pigment particles; and

(f) forming said whipped phosphorescent pigment particles and milled filler and melted wax blend into a desired shape.

12. A phosphorescent marker comprising a whipped mixture of an inert milled filler and wax base blend, and phosphorescent particles, said filler being at least partially transparent to actinic radiation, said phosphorescent particles being in the size range of 5 to 20 microns and continuously suspended in said whipped mixture, said whipped mixture comprising between 10 and 30 percent by weight of said filler and between 10 and 50 percent by weight said phosphorescent particles.

13. The phosphorescent marker as claimed in claim 12 wherein the percent by total weight of said phosphorescent particles is in the range of 205 to 50%.

14. The phosphorescent marker as claimed in claim 13 wherein said filler and wax blend includes an inert filler having particles in the size range of 8 to 10 microns.