Process for modifying clinoptilolite adsorbent

• US 5,116,793 A
• Filed: 04/24/1991
• Issued: 05/26/1992
• Est. Priority Date: 06/14/1988
• Status: Expired due to Term

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Rastelli, Henry, Chao, Chien C.
• Primary Examiner(s): DEES, CARL
• Application Number:
  US07/690,238
• Time in Patent Office: 398 Days
• Field of Search: 502/60, 502/74, 502/68
• US Class Current: 502/68
• CPC Class Codes: B01J 20/186 Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
• CPC Class Codes: C07C 7/13 by molecular-sieve technique

Abstract

Clinoptilolites, including both natural and synthetic clinoptilolites which have been ion-exchanged with metal cations such as lithium, sodium, potassium, calcium, magnesium, barium, strontiun, zinc, copper, cobalt, iron and manganese, are useful for the removal of traces of ammonia from streams of hydrocarbons having kinetic diameters of not more than about 5 Å. This invention relates to the process of producing the modified clinoptilolite adsorbent.

Claims

1. A process for the production of a modified clinoptilolite from natural or synthetic clinoptilolite wherein at least about 40% of the ion-exchangeable cations in the clinoptilolite comprise any one or more of lithium, potassium, calcium, magnesium, barium, strontium, zinc, copper, cobalt, iron and manganese cations, said process comprising subjecting a clinoptilolite to ion-exchange with a solution containing sodium cations until at least about 40% of the ion-exchangeable non-sodium cations in the clinoptilolite have been replaced by sodium cations, thereby producing a sodium clinoptilolite, and thereafter subjecting said sodium clinoptilolite to ion-exchange with a solution containing any one or more of lithium, potassium, calcium, magnesium, barium, strontium, zinc, copper, cobalt, iron and manganese cations.

2. A process according to claim 1 wherein, after the sodium ion-exchange but before the second ion-exchange, the sodium clinoptilolite is admixed with a binder and heated to produce pellets of clinoptilolite bound together by the binder, and the second ion-exchange is effected on the pellets so formed.

3. A process according to claim 2 wherein the binder is a clay binder.

4. A process according to claim 1 wherein the ion-exchange is continued until at least about 60% of the total cations in the clinoptilolite are replaced by sodium cations.