Sodium ion sensor

• US 5,120,422 A
• Filed: 03/01/1991
• Issued: 06/09/1992
• Est. Priority Date: 03/01/1991
• Status: Expired due to Fees

• Current Assignee: Ceramatec, Inc.
• Original Assignee: Ceramatec, Inc.
• Inventors: Joshi, Ashok V., Liu, Meilin
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): Bell, Bruce F.
• Application Number:
  US07/663,423
• Time in Patent Office: 466 Days
• Field of Search: 204/421, 204/422, 204/424, 204/414, 204/415, 204/418, 204/419, 204/416, 204/153.15
• US Class Current: 204/416
• CPC Class Codes: G01N 27/333 Ion-selective electrodes or membranes glass electrodes G01N27/36

Abstract

A sodium ion sensor having a composite electrolyte is disclosed. The sodium ion sensor has an outer electrolyte which is insensitive to water and has a high transport activity for sodium ions and an inner electrolyte which is a thin membrane having a very high sodium ion selectivity. The sodium ion sensor having such an electrolyte is sensitive only to the transport of sodium ions and may be operated in aqueous solutions without buffering and in the presence of other alkali ions and alkaline earth metal ions. Sensors of this type operate in EMF mode to give a substantially instantaneous determination of the sodium ion concentration of the aqueous medium being analyzed. The sensor may be used as an on-line sensor directly exposed to the medium to be analyzed.

Claims

1. A sodium ion sensor for selectively sensing sodium ions in the presence of other ions and varying pH conditions comprising:

an inner electrode;

a standard sodium ion material of a known sodium ion concentration, said standard material being in intimate contact with said inner electrode;

solid electrolyte comprising;

a first outer membrane adapted to contact a sodium ion solution to be analyzed, said outer membrane being insoluble in said sodium ion solution to be analyzed and being a sodium ion conductor, and

a second membrane in intimate contact with said standard sodium ion material and with said outer membrane and containing substantially only sodium ions as mobile, conductive ions;

a reference electrode in contact with said sodium ion solution to be analyzed and electrically connected through a voltmeter to said inner electrode, said voltmeter sized to detect the EMF generated across said composite electrolyte.

2. The sodium ion of claim 1 wherein said standard sodium ion material is a solid material selected from the class of metallic sodium and sodium-containing compounds.

3. The sodium ion sensor of claim 1 wherein said outer membrane is an impervious ceramic or glass containing a mobile sodium ion.

4. The sodium ion sensor of claim 1 wherein said inner membrane is a polymeric material containing sodium ions.

5. The sodium ion sensor of claim 4 wherein said polymeric material contains a sodium salt.

6. The sodium ion sensor of claim 4 wherein said inner membrane is physically bonded to said outer membrane.

7. The sodium ion sensor of claim 4 wherein said polymeric material is a high molecular weight polyethylene oxide.

8. The sodium ion sensor of claim 1 wherein said inner membrane is a sodium salt with high sodium ion selectivity.

9. The sodium ion sensor of claim 8 wherein said sodium salt is electronically conductive.

10. The sodium ion sensor of claim 3 wherein said ceramic is NASiCON, beta-alumina, or Nasiglass.

11. The sodium ion sensor of claim 10, wherein said ceramic is NASiCON.

13. The sodium ion sensor of claim 1 wherein said standard sodium ion material of a known sodium ion concentration is a sodium-containing compound.

14. The sodium ion sensor of claim 13 wherein said sodium-containing compound is a compound selected from the class consisting of sodium alloys, sodium metal, and sodium salts.

12. A sodium ion sensor selectively sensing sodium ions in the presence of other ions and under varying pH conditions, comprising:

a reference electrode/electrolyte system, said electrolyte containing a predetermined concentration of sodium ions; and

a dual solid electrolyte having an outer sodium-transporting membrane adapted to be in contact with the liquid to be analyzed, and an inner sodium ion-transporting electrolyte exposed to the interior surface of said outer membrane.

15. A cation sensor probe for use in a sensor determining the concentration in a liquid medium of a particular cation species, comprising:

an inner electrode;

a standard cation material of a known cation concentration of the cation species to be analyzed, said standard cation material being in intimate contact with said inner electrode;

a dual solid electrolyte having an outer membrane which contains mobile cations of the species to be detected, said outer membrane being inert to said liquid medium and an inner membrane in intimate contact with said standard cation material and with said outer membrane and a predetermined cation as substantially the only mobile, conductive cations in said inner membrane; and

an enclosure means for enclosing said inner electrode, standard cation material and dual electrolyte whereby only the outer surface of said outer membrane is exposed to said liquid medium.