Degradation resistant detergent compositions based on cellulase enzymes

• US 5,120,463 A
• Filed: 04/15/1991
• Issued: 06/09/1992
• Est. Priority Date: 10/19/1989
• Status: Expired due to Term

• Current Assignee: Genencor International Incorporated (International Flavors & Fragrances Incorporated)
• Original Assignee: Genencor International Incorporated (International Flavors & Fragrances Incorporated)
• Inventors: Bjork, Nancy S., Clarkson, Kathleen A., Weiss, Geoffrey L., Lad, Pushkaraj J.
• Primary Examiner(s): Willis, Jr., Prince
• Assistant Examiner(s): FRIES, KERY A
• Application Number:
  US07/686,265
• Time in Patent Office: 421 Days
• Field of Search: 252/174.12, 252/DIG. 12, 435/264
• US Class Current: 510/281
• CPC Class Codes: C11D 3/38645 containing cellulase

Abstract

Disclosed are detergent compositions containing a combination of exo-cellobiohydrolase I type cellulase components and endoglucanase components wherein the exo-cellobiohydrolase I type cellulase components are enriched relative to the endoglucanase components. The detergent compositions of this invention provide excellent cleaning of cotton garments while also providing substantially reduced degradation of the cotton fabric in the garment.

Claims

1. A detergent composition comprising at least one surface active agent and about 0.002 weight percent to about 10 weight percent relative to the total detergent composition of a cellulase composition wherein said cellulase composition contains a weight ratio of CBH I type cellulase components to EG components of about 10:

1 or more.

2. The detergent composition according to claim 1 wherein said detergent composition is substantially free of CBH II type cellulase components.

3. The detergent composition according to claim 2 wherein the weight ratio of said CBH I type cellulase components to said EG components is about 10:

1 or more.

4. The detergent composition according to claim 3 wherein the weight ratio of said CBH I type cellulase components to said EG components is about 40:

1 or more.

5. The detergent composition according to claim 1 wherein said composition is a liquid.

6. The detergent composition according to claim 1 wherein said composition is a powder.

7. The detergent composition according to claim 1 wherein said CBH I type cellulase components and said EG components are derived from a microorganism selected from the group consisting of Trichoderma reesei, Penicillum sp. and T. koningii.

8. The detergent composition according to claim 6 wherein said CBH I type cellulase components and said EG components are derived from Trichoderma reesei.

9. The detergent composition according to claim 7 wherein said CBH I type cellulase components and said EG components are derived from a Trichoderma reesei cellulase system having the following distribution of components:

space="preserve" listing-type="tabular">______________________________________ CBH I 45-55 weight percent CBH II 13-15 weight percent EG I 11-13 weight percent EG II 8-10 weight percent BG 0.5-1 weight percent ______________________________________

10. The detergent composition according to claim 1 wherein said composition is a laundry detergent composition.

11. The detergent composition according to claim 1 wherein said composition is a spot remover composition.

12. The detergent composition according to claim 1 wherein said composition is a presoak composition.

14. The method according to claim 12 wherein said CBH I type cellulase components are substantially free of CBH II type cellulase components.

16. The method according to claim 14 wherein the weight ratio of said CBH I type cellulase components to said EG components is about 40:

1 or more.

17. The method according to claim 12 wherein said detergent composition is a liquid.

18. The method according to claim 12 wherein said detergent composition is a powder.

19. The method according to claim 12 wherein said CBH I type cellulase components and said EG components are derived from a microorganism selected from the group consisting of Trichoderma reesei, Penicillum sp. and T. koningii.

20. The method according to claim 11 wherein said CBH I type cellulase components and said EG components are derived from Trichoderma reesei.

21. The method according to claim 18 wherein said CBH I type cellulase components and said EG components are derived from a Trichoderma reesei cellulase system having the following distribution of components:

space="preserve" listing-type="tabular">______________________________________ CBH I 45-55 weight percent CBH II 13-15 weight percent EG I 11-13 weight percent EG II 8-10 weight percent BG 0.5-1 weight percent ______________________________________

22. The method according to claim 12 wherein said detergent composition is a laundry detergent composition.

23. The method according to claim 12 wherein said detergent composition is a presoak detergent composition.

24. The method according to claim 12 wherein said detergent composition is a spot removing detergent composition.

13. A method for enhancing the degradation resistance to cotton fabric of a detergent composition containing cellulase which comprises:

(a) selecting a cellulase composition containing a weight ratio of CBH I type cellulase components to EG components of about 10;

1 or more; and

(b) adding said cellulase composition selected in (a) above to a detergent composition so as to form a degradation resistant detergent composition containing cellulase.

15. The method according to claim 13 wherein the weight ratio of said CBH I type cellulase components to said EG components is about 20:

1 or greater.