Fluid crystal device

• US 5,120,466 A
• Filed: 09/26/1988
• Issued: 06/09/1992
• Est. Priority Date: 07/13/1984
• Status: Expired due to Term

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Kanbe, Junichiro, Okada, Shinjiro, Katagiri, Kazuharu, Yoshinaga, Kazuo
• Primary Examiner(s): Stoll, Robert L.
• Assistant Examiner(s): WU, SHEAN CHIU
• Application Number:
  US07/251,028
• Time in Patent Office: 1,352 Days
• Field of Search: 350/350 S, 252/299.01, 252/299.4, 252/299.6, 359/56, 359/75, 359/76, 359/103, 359/104
• US Class Current: 252/299.01
• CPC Class Codes: C09K 19/0225 Ferroelectric
• CPC Class Codes: C09K 19/2021 Compounds containing at least one asymmetric carbon atom
• CPC Class Codes: C09K 19/50 containing steroidal liquid crystal compounds
• CPC Class Codes: G02F 1/1337 Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
• CPC Class Codes: G02F 1/133765 without a surface treatment
• CPC Class Codes: G02F 1/1341 Filling or closing of cells
• CPC Class Codes: G02F 1/141 using ferroelectric liquid crystals

Abstract

A liquid crystal device having a pair of base plates and a liquid crystal composition interposed between the pair of base plates. The liquid crystal composition contains a liquid crystal showing at least a chiral smectic phase and a liquid crystal showing at least a cholesteric phase. At least one of the pair of base plates has a face which has been provided with a function of preferentially orienting the axes of the liquid crystal molecules contacting the face in one direction.

Claims

1. A liquid crystal device comprising a pair of base plates and a ferroelectric chiral smectic liquid crystal composition interposed between the pair of base plates;

said ferroelectric chiral smectic liquid crystal composition exhibiting a phase transition through cholesteric phase and smectic A phase upon temperature decrease and comprising a first liquid crystal causing successive phase transition of isotropic phase, cholesteric phase, smectic A phase and chiral smectic phase on temperature decrease, and a second liquid crystal causing successive phase transition of isotropic phase, cholesteric phase and chiral smectic phase on temperature decrease in a proportion of 0.05 to 20 wt. parts of the total first liquid crystal content per 1 wt. part of the total second liquid crystal content;

said liquid crystal composition forming a grandjean texture in the cholesteric phase and being disposed in a layer thin enough to release the helical structure inherent to the chiral smectic phase in the absence of an electric field;

a face of each of said base plates being provided with an inorganic or organic insulating film having a rubbing or oblique vapor deposition uniaxial orientation treatment defining orientation axes, said orientation axes being parallel to each other.

2. The liquid crystal device according to claim 1, wherein said liquid crystal composition further contains 0.1-40 wt. % of a third liquid crystal causing successive phase transition of isotropic phase, smectic A phase and chiral smectic phase on temperature decrease.

3. The liquid crystal device according to claim 1, wherein said chiral smectic phase is C phase, H phase, F phase, I phase, K phase, J phase or G phase.

4. The liquid crystal device according to claim 1, wherein only one of the base plates is provided with the uniaxial orientation treatment.

5. The liquid crystal device according to claim 1, wherein the uniaxial orientation treatment is provided by rubbing the face of a base plate.

6. The liquid crystal device according to claim 1, wherein a film of an organic insulating material or an inorganic insulating material is formed on said face of a base plate.

7. The liquid crystal device according to claim 6, wherein said organic insulating material is at least one resin selected from the group consisting of polyvinyl alcohol, polyimide, polyamide-imide, polyester-imide, polyparaxylylene, polyester, polycarbonate, polyvinyl acetal, polyvinyl chloride, polyvinyl acetate, polyamide, polystyrene, cellulose resin, melamine resin, urea resin, acrylic resin and photoresist resins.

8. The liquid crystal device according to claim 6, wherein said inorganic insulating material is SiO, SiO₂, or TiO₂.

9. The liquid crystal device according to claim 1, wherein the uniaxial orientation treatment is provided by forming a film on the base plate by oblique vapor deposition of an inorganic insulating material.

10. The liquid crystal device according to claim 1, wherein said inorganic insulating material is SiO or SiO₂.

11. The liquid crystal device according to claim 1, wherein the uniaxial orientation treatment is provided by oblique etching of the face of a base plate.

12. The liquid crystal device according to claim 11, wherein a film of an organic or inorganic insulating material is formed on the face of the base plate and is subjected to oblique etching.

13. The liquid crystal device according to claim 12, wherein said organic insulating material is at least one resin selected from the group consisting of polyvinyl alcohol, polyamide, polyamide-imide, polyester-imide, polyparaxylylene, polyester, polycarbonate, polyvinyl acetal, polyvinyl chloride, polyvinyl acetate, polyamide, polystyrene, cellulose resin, melamine resin, urea resin, acrylic resin and photoresist resins.

14. The liquid crystal device according to claim 12, wherein said inorganic insulating material is glass, SiO, SiO₂ or TiO₂.

15. A liquid crystal device comprising a pair of base plates and a ferroelectric chiral smectic liquid crystal composition interposed between the pair of base plates;

said ferroelectric chiral smectic liquid crystal composition exhibiting a phase transition through cholesteric phase and smectic A phase upon temperature decrease and comprising a first liquid crystal showing at least chiral smectic phase and not cholesteric phase, and a second liquid crystal showing at least cholesteric phase and not chiral smectic phase in a proportion of 0.5 to 50 wt. parts of the total second liquid crystal content per 100 wt. parts of the total first liquid crystal content;

said liquid crystal composition being disposed in a layer thin enough to release the helical structure inherent to the chiral smectic phase in the absence of an electric field;

a face of each of said base plates being provided with an organic of inorganic insulating film having a rubbing or oblique vapor deposition uniaxial orientation treatment defining orientation axes, said orientation axes being parallel to each other.

16. The liquid crystal device according to claim 15, wherein only one of the base plates is provided with the uniaxial orientation treatment.

17. The liquid crystal device according to claim 15, wherein the uniaxial orientation treatment is provided by rubbing the face of a base plate.

18. The liquid crystal device according to claim 15, wherein the uniaxial orientation treatment is provided by forming a film on the base plate by the oblique vapor deposition of an inorganic insulating material.

19. The liquid crystal device according to claim 15, wherein the uniaxial orientation treatment is provided by the oblique etching of the face of a base plate.

20. The liquid crystal device according to claim 19, wherein a film of an organic or inorganic insulating material is formed on the face of the base plate and is subjected to oblique etching.

21. The liquid crystal device according to claim 17, wherein a film of an organic insulating material or an inorganic insulating material is formed on said face of a base plate.

22. The liquid crystal device according to claim 21, wherein said organic insulating material is at least one resin selected from the group consisting of polyvinyl alcohol, polyimide, polyamide-imide, polyester-imide, polyparaxylylene, polyester, polycarbonate, polyvinyl acetal, polyvinyl chloride, polyvinyl acetate, polyamide, polystyrene, cellulose resin, melamine resin, urea resin, acrylic resin and photoresist resins.

23. The liquid crystal device according to claim 21, wherein said inorganic insulating material is SiO, SiO₂ or TiO₂.

24. The liquid crystal device according to claim 18, wherein said inorganic insulating material is SiO or SiO₂.

25. The liquid crystal device according to claim 20, wherein said organic insulating material is at least one resin selected from the group consisting of polyvinyl alcohol, polyimide, polyamide-imide, polyester-imide, polyparaxylylene, polyester, polycarbonate, polyvinyl acetal, polyvinyl chloride, polyvinyl acetate, polyamide, polystyrene, cellulose resin, melamine resin, urea resin, acrylic resin and photoresist resins.

26. The liquid crystal device according to claim 20, wherein said inorganic insulating material is glass, SiO, SiO₂ or TiO₂.

27. The liquid crystal device according to claim 16, wherein said the other base plate is provided with a spacer member which has been provided by first forming a film of an insulating material and then etching the film except a selected portion thereof.

28. The liquid crystal device according to claim 27, wherein said spacer member is a member in the form of a stripe.

29. The liquid crystal device according to claim 28, wherein said spacer member is provided in plurality.

30. The liquid crystal device according to claim 15, wherein said chiral smectic phase is C phase, H phase, F phase, I phase, K phase, J phase or G phase.

31. A liquid crystal device comprising a pair of base plates and a ferroelectric chiral smectic liquid crystal composition interposed between the pair of base plates;

said ferroelectric chiral smectic liquid crystal composition exhibiting a phase transition through cholesteric phase and smectic A phase upon temperature decrease and comprising a first liquid crystal causing successive phase transition of isotropic phase, cholesteric phase, smectic A phase and chiral smectic phase on temperature decrease, and a second liquid crystal causing successive phase transition of isotropic phase, smectic A phase and chiral smectic phase on temperature decrease in a proportion of 0.1 to 50 wt. parts of the total first liquid crystal content per 1 wt. part of the total second liquid crystal content;

said liquid crystal composition being disposed in a layer thin enough to release the helical structure inherent to the chiral smectic phase in the absence of an electric field;

a face of each of said base plates being provided with an organic or inorganic insulating film having a rubbing or oblique vapor deposition uniaxial orientation treatment defining orientation axes, said orientation axes being parallel to each other.

32. The liquid crystal device according to claim 31, wherein said chiral smectic phase is C phase, H phase, F phase, I phase, K phase, J phase or G phase.

33. The liquid crystal device according to claim 31, wherein only one of the base plates is provided with the uniaxial orientation treatment.

34. The liquid crystal device according to claim 31, wherein the uniaxial orientation treatment is provided by rubbing the face of a base plate.

35. The liquid crystal device according to claim 34, wherein a film of an organic insulating material or an inorganic insulating material is formed on said face of a base plate.

36. The liquid crystal device according to claim 35, wherein said organic insulating material is at least one resin selected from the group consisting of polyvinyl alcohol, polyimide, polyamide-imide, polyester-imide, polyparaxylylene, polyester, polycarbonate, polyvinyl acetal, polyvinyl chloride, polyvinyl acetate, polyamide, polystyrene, cellulose resin, melamine resin, urea resin, acrylic resin and photoresist resins.

37. The liquid crystal device according to claim 35, wherein said inorganic insulating material is SiO, SiO₂ or TiO₂.

38. The liquid crystal device according to claim 31, wherein the uniaxial orientation treatment is provided to the face of a base plate by forming a film on the base plate by the oblique vapor deposition of an inorganic insulating material.

39. The liquid crystal device according to claim 31, wherein said inorganic insulating material is SiO or SiO₂.

40. The liquid crystal device according to claim 31, wherein the uniaxial orientation treatment is provided by oblique etching of the face of a base plate.

41. The liquid crystal device according to claim 40, wherein a film of an organic or inorganic insulating material is formed on the face of the base material and is subjected to oblique etching.

42. The liquid crystal device according to claim 41, wherein said organic insulating material is at least one resin selected from the group consisting of polyvinyl alcohol, polyimide, polyamide-imide, polyester-imide, polyparaxylylene, polyester, polycarbonate, polyvinyl acetal, polyvinyl chloride, polyvinyl acetate, polyamide, polystyrene, cellulose resin, melamine resin, urea resin, acrylic resin and photoresist resins.

43. The liquid crystal device according to claim 41, wherein said inorganic insulating material is glass, SiO, SiO₂ or TiO₂.

44. A liquid crystal device comprising a pair of base plates and a ferroelectric chiral smectic liquid crystal composition interposed between the pair of base plates;

said ferroelectric chiral smectic liquid crystal composition exhibiting a phase transition through cholesteric phase and smectic A phase upon temperature decrease and comprising a first liquid crystal causing successive phase transition of isotropic phase, cholesteric phase, smectic A phase and chiral smectic phase on temperature decrease, and a second liquid crystal causing successive phase transition of isotropic phase, cholesteric phase and crystalline phase, or of isotropic phase, cholesteric phase, smectic A phase and crystalline phase on temperature decrease in a proportion of 0.01 to 50 wt. parts of the total second liquid crystal content per 100 wt. parts of the total first liquid crystal content;

said liquid crystal composition being disposed in a layer thin enough to release the helical structure inherent to the chiral smectic phase in the absence of an electric field;

a face of each of said base plates being provided with an organic or inorganic insulating film having a rubbing or oblique vapor deposition uniaxial orientation treatment defining orientation axes, said orientation axes being parallel to each other.

45. The liquid crystal device according to claim 44, wherein said chiral smectic phase is C phase, H phase, F phase, I phase, K phase, J phase or G phase.

46. The liquid crystal device according to claim 44, wherein only one of the base plates is provided with the uniaxial orientation treatment.

47. The liquid crystal device according to claim 44, wherein the uniaxial orientation treatment is provided by rubbing the face of a base plate.

48. The liquid crystal device according to claim 47, wherein a film of an organic insulating material or an inorganic insulating material is formed on said face of a base plate.

49. The liquid crystal device according to claim 48, wherein said organic insulating material is at least one resin selected from the group consisting of polyvinyl alcohol, polyimide, polyamide-imide, polyester-imide, polyparaxylylene, polyester, polycarbonate, polyvinyl acetal, polyvinyl chloride, polyvinyl acetate, polyamide, polystyrene, cellulose resin, melamine resin, urea resin, acrylic resin and photoresist resins.

50. The liquid crystal device according to claim 48, wherein said inorganic insulating material is glass, SiO, SiO₂ or TiO₂.

51. The liquid crystal device according to claim 44, wherein the uniaxial orientation treatment is provided by forming a film on the base plate by oblique vapor deposition of an inorganic insulating material.

52. The liquid crystal device according to claim 44, wherein said inorganic insulating material is SiO or SiO₂.

53. The liquid crystal device according to claim 44, wherein the uniaxial orientation treatment is provided by oblique etching of the face of a base plate.

54. The liquid crystal device according to claim 53, wherein a film of an organic or inorganic insulating material is formed on the face of the base plate and is subjected to oblique etching.

55. The liquid crystal device according to claim 54, wherein said organic insulating material is at least one resin selected from the group consisting of polyvinyl alcohol, polyimide, polyamide-imide, polyester-imide, polyparaxylylene, polyester, polycarbonate, polyvinyl acetal, polyvinyl chloride, polyvinyl acetate, polyamide, polystyrene, cellulose resin, melamine resin, urea resin, acrylic resin and photoresist resins.

56. The liquid crystal device according to claim 54, wherein said inorganic insulating material is glass, SiO, SiO₂ or TiO₂.

57. A liquid crystal device comprising a pair of base plates and a ferroelectric chiral smectic liquid crystal composition interposed between the pair of base plates;

said ferroelectric chiral smectic liquid crystal composition exhibiting a phase transition through cholesteric phase and smectic A phase upon temperature decrease and comprising a first liquid crystal causing successive phase transition of isotropic phase, cholesteric phase and chiral smectic phase on temperature decrease, and a second liquid crystal causing successive phase transition of isotropic phase, cholesteric phase, smectic A phase and crystalline phase on temperature decrease in a proportion of 0.1 to 50 wt. parts of the total second liquid crystal content per 100 wt. parts of the total first liquid crystal content;

said liquid crystal composition being disposed in a layer thin enough to release the helical structure inherent to the chiral smectic phase in the absence of an electric field;

a face of each of said base plates being provided with an organic or inorganic insulating film having a rubbing or oblique vapor deposition uniaxial orientation treatment defining orientation axes, said orientation axes being parallel to each other.

58. The liquid crystal device according to claim 57, wherein said chiral smectic phase is C phase, H phase, F phase, I phase, K phase, J phase or G phase.

59. The liquid crystal device according to claim 57, wherein only one of the base plates is provided with the uniaxial orientation treatment.

60. The liquid crystal device according to claim 57, wherein the uniaxial orientation treatment is provided by rubbing the face of a base plate.

61. The liquid crystal device according to claim 60, wherein a film of an organic insulating material or an inorganic insulating material is formed on said face of a base plate.

62. The liquid crystal device according to claim 61, wherein said organic insulating material is at least one resin selected from the group consisting of polyvinyl alcohol, polyimide, polyamide-imide, polyester-imide, polyparaxylylene, polyester, polycarbonate, polyvinyl acetal, polyvinyl chloride, polyvinyl acetate, polyamide, polystyrene, cellulose resin, melamine resin, urea resin, acrylic resin and photoresist resins.

63. The liquid crystal device according to claim 61, wherein said inorganic insulating material is SiO, SiO₂ or TiO₂.

64. The liquid crystal device according to claim 57, wherein the uniaxial orientation treatment is provided by forming a film on the base plate by the oblique vapor deposition of an inorganic insulating material.

65. The liquid crystal device according to claim 57, wherein said inorganic insulating material is SiO or SiO₂.

66. The liquid crystal device according to claim 57, wherein the uniaxial orientation treatment is provided by oblique etching of the face of a base plate.

67. The liquid crystal device according to claim 66, wherein a film of an organic or inorganic insulating material is formed on the face of the base material and is subjected to oblique etching.

68. The liquid crystal device according to claim 67, wherein said organic insulating material is at least one resin selected from the group consisting of polyvinyl alcohol, polyimide, polyamide-imide, polyester-imide, polyparaxylylene, polyester, polycarbonate, polyvinyl acetal, polyvinyl chloride, polyvinyl acetate, polyamide, polystyrene, cellulose resin, melamine resin, urea resin, acrylic resin and photoresist resins.

69. The liquid crystal device according to claim 67, wherein said inorganic insulating material is SiO, SiO₂ or TiO₂.