Ethylene vinyl acetate polymers for latex caulks

• US 5,120,785 A
• Filed: 10/28/1988
• Issued: 06/09/1992
• Est. Priority Date: 10/28/1988
• Status: Expired due to Fees

• Current Assignee: National Starch and Chemical Holding Corporation (Nouryon BV)
• Original Assignee: National Starch and Chemical Investment Holding Corporation
• Inventors: Walker, James L., Mudge, Paul R.
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): Reddick, J. M.
• Application Number:
  US07/264,102
• Time in Patent Office: 1,320 Days
• Field of Search: 524/555, 524/425, 524/446, 524/451, 524/448, 524/449, 524/423, 524/445, 524/436
• US Class Current: 524/423
• CPC Class Codes: C04B 26/04 obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C08F 218/04 Vinyl esters
• CPC Class Codes: C08F 220/1804 C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
• CPC Class Codes: E04F 15/14 Construction of joints, e.g. dividing strips E04F15/02005 takes precedence; sealing joints not restricted to flooring E04B1/68 , construction of joints in roads or airfields E01C11/02

Abstract

Latex caulk compositions comprising 30 to 80% filler and 20 to 70% by weight of an emulsion polymer prepared for the interpolymerization of 30 to 70 parts by weight of a vinyl ester of an alkanoic acid; 15 to 60 parts of an alkyl (C₂ and C₈) acrylate or dialkyl (C₂ to C₁₀) maleate; 10 to 30 parts ethylene; 1 to 5 parts olefinically unsaturated carboxylic acid; 0 to 5 parts polyolefinically unsaturated monomer and 0 to 8 parts of a copolymerizable functional monomer containing hydroxyl, amide or methylol substituents, (to total 100 parts by weight).

Claims

1. Latex caulk compositions comprising 30 to 80% of a filler selected from the group consisting of calcium carbonate, mica, talc, diatomaceous earth, barytes, alumina, slate flour, calcium silicate, clay, colloidal silica, magnesium carbonate and magnesium silicate and 20 to 70% by weight of a polymer prepared by emulsion polymerization techniques, said polymer comprising 30 to 70 parts by weight of a vinyl ester of an alkanoic acid;

15 to 60 parts by weight of an alkyl (C₂ to C₈) acrylate or dialkyl (C₂ to C₁₀) maleate;

10 to 30 parts by weight ethylene;

1 to 5 parts by weight of an olefinically unsaturated mono-or dicarboxylic acid;

0 to 5 parts by weight of a multi-functional monomer selected from the group consisting of a lower alkenyl lower alkenoates;

di-lower alkenyl alkanedioates, di-lower alkylene bisacrylamides and lower alkylene bis-methacrylamides, and triallyl cyanurate; and

0 to 8 parts by weight of a copolymerizable functional monomer containing hydroxyl, amide or methylol substituents, (to total 100 parts by weight).

2. The caulk of claim 1 wherein the vinyl ester is vinyl acetate.

3. The caulk of claim 1 wherein the vinyl ester is present in an amount of 50 to 60% by weight of the polymer.

4. The caulk of claim 1 wherein the alkyl(C₂ to C₈) acrylate or dialkyl (C₂ to C₁₀) maleate component is present in an amount of 25 to 40% weight.

5. The caulk of claim 1 wherein the olefinically-unsaturated carboxylic acid is selected from the group consisting of acrylic acid, meth-acrylic acid, crotonic acid, itaconic acid, maleic acid or fumaric acid, or mixtures thereof.

6. The caulk of claim 1 wherein there is present a monomer selected from the group consisting of vinyl crotonate, allyl acrylate, allyl methacrylate, diallyl maleate, divinyl adipate, diallyl adipate, diallyl phthalate, ethylene glycol diacrylate, ethylene glycol dimethacrylate, butanediol dimethacrylate, methylene bis-acrylamide and triallyl cyanurate.

7. The caulk of claim 1 wherein there is also present in the polymer a copolymerizable comonomer selected from the group consisting of methacrylamide, acrylamide, hydroxyalkyl (C₂ -C₄) acrylates or methacrylates.

8. The caulk of claim 1 wherein the polymer has a glass transition temperature of -40°

to 0°

C.

9. The caulk of claim 1 wherein the polymer has a glass transition temperature of -30°

to 10°

C.

10. The caulk of claim 1 containing, in addition to the filler and emulsion polymer at least one member selected from the group consisting of pigments, plasticizers, free-thaw stabilizers, drying oils, pigment dispersants, solvents, anti-bacterial or anti-fungal preservatives, thickeners and anti-slump agents.

11. The caulk of claim 1 wherein there is present in the polymer 1 to 8 parts by weight of N-methylol acrylamide.