Air separation

• US 5,123,249 A
• Filed: 04/17/1991
• Issued: 06/23/1992
• Est. Priority Date: 04/18/1990
• Status: Expired due to Term

• Current Assignee: BOC Group BV (Linde Plc)
• Original Assignee: BOC Group BV (Linde Plc)
• Inventors: Buttle, Andrea
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US07/686,738
• Time in Patent Office: 433 Days
• Field of Search: 62/13, 62/24, 62/38, 62/43
• US Class Current: 62/646
• CPC Class Codes: F25J 2245/40 the recycled stream being air
• CPC Class Codes: F25J 2290/10 Mathematical formulae, modeling, plot or curves; Design methods
• CPC Class Codes: F25J 3/042 having an intermediate feed connection
• CPC Class Codes: F25J 3/0429 of feed air, e.g. used as waste or product air or expanded into an auxiliary column
• CPC Class Codes: F25J 3/04303 Lachmann expansion, i.e. expanded into oxygen producing or low pressure column
• CPC Class Codes: F25J 3/04309 of nitrogen
• CPC Class Codes: F25J 3/04393 using multiple or multistage gas work expansion
• CPC Class Codes: F25J 3/04412 in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
• CPC Class Codes: F25J 3/04678 cooled by oxygen enriched liquid from high pressure column bottoms
• CPC Class Codes: Y10S 62/939 Partial feed stream expansion, air

Abstract

A compressed air stream is separated in a double rectification column having a higher pressure stage and a lower pressure stage. The lower pressure stage contains a low pressure drop liquid-vapor contact means having a pressure drop of less than about 400.0 Pa per theoretical stage, for example a structured packing, to effect mass transfer between ascending vapor and descending liquid. A product gaseous oxygen stream is withdrawn from the lower pressure stage through an outlet thereof and is warmed to about ambient temperature in a heat exchanger in countercurrent flow relationship with the compressed air stream which is thereby cooled. Refrigeration for the process is created by expansion of part of the incoming air. By using a low pressure drop liquid-vapor contact means in the lower pressure stage, the resulting operating pressure in the higher pressure stage is able to be lower than in a conventional process enabling the incoming air to be compressed to a lower pressure (for example a pressure in a range of about 5.0 to 6.0 bar). At such pressures, two expansion turbines are used to enable the heat exchanger to be operated efficiently.

Claims

1. A method of separating an oxygen product from air, including:

reducing the temperature of a compressed air stream by heat exchange in heat exchange means to a value suitable for its separation by rectification;

introducing the thus cooled air stream into the higher pressure stage of a double rectification column for the separation of air;

said double rectification column comprising a lower pressure stage and a higher pressure stage;

employing the higher pressure stage of the column to provide liquid nitrogen reflux and an oxygen-enriched air feed for the lower pressure stage; and

withdrawing oxygen product from the lower pressure stage;

wherein at least about 70.0% of the oxygen product is taken as gas from the double rectification column;

at least the lower pressure stage includes a low pressure drop liquid-vapour contact means, having a pressure drop of less than about 400.0 Pa per theoretical stage of separation for effecting intimate contact and hence mass transfer between liquid and vapour; and

wherein refrigeration for the method is created in two steps by performing at least two separate expansions of fluid with the performance of external work, a first such expansion taking fluid from the heat exchange means at a higher temperature and returning the fluid thereto at a lower temperature, both said higher and lower temperatures being between the temperature of the air stream at the cold end and that at the warm end of the heat exchange means; and

a second such expansion producing fluid at a lowermost of no greater than temperature that at which the said compressed air stream leaves the cold end of the heat exchange means.

2. The method of claim 1, in which at least one of the at least two separate expansions is performed on compressed air taken from the compressed air stream.

3. The method of claim 1, in which the first expansion produces fluid at a temperature in a range of between about 120.0°

K. and about 160.0°

K.

4. The method of claim 1, in which the fluid for the second expansion is taken from the heat exchange means at a temperature in a range of between about 120.0°

K. and about 160.0°

K.

5. The method of claim 1, in which one of the expansions is performed on a nitrogen stream withdrawn from the higher pressure stage of the rectification column.

6. The method of claim 1, in which the oxygen product is taken as one of entirely as gas and less than about 10.0% by volume of the oxygen product is produced in liquid state.

7. The method of claim 1 in which the low pressure drop liquid-vapour contact means comprises structured packing.

8. The method of claim 1 in which the higher pressure stage of the double rectification column operates at a pressure, half way up the stage, in the range of between about 4.5 and about 5.5 bar.

9. An apparatus for separating an oxygen product from air comprising:

a main air compressor;

heat exchange means for reducing a compressed air stream from the main air compressor to a temperature suitable for its separation by rectification;

a double rectification column having a lower pressure stage and a higher pressure stage, the higher pressure stage communicating with an outlet for the compressed air stream from the heat exchange means and at least the lower pressure stage including a low pressure drop liquid-vapour contact means having a pressure drop of less than 400 Pa per theoretical stage of separation for effecting intimate contact and hence mass transfer between liquid and vapour;

two conduits leading from the lower pressure stage to the higher pressure stage for transferring respectively oxygen-rich fluid from the bottom of the lower pressure stage and liquid nitrogen from the top of the higher pressure stage to the lower pressure stage;

an oxygen product conduit and a nitrogen conduit leading back from the low pressure column to the cold end of the heat exchange means whereby oxygen and nitrogen are able to pass back through the heat exchange means in countercurrent heat exchange relationship to the incoming air;

the oxygen product conduit arranged so as to enable at least about 70.0% of the oxygen product to be taken as gas;

a first expansion turbine for producing refrigeration for the apparatus which in use takes fluid from the heat exchange means at a higher temperature and returns the fluid thereto at a lower temperature, both said higher and lower temperatures being between the temperature of the air stream at the cold end and at the warm end of the heat exchange means; and

a second such expansion turbine which in use has an outlet temperature at or below that at which the compressed air stream leaves the cold end of the heat exchange means.

10. The apparatus of claim 9, in which the low pressure liquid-vapour contact means comprises structured packing.