Copper chromite catalyst and process for preparation said catalyst

• US 5,124,295 A
• Filed: 12/13/1990
• Issued: 06/23/1992
• Est. Priority Date: 12/13/1990
• Status: Expired due to Term

• Current Assignee: Engelhard Corporation (BASF SE)
• Original Assignee: Engelhard Corporation (BASF SE)
• Inventors: Kelly, Donald G., Nebesh, Eugene, Novak, Lawrence T.
• Primary Examiner(s): Shine, W. J.
• Application Number:
  US07/627,013
• Time in Patent Office: 558 Days
• Field of Search: 502/64, 502/244, 502/318
• US Class Current: 502/64
• CPC Class Codes: B01J 23/868 copper and chromium
• CPC Class Codes: B01J 35/60 characterised by their surface properties or porosity
• CPC Class Codes: B01J 35/613 10-100 m2/g
• CPC Class Codes: B01J 35/615 100-500 m2/g
• CPC Class Codes: B01J 35/633 less than 0.5 ml/g
• CPC Class Codes: B01J 35/635 0.5-1.0 ml/g
• CPC Class Codes: B01J 37/0009 Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst

Abstract

In one embodiment,the invention relates to a formed copper chromite catalyst prepared from a blend comprising from about 20 to about 80% by weight of copper chromite and from about 20 to about 80% by weight of at least one extrudable inorganic binder material wherein the catalyst has a surface area of from about 20 to about 225 m² /g, and the total pore volume of the pores in said catalyst having a diameter of up to about 95,000 Å is between about 0.35 to about 1 cc/g. In another embodiment, the invention relates to a process for preparing the formed copper chromite catalyst of the invention, and the process comprises

(A) preparing a blend comprising from about 20 to about 80% by weight of copper chromite, from about 20 to about 80% by weight of at least one extrudable inorganic binder material, from about 1 to about 10% by weight, based on the weight of the binder, of a peptizing agent, and sufficient water to form an extrudable blend;

(B) extruding the blend to form an extrudate; and

(C) calcining the extrudate.

The invention also relates to a process for hydrogenating aldehydes, ketones, carboxylic acids and carboxylic acid esters with catalysts of the type described.

Claims

1. A formed copper chromite catalyst prepared from a blend comprising from about 20 to about 80% by weight of copper chromite and from about 20 to about 80% by weight of at least one extrudable inorganic binder material wherein the catalyst has a surface area from about 20 to about 225 m² /g, and the total pore volume of the pores in said catalyst having a diameter of up to about 95,000 Å

is between about 0.35 to about 1 cc/g.

2. The catalyst of claim 1 wherein the total pore volume of the pores in said catalyst having a diameter of up to about 95,000 Å

is between about 0.4 to about 0.6 cc/g.

3. The catalyst of claim 1 wherein the surface area of the catalyst is between about 75 and 180 m² /g.

4. The catalyst of claim 1 wherein at least a portion of the copper chromite in the blend has the formula

5. The catalyst of claim 1 wherein the binder material comprises a mixture of alumina and at least one additional inorganic oxide.

6. The catalyst of claim 1 comprising from about 50 to about 80% by weight of copper chromite and from about 20 to about 50% by weight of at least one inorganic binder material.

7. The catalyst of claim 5 wherein the binder material comprises a mixture of alumina and silica.

8. The catalyst of claim 1 wherein the binder material comprises a mixture of alumina and a crystalline inorganic polymer comprising silica and alumina.

9. The catalyst of claim 8 wherein the mole ratio of silica to alumina is at least 10.

10. The catalyst of claim 8 wherein the crystalline inorganic polymer is an aluminosilicate zeolite.

11. The catalyst of claim 8 wherein the catalyst comprises from about 5% to about 30% of the crystalline inorganic polymer.

12. The catalyst of claim 1 wherein at least of portion of the copper and copper chromite are present in the reduced state.

13. The catalyst of claim 1 also including up to about 10% by weight of a stabilizer selected from the group consisting of barium and manganese.

19. A method of preparing the formed copper chromite catalyst of claim 1 comprising

(A) preparing a blend comprising from about 20 to about 80% by weight of copper chromite, from about 20 to about 80% by weight of at least one extrudable inorganic binder material, from about 1 to about 10% by weight, based on the weight of the binder, of a peptizing agent, and sufficient water to form an extrudable blend;

(B) extruding the blend to form an extrudate; and

(C) calcining the extrudate.

20. The method of claim 19 wherein the calcined extrudate obtained in step (c) is reduced.

21. The method of claim 20 wherein the reduced catalyst is stabilized with air or CO₂ or protected with an inert liquid.

22. The method of claim 19 wherein the peptizing agent is a mineral or an organic acid.

14. A formed copper chromite catalyst prepared from a blend of from about 20 to about 80% by weight of copper chromite wherein at least a portion has the formula

View Dependent Claims (15, 16, 17, 18)

15. The catalyst of claim 14 wherein the total pore volume of the pores in said catalyst having a diameter of up to about 95,000 Å

is between about 0.40 and 0.60 cc/g.

16. The catalyst of claim 14 wherein the inorganic binder material comprises a mixture of alumina and an aluminosilicate zeolite.

17. The catalyst of claim 14 wherein the blend comprises from about 60 to about 80% by weight of the copper chromite and from about 20 to about 40% by weight of a mixture of binder materials comprising alumina and at least one other inorganic oxide.

18. The catalyst of claim 14 wherein at least a portion of the copper and copper chromite are present in the reduced state.