Films or sheets of blends of amorpous poly(aryl ether ketones) with polyarylates and laminates thereof

• US 5,124,413 A
• Filed: 09/13/1990
• Issued: 06/23/1992
• Est. Priority Date: 09/13/1990
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Luise, Robert R.
• Primary Examiner(s): SHORT, PATRICIA A
• Application Number:
  US07/581,996
• Time in Patent Office: 649 Days
• Field of Search: 525/437, 525/448
• US Class Current: 525/448
• CPC Class Codes: C08L 2666/18 Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
• CPC Class Codes: C08L 2666/22 Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
• CPC Class Codes: C08L 65/00 Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain C08L7/00 - C08L57/00, C08L61/00 take precedence; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 67/03 the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
• CPC Class Codes: C08L 71/00 Compositions of polyethers obtained by reactions forming an ether link in the main chain of polyacetals C08L59/00; of epoxy resins C08L63/00; of polythioether-ethers C08L81/02; of polyether-sulfones C08L81/06; Compositions of derivatives of such polymers

Abstract

A melt-processable, miscible or partially miscible blend of an amorphous, isotropic polyarylate with a poly(ether ketone ketone) that does not possess a sharp or well defined melting endotherm by differential scanning calorimetry when observed on second heating under defined conditions can be extruded into sheets useful in aircraft panels and in other applications that require high burn resistance and good melt processability.

Claims

1. A readily melt-processable, miscible, or partially miscible amorphous blend of about 10-70 weight percent of an amorphous, isotropic polyarylate derived from a reaction of one or more dihydric phenols with one or more aromatic dicarboxylic acids with a complementary amount of 90-30 weight percent of an amorphous poly(ether ketone ketone) having repeating units of the following formula ##STR2## where Ph stands for 1,4-phenylene:

Ph'"'"' stands for 1,3-phenylene; and

x and y are positive numbers, x being a number selected from the ranges consisting of (x+y)(0 to

     40)/100 and (x+y)(55 to

     65)/100, and y is a number selected from the ranges of (x+y)(60 to

     100)/100 and (x+y)(35 to

     45)/100, the amorphous condition of the poly(ether ketone ketone) being determined by differential scanning calorimetry when observed on second heat under nitrogen at a rate of 20°

C. or more per minute, after the specimen has been initially heated in the calorimeter at a rate of 20°

C. or more per minute from room temperature to 370°

C., then cooled to 100°

C. at a rate of 20°

C. or more per minute.

2. A blend of claim 1 wherein x is a number from 55(x+y)/100 to 65(x+y)/100, and y is a number from 35(x+y)/100 to 45(x+y)/100.

3. A blend of claim 2 wherein x is about 60(x+y)/100, and y is about 40(x+y)/100.

4. A blend of claim 1 wherein the polyarylate is a mixed polyester of bisphenol A with terephthalic and isophthalic acids.

5. A blend of claim 1 wherein the polyarylate is a polyester of at least one dihydroxybenzene with isophthalic acid or a mixture of isophthalic acid with terephthalic acid.

6. A completely miscible blend of claim 1.

7. A completely miscible blend of claim 2.

8. A completely miscible blend of claim 4.

9. A completely miscible blend of claim 5.

10. A blend of claim 1 wherein the amount of polyarylate is 50-70 weight percent and the amount of poly(ether ketone ketone) is 30-50 weight percent.