Tritiated light emitting polymer electrical energy source

• US 5,124,610 A
• Filed: 03/04/1991
• Issued: 06/23/1992
• Est. Priority Date: 03/03/1989
• Status: Expired due to Term

• Current Assignee: E F Johnson Company (JVC Kenwood Corporation)
• Original Assignee: E F Johnson Company (JVC Kenwood Corporation)
• Inventors: Conley, Jerry J., Mortensen, Gary B.
• Primary Examiner(s): Moskowitz, Nelson
• Application Number:
  US07/664,203
• Time in Patent Office: 477 Days
• Field of Search: 310/302, 310/303, 136/249, 136/253, 357/30, 313/504
• US Class Current: 310/303
• CPC Class Codes: G21H 1/12 Cells using conversion of the radiation into light combined with subsequent photoelectric conversion into electric energy
• CPC Class Codes: H01L 31/12 structurally associated with, e.g. formed in or on a common substrate with, one or more electric light sources, e.g. electroluminescent light sources, and electrically or optically coupled thereto semiconductor devices with at least one potential barrier or surface barrier adapted for light emission H01L33/00; amplifiers using electroluminescent element and photocell H03F17/00; electroluminescent light sources per se H05B33/00

Abstract

An electrical energy source is created by the combination of a light emitting polymer material having at least one light emitting surface emitting light energy of a specified frequency bandwidth and a photovoltaic cell having a light collecting surface and a pair of electrical contacts. The light collecting surface of the photovoltaic cell is optically coupled with the light emitting surface of the light emitting polymer material. An open-circuit voltage is generated between the pair of electrical contacts as a result of the absorption of emitted light energy from the light emitting polymer material by the photovoltaic cell. The light emitting polymer comprises a mixture of a polymer labelled with a tritium and an organic compound which emits light energy when subjected to radiation generated by the tritium. The organic compound is at least partly bonded to the polymer and the mixture is translucent at the specified frequency bandwidth of the light energy. Maximum absorption of the emitted light energy is achieved by the intimate optical contact between the light emitting surface and the light collecting surface, by matching the maximum absorption frequency bandwidth of the photovoltaic cell with the specified frequency bandwidth of the emitted light energy from the light emitting polymer material, and by the structural arrangement of the light emitting polymer material itself.

Claims

1. An electrical energy source, comprising:

a light emitting polymer material having at least one light emitting surface emitting light energy in a specified frequency bandwidth, the light emitting polymer material comprising a mixture of a polymer labelled with a tritium and an organic compound which emits the light energy when subjected to radiation generated by the tritium, where the organic compound is at least partly bonded to the polymer and the mixture is translucent at the specified frequency bandwidth of the light energy; and

a photovoltaic cell having a light collecting surface and a pair of electrical contacts, the light collecting surface of the photovoltaic cell being substantially intimately optically coupled to the light emitting surface of the light emitting polymer material, such that an open-circuit voltage is generated between the pair of electrical contacts as a results of the photovoltaic cell'"'"'s absorption of the light energy emitted from the light emitting polymer material.

2. The electrical energy source of claim 1 wherein organic compound is comprised of a primary organic phosphor for absorbing a beta particle emitted by the polymer labelled with tritium and emitting photons at a first frequency bandwidth and a secondary organic phosphor for shifting the frequency bandwidth of the photons emitted by the primary organic phosphor to establish the specified frequency bandwidth for the light energy emitted by the light emitting polymer material.

3. The electrical energy source of claim 2 wherein the primary organic phosphor consists of a phosphor from the group PPO, PBD, and POPOP.

4. The electrical energy source of claim 1 wherein the photovoltaic cell has a maximum absorption value at a specified frequency bandwidth that is matched to the specified frequency bandwidth of the emitted light energy of the light emitting polymer material.

5. The electrical energy source of claim 1 wherein the specified frequency bandwidth of the emitted light energy of the light emitting polymer is substantially monochromatic.

11. The electrical energy source of claim 1 wherein the polymer is a vinyl aromatic hydrocarbon.

12. The electrical energy source of claim 1 wherein the polymer is comprised of a combination of tritium-labeled monomers and unlabled monomers which are subjected to polymerization along with the organic compound.

13. The electrical energy source of claim 12 wherein the tritium labeled monomers and the unlabled monomers are deuterated prior to polymerization.

14. The electrical energy source of claim 1 wherein the polymer is labelled to an activity of 1-100 Ci/g.

6. An active electrical element, comprising:

a light emitting polymer material having at least one light emitting suface emitting light energy in a specified frequency bandwidth, the light emitting polymer material comprising comprising a mixture of a polymer labelled with a tritium and a first organic compound which emits the light energy when subjected to radiation generated by the tritium wherein the organic compound is at least partly bonded to the polymer and the mixture is translucent at the specified frequency bandwidth of the light energy;

a photovoltaic cell having a light collecting surface and a pair of electrical contacts, the light collecting surface of the photovoltaic cell being optically coupled to the light emitting surface of the light emitting polymer material; and

optical control means intimately interposed between the light emitting surface of the light emitting polymer material and the light collecting surface of the photovoltaic cell for controlling the amount of light energy that may be absorbed by the photovoltaic cell,

such that an open-circuit voltage is generated between the pair of electrical contacts as a result of the photovoltaic cell'"'"'s absorption of the light energy emitted from the light emitting polymer material when the optical control means allows at least a minimum amount of the emitted light energy to be absorbed by the photovoltaic cell.

7. The electrical energy source of claim 6 wherein the optical control means is a liquid crystal display material.

8. The electrical energy source of claim 6 wherein the optical control means is a lead lantium zirconium titinate material.

9. The electrical energy source of claim 6 wherein the photovoltaic cell has a maximum absorption value at a specified frequency bandwidth that is matched to the specified frequency bandwidth of the emitted light energy of the light emitting polymer material.

10. The electrical energy source of claim 9 wherein the specified fequency bandwidth of the emitted light energy of the light emitting polymer is substantially monochromatic.

15. The active electrical element of claim 6 wherein the organic compound is comprised of a primary organic phosphor for obsorbing a beta particle emitted by the polymer labelled with tritium and emitting photons at a first frequency bandwidth and a secondary organic phosphor for shifting the frequency bandwidth of the photons emitted by the primary organic phosphor to establish the specified frequency bandwidth for the light energy emitted by the light emitting polymer material.

16. The active electrical element of claim 15 wherein the primary organic phosphor consists of a phosphor from the group PPO, PBD and POPOP.

17. The active eletrical element of claim 6 wherein the polymer is a vinyl aromatic hydrocarbon.

18. The active electrical element of claim 6 wherein the polymer is comprised of a combination of tritium-labeled monomers and unlabeled monomers which are subjected to polymerization along with the organic compound.

19. The active electrical element of claim 18 wherein the tritium labeled monomers and the unlabeled monomers are deuterated prior to polymerization.

20. The active electrical element of claim 6 wherein the polymer is labelled to an activity of 1-100 Ci/g.