Mica and vermiculite paper and its preparation

• US 5,126,013 A
• Filed: 03/18/1991
• Issued: 06/30/1992
• Est. Priority Date: 03/18/1991
• Status: Expired due to Fees

• Current Assignee: Armstrong World Industries Incorporated
• Original Assignee: Armstrong World Industries Incorporated
• Inventors: Wiker, Anthony L., Work, James L.
• Primary Examiner(s): Chin, Peter
• Application Number:
  US07/671,087
• Time in Patent Office: 470 Days
• Field of Search: 162/181.6, 162/152, 162/156, 162/145, 162/157.2, 162/146, 162/183, 162/164.6, 162/168.2, 162/168.3
• US Class Current: 162/156
• CPC Class Codes: D21H 13/26 Polyamides; Polyimides
• CPC Class Codes: D21H 13/40 vitreous, e.g. mineral wool, glass fibres
• CPC Class Codes: D21H 13/44 Flakes, e.g. mica, vermiculite
• CPC Class Codes: D21H 17/375 Poly(meth)acrylamide
• CPC Class Codes: D21H 17/45 Nitrogen-containing groups
• CPC Class Codes: D21H 23/765 Addition of all compounds to the pulp

Abstract

Mineral paper is provided which comprises a wet-laid sheet of 1) fibers, 2) a floc of a silicate selected from the group consisting of mica and vermiculite, the said floc having a cationic polymeric flocculant having a molecular weight in the range of from about 10,000 to about 1,000,000, and 3) a non-ionic polymeric flocculant having a molecular weight of from about 2,000,000 to about 10,000,000. A process is described herein for the preparation of the paper using the two flocculants by first flocculating with the cationic polymeric flocculant and then flocculating in another step with the non-ionic polymeric flocculant to obtain an easily drained flocculated mixture which is dewatered to obtain the mineral paper.

Claims

1. A mineral paper comprising a wet-laid sheet of 1) fibers, 2) a floc of a chemically delaminated 2:

1 layered silicate selected from the group, consisting of mica and vermiculite, the said floc having a cationic polymeric flocculant with from about 3 to about 8 milliequivalents of cation per gram of the polymeric flocculant, said cationic polymeric flocculant being present at an amount in the range of from about 3.5 to about 6 percent by weight, and further having a molecular weight in the range of from about 10,000 to about 1,000,000 and

     3) a nonionic polyacrylamide flocculant at an amount in the range of from about 5.5 to about 8 percent by weight which further has a molecular weight in the range of from about 2,000,000 to 10,000,000.

2. The paper of claim 1 wherein the fiber is selected from the group consisting of polybenzimidazole, glass, cellulose, polyamide, polyolefin, aromatic polyamide, and polyester.

3. The paper of claim 1 wherein the cationic polymeric flocculant is an amine.

4. The paper of claim 1 also having a filler.

5. The paper of claim 1 having from about 5 to about 85% by weight fiber and from about 20 to about 95% by wt. of the silicate.

6. The paper of claim 1 wherein the fiber is selected from the group consisting of polybenzimidazole and glass.

7. A process for the preparation of mineral paper which comprises the steps of 1) preparing an aqueous suspension containing, as solids ingredients, fibers and a chemically delaminated 2:

1 layered silicate selected from the group consisting of mica and vermiculite,

     2) adding a cationic polymeric flocculant at an amount in the range of from about 0.04 to about 0.06 grams per gram of the solids ingredients to obtain a flocculation, wherein the cationic flocculant has a molecular weight in the range of from about 10,000 to about 1,000,000,

     3) flocculating again with a non-ionic polyacrylamide flocculant at an amount in the range of from about 0.06 to about 0.08 grams per gram of the solids ingredients, said non-ionic polyacrylamide flocculant having a molecular weight of from about 2,000,000 to about 10,000,000, and

     4) dewatering to form the mineral paper.

8. The process of claim 7 wherein the fiber is selected from the group consisting of polybenzimidazole, glass, cellulose, polyamide, polyolefin, aromatic polyamide, and polyester.

9. The process of claim 7 wherein the cationic polymeric flocculant has from about 3 to about 8 milliequivalents of cation per gram of the flocculant.

10. The process of claim 7 wherein the cationic polymeric flocculant is an amine.

11. The process of claim 7 wherein the fiber is selected from the group consisting of polybenzimidazole and glass.

12. The process of claim 7 having from about 5 to about 85% by wt. fiber and from about 20 to about 95% by wt. of the silicate.