Transparent polyurethane layer resistant to fogging, method of manufacture and glazing provided with said layer

• US 5,126,209 A
• Filed: 02/02/1988
• Issued: 06/30/1992
• Est. Priority Date: 02/02/1987
• Status: Expired due to Fees

• Current Assignee: Saint-Gobain Vitrage
• Original Assignee: Saint-Gobain Vitrage
• Inventors: Kruger, Albert A.
• Primary Examiner(s): McCamish, Marion E.
• Assistant Examiner(s): KOECKERT JR, ARTHUR
• Application Number:
  US07/151,492
• Time in Patent Office: 1,610 Days
• Field of Search: 523/169, 522/144, 427/44, 427/53.1, 427/54.1, 428/423.1, 428/424.2, 525/440, 525/454
• US Class Current: 428/425.6
• CPC Class Codes: B32B 17/1077 containing polyurethane
• CPC Class Codes: C08F 220/06 Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
• CPC Class Codes: C08F 283/006 on to polymers provided for in C08G18/00 C08F283/004 takes precedence
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 7/18 using wave energy or particle radiation
• CPC Class Codes: Y10S 522/911 Specified treatment involving megarad or less
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31573 Next to addition polymer of ethylenically unsaturated monomer
• CPC Class Codes: Y10T 428/31601 Quartz or glass

Abstract

A transparent polyurethane layer which is resistant to fogging. The layer contains monomers and/or oligomers of acrylic acid or of salts of said acid grafted radiochemically to the surface of said layer. The layer is used as a coating layer for laminated glazings.

Claims

1. A transparent aliphatic polyurethane layer having cross-link bonds, which can be used in safety glazing, this layer having properties of the surface including resistance to scratching and abrasion, and having monomers and/or oligomers of acrylic acid or of salts of said acrylic acid radiochemically grafted to its surface such that the resulting layer has anti-fogging properties.

2. A laminated glazing containing a coating of the polyurethane layer in accordance with claim 1.

4. A method of making a layer of polyurethane having improved surface properties in accordance with claim 2, wherein acrylic acid is grafted onto a polyurethane surface by putting the polyurethane layer in contact with said acrylic acid and grafting by irradiation, said irradiation being by electron bombardment or photoemission.

5. The polyurethane layer formed by the process of claim 4.

3. A method for manufacture of a polyurethane layer having anti-fogging properties, and having properties of the surface including resistance to scratching and abrasion, which can be employed in safety glazing, wherein acrylic acid or a salt thereof is grafted to the surface of the polyurethane by placing the polyurethane layer in the presence of the acrylic acid and grafting by irradiation of said polyurethane surface and preventing the formation of an acrylic polymer.

6. The method in accordance with claim 3, wherein the acrylic acid is grafted by a low energy electron bombardment.

7. The method in accordance with claim 6, wherein the aqueous solution of acrylic acid is deposited onto the polyurethane layer and the layer covered in this manner is submitted to electronic bombardment.

8. The method of claim 6, wherein said polyurethane surface is first irradiated and then contacted with said acrylic acid.

9. The method in accordance with claim 3, wherein the placing of the polyurethane layer in the presence of the acrylic acid is carried out by the deposit onto the polyurethane layer of an aqueous solution whose acrylic acid content is less than 20%.

10. The method of claim 9, wherein said concentration is less than 10%.

11. The method in accordance with claim 3, wherein, after grafting the acrylic acid to the surface of the polyurethane layer, the acid groups are transformed into carboxylate groups through the action of a base.

12. The polyurethane layer formed by the process of claim 3.