Device for measuring chemical and physical parameters of a liquid or gaseous medium

• US 5,128,019 A
• Filed: 11/16/1989
• Issued: 07/07/1992
• Est. Priority Date: 12/01/1988
• Status: Expired due to Fees

• Current Assignee: AVL AG
• Original Assignee: Avl Medical Instruments AG (Roche Holding AG)
• Inventors: Jobstl, Ewald, Offenbacher, Helmut, Karpf, Hellfried, Kleinhappl, Erich, Marsoner, Hermann
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): BELL, BRUCE F
• Application Number:
  US07/437,202
• Time in Patent Office: 964 Days
• Field of Search: 204/416, 204/418, 204/419, 356/317, 356/318, 250/458.1, 250/459.1, 422/82.06, 422/82.07
• US Class Current: 204/416
• CPC Class Codes: G01N 21/251 Colorimeters; Construction thereof
• CPC Class Codes: G01N 21/7703 using reagent-clad optical fibres or optical waveguides using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B

Abstract

In order to reduce the measuring volume in a device for measuring chemical and physical parameters of liquid or gaseous media by means of optical sensor elements whose optodes may be replaced easily, a measuring unit with a sample channel is provided which may be inserted into a supporting frame of the device and which may be connected to ingoing and outgoing sample lines via capillary bores. The measuring unit contains a sensor carrier forming the boundary of the sample channel on one side, which sensor carrier has bores holding the optodes. The indicator film of each individual optode is situated in the plane of the sensor carrier facing the sample channel.

Claims

1. A device for measuring chemical and physical parameters of a fluid medium, said device comprising:

a supporting frame which is connectable to an input line for fluid medium and to an output line for fluid medium,

a measuring unit insertable into said supporting frame to define a sample channel for fluid medium flowing between said input line and said output line, said measuring unit comprising a sensor carrier defining a flat surface facing said sample channel and including a bore therethrough,

an optode having a indicator film positioned in said bore of said sensor carrier such that said indicator film is positioned in said plane of said sensor carrier and in communication with fluid medium flowing through said sample channel, and

means for optically exciting said indicator film of said optode and for detecting and evaluating optical signals emitted therefrom so as to measure chemical and physical parameters of said fluid medium.

2. A device according to claim 1, wherein said sensor carrier includes a plurality of bores therethrough;

including a plurality of optodes having indicator films which are respectively positioned in said bores of said sensor carrier such that said indicator films are positioned in said plane of said sensor carrier and in communication with fluid medium flowing through said sample channel; and

including means for optically exciting each indicator film of each optode and for detecting and evaluating optical signals emitted therefrom.

3. A device according to claim 2, wherein each of said individual optodes is provided with an optically transparent carrier element located in each of said bores of said sensor carrier, which elements end level with a plane of said sensor carrier facing away from said sample channel, and wherein an optical fiber connector is provided which comprises optical connections for each of said optodes, the ends of said optical connections are situated in a surface-polished plate being in contact with said sensor carrier.

4. A device according to claim 1, wherein said supporting frame is furnished with a spring-loaded coupling element in connection with said outgoing sample line, which centers said measuring unit and presses said measuring unit against a coupling element connected with said ingoing sample line, wherein sealing elements being arranged between said coupling elements and capillary bores connected with said sample channel, and wherein said spring-loaded coupling element, having a press lever releasing it.

5. A device according to claim 3, wherein said sensor carrier is configured as a corrosion-resistant metal disk in which said bores for said optodes are placed along the diameter of said metal disk, and wherein said optodes are sealed into said bores by means of an adhesive.

6. A device according to claim 5, wherein said metal disk consists of anodized aluminium and wherein said optodes are pH- and pO₂ - and pCO₂ -optodes.

7. A device according to claim 5, wherein a capillary gap is formed between each of said individual optodes and each of said bores in said sensor carrier, and wherein sealant is filled into at least one groove-shaped recess at the periphery of each of said bores extending almost as far as to said plane of said sensor carrier adjacent to said sample channel.

8. A device according to claim 6, wherein said pH-optode is covered by a sleeve containing said optically transparent carrier element and carrying in a circumferential groove a flexible fastening element for a protein-impermeable membrane covering the active area of said pH-optode, and wherein a capillary gap in said sensor carrier situated between said sleeve and said bore is packed with a sealant.

9. A device according to claim 8, wherein said protein-impermeable membrane is made of regenerated cellulose.

10. A device according to claim 8, wherein said sleeve is made of plastics material with memory effect, which is shrunk onto said optically transparent carrier element.

11. A device according to claim 10, wherein the side-wall of said sleeve facing said carrier element is covered with a thin layer whose refractive index is smaller than that of said carrier element.

12. A device according to claim 1, wherein said measuring unit is made of optically transparent material, and wherein an optical waveguide is provided in said supporting frame of said measuring unit for illuminating said sample channel.

13. A device according to claim 3, wherein said fiber connector is provided with a waveguide sleeve contained in a housing, said sleeve contains said optical connections for each of said optodes and has a front end which carries said surface-polished plate being in contact with said sensor carrier and wherein said waveguide sleeve is pressed against said sensor carrier at constant pressure by the force of a spring supported by said housing.

14. A device according to claim 13, wherein said optical fiber connector is provided with at least one heating element and a thermoelement for thermostat control of said sensor carrier in contact with said fiber connector.

15. A device according to claim 2, wherein said sample channel in said measuring unit is configured as a capillary groove extending over each of said indicator films of each of said individual optodes having an inlet opening angle α

and an outlet opening angle β and

wherein capillary bores opening into said sample channel are placed outside of the plane of said capillary groove and are connected to said capillary groove by short bores.

16. A device according to claim 15, wherein said inlet opening angle α

in the plane of said capillary groove is 10°

to 60°

, and the outlet opening angle β

is 10°

to 90°

.

17. A device according to claim 16, wherein said inlet opening angle α

is 15°

to 25° and

said outlet opening angle β

is 30°

to 60°

.

18. A device according to claim 15, wherein the width of said capillary groove is reduced to narrow passages between said individual optodes.

19. A device according to claim 15, wherein the flow past said individual optodes is asymmetric.

20. A device according to claim 15, wherein said sensor carrier is sealed into said measuring unit by means of a adhesive.