Method for rapid and uniform heating of a transparent and/or reflecting multilayer optical system with polymeric solid electrolyte

• US 5,130,842 A
• Filed: 02/21/1991
• Issued: 07/14/1992
• Est. Priority Date: 05/10/1989
• Status: Expired due to Fees

• Current Assignee: Societe Nationale Elf Aquitaine (Cook Composites and Polymers)
• Original Assignee: Societe Nationale Elf Aquitaine (Cook Composites and Polymers)
• Inventors: Muller, Daniel, Gauthier, Michel, Ricoux, Philippe
• Primary Examiner(s): Hille, Rolf
• Assistant Examiner(s): Ho, Tan
• Application Number:
  US07/635,521
• Time in Patent Office: 509 Days
• Field of Search: 350/353, 350/355, 350/357, 252/62.2, 252/600, 359/265, 359/270, 359/273, 359/275, 359/271, 204/130, 204/1.11, 219/219, 219/209
• US Class Current: 359/265
• CPC Class Codes: B29C 2035/0211 resistance heating B29C2035/0811 takes precedence
• CPC Class Codes: B29C 35/02 Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mouldcold vulcanisation B29C35/18 ; vulcanising tyres, presses therefor B29D30/0601
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 2310/022 Electrical resistance
• CPC Class Codes: B32B 37/06 characterised by the heating method
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
• CPC Class Codes: H01M 10/0565 Polymeric materials, e.g. gel-type or solid-type
• CPC Class Codes: H01M 10/615 Heating or keeping warm
• CPC Class Codes: H01M 10/6571 Resistive heaters arrangements for heating the battery by its resistance to the internal current H01M10/637
• CPC Class Codes: H01M 6/181 with polymeric electrolytes
• CPC Class Codes: H05B 2203/009 Heaters using conductive material in contact with opposing surfaces of the resistive element or resistive layer
• CPC Class Codes: H05B 2203/017 Manufacturing methods or apparatus for heaters
• CPC Class Codes: H05B 3/0004 Devices wherein the heating current flows through the material to be heated Circuit arrangements for heating by passing the current directly across the material to be heated H05B3/0023; granular, powdered or fluid material H05B3/60
• CPC Class Codes: H05B 3/146 Conductive polymers, e.g. polyethylene, thermoplastics
• CPC Class Codes: H05B 3/36 heating conductor embedded in insulating material
• CPC Class Codes: H05B 3/60 Heating arrangements wherein the heating current flows through granular powdered or fluid material, e.g. for salt-bath furnace, electrolytic heating H05B3/38 takes precedence
• CPC Class Codes: H05B 3/86 the heating conductors being embedded in the transparent or reflecting material H05B3/845 takes precedence
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The optical system, which is comprised of a thin layer of ion conducting, macromolecular material, or solid polymer electrolyte sandwiched between two electrodes presenting each a conducting deposition carried by a support plate such that at least one of the conductor depositions and the associated support plate are transparent, is heated by applying between the conductor depositions of said electrodes an electric voltage signal of which at least one portion includes an alternating component which has an amplitude between 0.05 and 100 volts and a frequency lower than 5 kHz and preferably between 2 and 2000 Hz so as to generate within said optical system an alternating ionic current susceptible of producing a heating of the ion conducting macromolecular material by Joule effect. The optical system to be heated, which may be an electrochromium device, may have particularly a glazing type structure or a mirror type structure.

Claims

1. A method for rapid and uniform heating of a transparent and/or reflecting multilayer optical system, said system comprising two electrodes between which is sandwiched a thin layer of an ion-conducting macromolecular material of polymeric solid electrolyte, especially a conductor of protons or of alkali metal ions, which is transparent in the thicknesses employed, these electrodes, on the one hand, being in direct contact with the layer of polymeric solid electrolyte to which they adhere strongly and, on the other hand, each comprising a current-conducting deposit which is in contact with one of the facing sides of two support plates situated on both sides of the said electrodes and at least one of the plates and the associated conducting deposit are transparent, the method comprising the steps of:

applying an electrical voltage signal between the conducting deposits of the electrodes of the optical system, at least part of which comprises an alternating component which has a frequency of less than 5 kHz and an amplitude, that is to say a difference between its maximum and means values, between 0.05 and 100 volts, and generating in the optical system as a result of the applied voltage an alternating ion current capable of producing a heating of the ion-conducting macromolecular material by Joule effect.

2. The method according to claim 1, wherein the frequency of the alternating component of the electrical voltage signal applied between the conducting deposits of the electrodes of the optical system is between 2 and 2000 Hz and is preferably between 10 and 500 Hz.

3. The method according to claim 1 or 2, wherein the amplitude of the alternating component of the electrical voltage signal applied between the conducting deposits of the electrodes of the optical system is between 0.05 and 30 volts.

4. The method according to claim 1, wherein the alternating component of voltage is selected from the group consisting of an uninterrupted signal and a noncontinuous signal.

5. The method according to claim 4, wherein the alternating component of voltage is a sinusoidal signal.

6. The method according to claim 1, wherein a temperature within the ion-conducting macromolecular material is monitored in order not to exceed a predetermined temperature, the said monitoring being carried out by at least one of employing an electrical voltage signal whose alternating component has a high constant effective value and by limiting the intensity of the alternating current generated, and keeping constant the intensity of the alternating current flowing in the ion-conducting material and by limiting the amplitude of the alternating component of the electrical voltage signal.

7. The method according to claim 1, wherein the thin layer of ion-conducting macromolecular material of the optical system has a thickness of between 5 μ

m and 2000 μ

m.

8. The method according to claim 1, wherein the ion-conducting macromolecular material has simultaneously an ionic conductivity of at least 10^-7 siemens/cm at room temperature and an electronic conductivity of less than 10^-10 siemens/cm.

9. The method according to claim 1, wherein the ion-conducting macromolecular material consists of a solid solution of at least one ionisable salt in a plastic polymeric material comprising at least one of one or more polymers and copolymers of monomers containing at least one heteroatom capable of forming bonds of the donor/acceptor type with the cation of the ionisable salt.

10. The method according to claim 9, wherein said at least one ionisable salt is an alkali metal salt.

11. The method according to claim 9, wherein said at least one ionisable salt is a lithium salt.

12. The method according to claim 9, wherein said at least one heteroatom is selected from the group consisting of oxygen and nitrogen.

13. The method according to claim 9, wherein said polymer(s) and copolymer(s) are polyethers.

14. The method according to claim 9, wherein said polymer(s) and copolymer(s) are selected from the group consisting of ethylene oxide homopolymers, propylene oxide homopolymers and copolymers of ethylene oxide and of at least one other cyclic ether.

15. The method according to claim 1, wherein the ion-conducting macromolecular material consists of a solid solution of an ionisable salt in a polymeric material chosen from organometallic polymers in which at least two polyether chains are linked by a metal atom selected from the group consisting of Al, Zn, Mg, Si, Cd, B and Ti or from polyphosphazenes carrying two polyether groups on each phosphorous atom.

16. The method according to claim 15, wherein said polymeric material is chosen from polyphosphazenes carrying two polyoxyethylene groups on each phosphorus atom.

17. The method according to claim 8, wherein the ion-conducting macromolecular material is chosen from mixtures of polymers of polar nature and/or solvating with any salt, acid or base sufficiently dissociated in the polymer to obtain the desired ion conductivity, the polymers carrying ionisable functional groups producing anions or cations attached to the macromolecular chains, polymeric protonic conductors and mixtures of inert polymers with inorganic or organic ion-conducting materials dispersed in the polymeric matrix.

18. The method according to claim 1, wherein the current-conducting transparent deposit which at least one of the electrodes of the optical system comprises is based on tin oxide.

19. The method according to claim 18, wherein the current-conducting transparent deposit which at least one of the electrodes of the optical system includes comprises a member selected from the group consisting of mixed tin indium oxide, mixed tin cadmium oxide, tin oxide doped with antimony oxide and tin oxide doped with fluorine.

20. The method according to claim 1, wherein the optical system to be heated is such that each of its electrodes is made up of a current-associated with each conducting deposit is made of an inorganic or organic transparent material, the said optical system forming a window-type structure.

21. The method according to claim 1, wherein the optical system to be heated is such that one of its electrodes is made up of a current-conducting transparent deposit, the associated support plate being made of an inorganic or organic transparent material, and the other electrode comprises a conductor made of a current-conducting material and capable of forming a reflecting surface.

22. The method according to claim 21, wherein said current-conducting material is a metal selected from the group consisting of Ag, Al, Ni, Li, Cr and stainless steel.

23. The method according to claim 1, wherein at least one of the electrodes of the optical system contains a material, called an electrochromic material, which is placed facing the layer of ion-conducting macromolecular material and in which the insertion or the deinsertion of ions results in a change in at least one of the light absorption and reflection spectrum of the said electrochromic material, the said optical system forming the electrochromic system.

24. The method according to claim 23, wherein the material whose at least one of light absorption and reflection spectrum changes owing to insertion or deinsertion of ions is based on a transition metal oxide or on a mixture or a solid solution of transition metal oxides.

25. The method according to claim 23 or 24, wherein an electrical voltage which is the resultant of the alternating component of heating voltage and of a voltage which has a value equal to the voltage for controlling the electrochromic system is applied between the conducting deposits of the electrochromic system.

26. The methods according to claim 25, wherein the said voltages are applied either simultaneously and separately or in the form of a single voltage resulting from the superposition of the said voltages.

27. The method according to claim 24, wherein the inserted or deinserted ions are selected from the group consisting of alkali metal ions and protons.

28. The method according to claim 23, wherein the electrochromic material inserts or deinserts ions selected from the group consisting of alkali metal ions and protons.

29. The method according to claim 25, wherein the electrochromic system to be heated is such that the current-conducting deposit which each of its electrodes comprises is transparent and that the support plate associated with each current-conducting deposit is made of an inorganic or organic transparent material, the said electrochromic system forming a window-type structure.

30. The method according to claim 23, wherein the electrochromic system to be heated is such that the conducting deposit which one of its electrodes comprises is transparent, the associated support plate being made of an inorganic or organic transparent material, and the current-conductor which the other electrode comprises is made of a current-conducting material capable of forming a reflecting surface.

31. The method according to claim 30, wherein said current-conducting material is a metal selected from the group consisting of Ag, Al, Ni, Li, Cr and stainless steel.