Method for continual monitoring and treating a hydrocarbon oil stream

• US 5,132,225 A
• Filed: 06/14/1991
• Issued: 07/21/1992
• Est. Priority Date: 04/15/1985
• Status: Expired due to Term

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Dickakian, Ghazi B.
• Primary Examiner(s): Housel, James C.
• Assistant Examiner(s): REDDING, DAVID A
• Application Number:
  US07/715,329
• Time in Patent Office: 403 Days
• Field of Search: 436/53, 436/60, 436/139, 436/162, 73/61.1 C, 73/61.4, 73/64, 73/61.2, 208/48 AA, 208/309
• US Class Current: 436/60
• CPC Class Codes: G01N 30/90 Plate chromatography, e.g. thin layer or paper chromatography
• CPC Class Codes: G01N 30/95 Detectors specially adapted therefor; Signal analysis
• CPC Class Codes: G01N 33/2805 investigating the resistance to heat or oxidation to the weather, to corrosion, or to light G01N17/00
• CPC Class Codes: Y10T 436/21 Hydrocarbon

Abstract

Samples of a petroleum oil stream (e.g. crude oil feed stream to a refinery) are continually monitored to determine incompatible asphaltenes therein and the rate of antifoulant is adjusted in response to changes in the level of incompatible asphaltenes. The method of the present invention employs thin layer chromatographic films for separating incompatible asphaltenes and for measuring an optical property indicative of the incompatible asphaltenes, and for varying antifoulant addition in response to changes of the optical property measured.

Claims

1. A method of treating a crude oil stream containing incompatible fouling asphaltenes wherein an antifoulant is introduced into said stream which comprises

(a) continually obtaining a sample from said stream at frequent time intervals;

(b) for each sample obtained measuring a property of the sample which is indicative of the incompatible asphaltenes therein; and

(c) adjusting the introduction of the antifoulant in response to changes in the level of incompatible asphaltenes in the samples as indicated in step (b).

2. The method of claim 1 wherein the sample is first mixed with an antisolvent before measurement of said property.

3. the method as defined in claim 1 wherein the measuring step comprises

(i) depositing a portion of each sample of the oil stream onto a surface of a thin film made up of a chromatographic separation material;

(ii) letting the sample of the liquid hydrocarbon migrate

(iii) letting the sample of liquid hydrocarbon migrate radially outward within said film for sufficient time so that hydrocarbon compatible fractions in the same separate from any hydrocarbon-incompatible asphaltenes in the sample, wherein said hydrocarbon compatible fractions form a matrix portion in the film and any hydrocarbon-incompatible fractions form a dark ring within the matrix portion and wherein any ring formed is disposed within a central region of the matrix portion and is distinguished from the matrix portion by a dark area having a boundary with respect to a lighter area; and

(iv) determining the tendency of the liquid hydrocarbon stream to foul equipment by comparing the matrix portion with any dark ring formed from any hydrocarbon-incompatible asphaltenes in the sample, wherein the area and intensity of any ring formed in relation to the matrix portions provides an indication of the tendency of the liquid hydrocarbon stream to foul equipment.

4. The method of claim 3 wherein the film is a polymeric membrane capable of chromatographic separation of incompatible asphaltenes from compatible components of the sample.