Electrolytic storage cell monitoring system

• US 5,132,626 A
• Filed: 05/31/1989
• Issued: 07/21/1992
• Est. Priority Date: 05/31/1989
• Status: Expired due to Term

• Current Assignee: Serveron Corporation (Fortive Corp.)
• Original Assignee: Amoco Corporation (BP PLC)
• Inventors: Limuti, Donald, Churchill, Thomas L., Ross, James M. Jr.
• Primary Examiner(s): Weider, Kenneth A.
• Assistant Examiner(s): Regan, Maura K.
• Application Number:
  US07/359,642
• Time in Patent Office: 1,147 Days
• Field of Search: 324/430, 324/432, 324/434, 324/204, 324/425, 324/650, 324/663, 324/671, 324/687, 340/636, 73/32 R, 73/304 R, 73/304 C, 73/313, 73/290 R
• US Class Current: 324/432
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 10/484 for measuring electrolyte level, electrolyte density or electrolyte conductivity
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Nonintrusive sensors capable of measuring various storage cell parameters such as voltage, state-of-charge, electrolyte level, internal resistance, and temperature are attached to a monitoring module which gathers and processes signals representative of information concerning the condition of electrolytic storage cells and transmits the information to a central computer for further processing. In response to commands issued by the central computer, appropriate maintenance and/or repair operations can be initiated. Alternatively, the system described can be used to automatically perform such maintenance tasks as checking and adding electrolyte levels, reducing the voltage in cells whose output voltage is too high, and leveling the state-of-charge of each cell in an array of electrolytic storage cells. The system can monitor other functions of the electrolytic storage cells, including the evolution of hydrogen gas and the accumulation of sediments in individual electrolytic storage cells.

Claims

1. A system for monitoring electrolytic parameters of one or more electrolytic storage cells, each storage cell including a plurality of conductive metal plates immersed in an electrolyte, comprising:

a monitoring module associated with each storage cell, each monitoring module having;

a. one or more sensors attached to the associated storage cell,

b. means for making a measurement of the complex impedance of each of the attached sensors at a single predetermined frequency, the complex impedance being a function of frequency and at least one of the electrolytic parameters of the associated storage cell, and

c. means for producing signals representative of the electrolytic parameters of the associated storage cell from the measurement of the complex impedance of each attached sensor at the single predetermined frequency;

means for addressing each monitoring module to collect the signals representative of the electrolytic parameters of each storage cell; and

means for processing the collected signals to monitor the electrolytic parameters of each storage cell.

2. The system of claim 1 wherein the one or more sensors include a sensor for detecting the level of an electrolyte in the associated storage cell.

3. The system of claim 2 wherein the sensor for detecting the level of an electrolyte in the associated storage cell includes a plurality of capacitive sensors, some of the capacitive sensors being above the level of the electrolyte and some of the capacitive sensors being below the level of the electrolyte.

4. The system of claim 3 wherein the capacitors are linearly arranged and each capacitor is connected in parallel to an inductor, thereby forming a resonant circuit having a complex impedance that is dependent upon the level of the electrolyte in the associated storage cell.

5. The system of claim 2 wherein the sensor for detecting the level of an electrolyte in the associated storage cell comprises a first inductive coil placed adjacent the associated storage cell so that at least a portion of the first inductive coil is below a plane defined by the level of the electrolyte.

6. The system of claim 5 wherein the means for detecting the level of an electrolyte comprises a first inductive coil placed adjacent the associated storage cell so that at least a portion of the first inductive coil is below a plane defined by the level of the electrolyte.

7. The system of claim 6, wherein another one of the one or more sensors comprises a second inductive coil for detecting the specific gravity of the electrolyte, the second inductive coil being placed adjacent the associated storage cell so that the second inductive coil is below the plane defined by the level of the electrolyte.

8. The system of claim 5 wherein the means for detecting the level of an electrolyte comprises a first inductive coil placed adjacent the associated storage cell so that at least a portion of the first inductive coil is below a plane defined by the level of the electrolyte and another one of the one or more sensors comprises a second inductive coil for detecting the specific gravity of the electrolyte, the second inductive coil being placed adjacent the associated storage cell so that the second inductive coil is below the plane defined by the level of the electrolyte.

9. The system of claim 1 wherein the one or more sensors includes a sensor for detecting the specific gravity of an electrolyte in the associated storage cell.

10. The system of claim 1 wherein the one or more sensors includes a sensor for detecting the state-of-charge of the associated storage cell.

11. The system of claim 10 wherein the means for detecting the state-of-charge includes a multi-turn planar coil lying substantially in a horizontal plane that intersects the plurality of conductive metal plates and the electrolyte of the associated storage cell below its surface.

12. The system of claim 10 wherein the state-of-charge sensing means comprises means for generating a charge pulse, means for applying the charge pulse to the associated storage cell, and means for generating a signal indicating the response of the associated storage cell to the charge pulse.

13. The system of claim 1 wherein the one or more sensors includes a circuit for measuring the voltage, the internal resistance, the temperature, the resistance of the external connections, and the current passing through the associated storage cell.

20. The system of claim 1 wherein one of said one or more sensors comprises means for detecting the level of an electrolyte in the associated storage cell.

21. The system of claim 20 wherein the means for detecting the levle of an electrolyte comprises a first inductive coil placed adjacent the associated storage cell so that at least a portion of the first inductive coil is below a plane defined by the level of the electrolyte.

22. The system of claim 21, wherein another one of the one or more sensors comprises a second inductive coil for detecting the specific gravity of the electrolyte, the second inductive coil being placed adjacent the associated storage cell so that the second inductive coil is below the plane defined by the level of the electrolyte.

23. The system of claim 1 wherein the means for detecting the levle of an electrolyte in the associated storage cell includes a plurality of capacitive sensors.

14. A system for monitoring electrolytic parameters of one or more electrolytic storage cells, comprising:

a monitoring module attached to each storage cell, each monitoring module having;

a. means for generating a signal including at least a single predetermined frequency,

b. a sensor attached to the associated storage cell,

c. means for coupling the signal to the sensor,

d. means for making a measurement of the complex impedance of the sensor at the single predetermined frequency, the complex impedance being a function of frequency and at least one of the electrolytic parameters of the associated storage cell, and

e. means for producing signals representative of the electrolytic parameters of the associated storage cell from the measurement of the complex impedance of each attached sensor at the single predetermined frequency;

means for addressing each monitoring module to collect the signals representative of the electrolytic parameters of each storage cell; and

means for processing the collected signals to monitor the electrolytic parameters of each storage cell.

15. The system of claim 14 wherein the means for measuring the complex impedance of the sensor is an inductive means attached to the associated storage cell.

16. The system of claim 14 wherein the monitoring module further includes means for sensing the specific gravity of the associated storage cell.

17. The system of claim 14 wherein the monitoring module further comprises means for sensing the state-of-charge of the associated storage cell.

18. The system of claim 17 wherein the state-of-charge sensing means comprises means for generating a charge pulse, means for applying the charge pulse to the associated storage cell, and means for generating a signal indicating the response to the associated storage cell to the charge pulse.

19. A system for monitoring electrolytic parameters of one or more electrolytic storage cells including a plurality of conductive metal plates immersed in an electrolyte, comprising:

a monitoring module attached to each storage cell, each monitoring module having;

a. means for generating a signal including at least a single predetermined frequency,

b. coupling means for coupling the signal into each storage cell,

c. a sensor attached to the associated storage cell,

d. means for measuring the complex impedance of the sensor at the single predetermined frequency, the complex impedance being a function of the electrolytic parameters of the associated storage cell,

e. means for producing signals representative of the electrolytic parameters of the associated storage cell; and

f. means for sensing the state-of-charge of the associated storage cell, including a multi-turn planar coil lying substantially in a horizontal plane that intersects the plurality of conductive metal plates and the electrolyte of the associated storage cell below its surface;

means for addressing each monitoring module to collect the signals representative of the electrolytic condition of each storage cell; and

means for processing the collected signals to monitor the condition of each storage cell.