Ink composition containing fluorescent component and method of tagging articles therewith

• US 5,135,569 A
• Filed: 08/24/1990
• Issued: 08/04/1992
• Est. Priority Date: 08/24/1990
• Status: Expired due to Fees

• Current Assignee: W R Grace & Company - CONN (Standard Industries Holdings, Inc.)
• Original Assignee: W R Grace & Company - CONN (Standard Industries Holdings, Inc.)
• Inventors: Mathias, Eckart
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): KLEMANSKI, HELENE G
• Application Number:
  US07/573,087
• Time in Patent Office: 711 Days
• Field of Search: 106/19, 106/20, 106/21, 106/22, 252/301.16
• US Class Current: 106/31.32
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks

Abstract

Provided is an ink composition which comprises a fluorescent dye. The ink composition is useful in tagging for subsequent identification various articles having a polymeric or porous organic or inorganic surface. The ink composition comprises a non-fluorescent ink such as a black ink, a fluorescent dye, and a solvent for the fluorescent dye, which solvent swells and impregnates the surface of the article thereby permitting impregnation of the article by the fluorescent dye. The resulting tagged article has a printed surface with a fluorescent dye impregnated within the article directly beneath the printing on the surface. Identification of the article can then take place by removing printed material, and subjecting the article to UV irradiation. Observing a bright fluorescent color characteristic of the fluorescent dye used confirms the authenticity of the article.

Claims

1. An ink composition which comprises

(i) a fluorescent dye;

(ii) a non-fluorescing ink which masks the presence of the fluorescent dye so that fluorescence is not observed;

(iii) a solvent for the fluorescent dye which permits the fluorescent dye to impregnate the surface of a substrate, while allowing the non-fluorescing ink to remain substantially on the surface of the substrate.

2. The ink composition of claim 1, wherein said non-fluorescing ink is a black ink.

3. The ink composition of claim 2, wherein the solvent comprises a mixture of ketones.

4. The ink composition of claim 2, wherein the solvent comprises diethylketone.

5. The ink composition of claim 1, wherein the fluorescent dye fluoresces with a blue/white, orange or green color.

6. The ink composition of claim 1, wherein the solvent comprises a ketone, chlorinated hydrocarbon, aromatic hydrocarbon, an ester or an ether.

7. The ink composition of claim 1, wherein the solvent comprises a ketone.

8. The ink composition of claim 1, wherein the solvent comprises diethylketone.

9. The ink composition of claim 1, wherein the solvent for the fluorescent dye comprises a mixture of solvents.

10. The ink composition of claim 1 wherein the fluorescent dye is a sulfuric acid disodium salt mixture with 7-(diethylamino)-4-methyl-2H-1-benzopyran-2-one;

3'"'"',6'"'"'-bis(diethylamino)spiro(isobenzofuran-1(3H)-9'"'"'-(9H)xanthen)-3-one;

4-amino-N-2,4-xylyl-naphthalimide;

7-(diethylamino)-4-methyl-coumarin;

14H-anthra[2,1,9-mna]thioxanthen-14-one;

or, N-butyl-4-(butylamino)-naphthalimide.

11. The ink composition of claim 1, wherein the amount of fluorescent dye ranges from about 0.01% to about 15% by weight.

12. The ink composition of claim 1, wherein the amount of fluorescent dye ranges from about 1.0% to about 7% by weight.

13. The ink composition of claim 1, wherein the amount of solvent for fluorescent dye present ranges from about 5 to about 15% by weight.

14. The ink composition of claim 1 wherein the amount of fluorescent dye is about 0.01% to 15% by weight and the amount of solvent for the fluorescent dye is about 5 to 15% by weight.