Method of impregnating reticulated foam with polymide foam and products thereof

• US 5,135,959 A
• Filed: 05/20/1991
• Issued: 08/04/1992
• Est. Priority Date: 05/20/1991
• Status: Expired due to Fees

• Current Assignee: Sorrento Engineering Incorporated
• Original Assignee: Sorrento Engineering Incorporated
• Inventors: Hill, Francis U.
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US07/702,952
• Time in Patent Office: 442 Days
• Field of Search: 521/52, 521/54, 521/184, 521/185, 521/137, 521/139, 521/134, 264/51
• US Class Current: 521/54
• CPC Class Codes: B29C 44/5618 Impregnating foam articles
• CPC Class Codes: B29C 67/202 comprising elimination of a solid or a liquid ingredient
• CPC Class Codes: C08J 2201/046 Elimination of a polymeric phase
• CPC Class Codes: C08J 2479/00 Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2461/00 - C08J2477/00
• CPC Class Codes: C08J 9/26 by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
• CPC Class Codes: C08J 9/405 with polymerisable compounds

Abstract

A method of forming complex polyimide foam shapes by impregnating a low density, open cell, reticulated form with polymide foam precursor, placing the combination in a mold, closing the mold, then heating the assembly to the foaming and curing temperatures of the precursor. As the powdered precursor expands, it spreads throughout the reticulated foam producing a product having substantially uniform density and polyimide foam characteristics. If desired, the reticulated foam can be removed from the product by using a material that outgasses and boils away at polyimide processing temperatures. Radar absorbing materials may be incorporated in the reticulated foam so that the final product will have uniformly distributed radar absorbing components with the desirable high temperature resistance and other properties of polyimide foams.

Claims

1. The method of making complex polyimide foam products which comprises the steps of:

providing a reticulated foam shape having substantially the dimensions of the intended polyimide foam product;

impregnating said reticulated foam with a polyimide foam precursor;

heating said impregnated reticulated foam in a substantially closed mold to the foaming temperature of the polyimide foam precursor;

further heating the resulting assembly to the curing temperature of said polyimide foam for a time sufficient for substantially complete cure;

said reticulated foam material having a vaporization temperature below the degradation temperature of the cured polyimide foam; and

heating said assembly to a temperature above the vaporization temperature of said reticulated foam material but below the degradation temperature of said cured polyimide foam;

whereby said reticulated foam is substantially eliminated.

2. The method according to claim 1 wherein reticulated foam has the maximum open volume.

3. The method according to claim 1 including the further step of adhesively bonding a plurality of finely divided particles to said reticulated foam prior to impregnation of said reticulated foam with said polyimide foam precursor.

4. The method according to claim 3 wherein said particles are inorganic microwave absorbing particles.

5. The method according to claim 4 wherein said particles are selected from the group consisting of metal, ferrite, carbon and mixtures thereof.

6. The method according to claim 1 wherein said polyimide precursor is impregnated into said reticulated foam by spreading finely powdered dry polyimide precursor particles over the surface of said reticulated foam.

7. The method according to claim 1 wherein said polyimide precursor is impregnated into said reticulated foam by dipping said reticulated foam into a viscous liquid polyimide precursor.

8. The method according to claim 7, further including the step of squeezing out excess liquid polyimide precursor.

9. The method according to claim 8 further including the step of drying said liquid polyimide precursor prior to foaming of the precursor.

10. The method according to claim 1 wherein said mold is closed during foaming only sufficiently to prevent leaking of foam from the mold while permitting exit of gases therefrom.