Optical spectral analysis apparatus

• US 5,137,364 A
• Filed: 01/31/1991
• Issued: 08/11/1992
• Est. Priority Date: 01/31/1991
• Status: Expired due to Fees

• Current Assignee: Cornelius J. Mccarthy
• Original Assignee: Cornelius J. Mccarthy
• Inventors: McCarthy, Cornelius J.
• Primary Examiner(s): EVANS, FANNIE L
• Application Number:
  US07/648,798
• Time in Patent Office: 558 Days
• Field of Search: 356/402, 356/405, 356/406, 356/407, 356/416, 356/419, 356/425, 250/226, 364/526
• US Class Current: 356/402
• CPC Class Codes: G01J 2003/467 Colour computing
• CPC Class Codes: G01J 3/02 Details
• CPC Class Codes: G01J 3/0218 using optical fibers
• CPC Class Codes: G01J 3/50 using electric radiation detectors
• CPC Class Codes: G01J 3/501 Colorimeters using spectrally-selective light sources, e.g. LEDs
• CPC Class Codes: G01J 3/524 Calibration of colorimeters
• CPC Class Codes: G01N 21/255 Details, e.g. use of specially adapted sources, lighting or optical systems
• CPC Class Codes: G01N 2201/0826 Fibre array at source, distributing
• CPC Class Codes: G01N 2201/0833 Fibre array at detector, resolving

Abstract

Apparatus for low cost measurement of light energy in terms of multiple spectral integrations with differing wavelength-dependent weights for consistency of measurements in spite of variations in component characteristics or temperature.

Claims

1. Optical spectral analysis apparatus for measurements of optical properties of a sample which comprises a plurality of sources of radiant energy, a plurality of devices for the conversion of radiant energy in to electrical signals, means in each of said sources for providing a spectrum of energy with reference to wavelength which said spectrum is different from said spectrum of the others of said sources, means in each of said devices for providing a response to radiant energy as a function of wavelength which differs from the response to radiant energy for each of the others of said devices, and means for operating said apparatus by first providing electrical energy to each said source of radiant energy, for each of distinct periods of time during which said periods of time at least one of the other sources of radiant energy is not provided with electrical energy, and second allowing or directing radiant energy produced by said sources to interact with the sample in such a fashion that some radiant energy reflected from and/or transmitted by and/or emitted by said sample is returned to said devices, and third recording the electrical signals from each said device for the conversion of radiant energy to electrical signal output during each such said period of time, and fourth calculating from each said recorded electrical signal output a value which is a weighted integration of radiant energy over wavelength, thus producing a set of said weighted integration values whose number is equal to the product of the number of said distinct time periods with the number of said devices for the conversion of radiant energy to electrical signal, and fifth calculating from said set of weighted integration values said set of multiple measurements by linear transformation of said set of weighted integration values utilizing predetermined coefficients for transformation.

2. Apparatus as per claim 1 wherein said sources are electrical to radiant energy conversion devices.

3. Apparatus as per claim 2 in wherein at least two of said devices are light emitting diodes.

4. Apparatus per claim 1 in which said sources of radiant energy and said devices for the conversion of radiant energy to electrical signal are mounted on a common substrate, which substrate provides mechanical positioning, electrical connections, and a common thermal contact.

5. Apparatus per claim 4 in which an electrical device sensitive to temperature is also mounted in thermal contact with said substrate.

6. Apparatus per claim 5 in which a device for the creation or removal of heat energy is in thermal contact with said substrate.

7. Apparatus per claim 4 in which said sources of radiant energy, and devices, and common substrate are sealed with a material which is transparent to light energy of the wavelengths of interest in the measurements performed, but impervious to moisture.

8. Apparatus per claim 1 in which said operations means have means for computing said coefficients of said linear transformation at the time of manufacture of said apparatus by recording a set of observed weighted integrations for each of a number of objects or materials with established optical characteristics, and calculating the coefficients of the linear transformation using techniques of multiple regression.

9. Apparatus per claim 8 in which a plurality of sets of said coefficients are computed each said set being determined while said apparatus is maintained at a temperature different from the temperature maintained during the determination of each other said set, and said operating means having means for the selection of a particular set of coefficients from said plurality of sets as a function of temperature.

10. Apparatus per claim 9 in which said operating means includes means for the selection of said coefficients of linear transformation as a function of temperature by interpolation between said sets of coefficients.

11. Apparatus per claim 1 in which radiation is directed to said sample from said sources by multiple optical fibers, which fibers have a core diameter which is at least 90% of their clad diameter.

12. Apparatus per claim 1 in which radiation is directed from the sample to said devices for the conversion of radiant energy to electrical signal by optical fibers.

13. Apparatus per claim 11 in which said optical fibers are rigidly positioned.

14. Apparatus per claim 11 in which a plurality of semiconductor chips, provide said sources of radiant energy and said devices said chips being in physical contact with said optical fibers.

15. Apparatus for the determination of multiple measurements of radiant energy emitted by a sample comprising multiple devices for the conversion of radiant energy to electrical signal, means for optical coupling said devices to said sample, means in said multiple devices for the conversion of radiant energy to electrical signals so that each said device for the conversion of radiant energy to electrical signal has a response to optical energy as a function of wavelength which differs from the response to radiant energy for the other of said devices, and means for operating said apparatus including first means for observing and recording the electrical output of each of said devices for the conversion of radiant energy to electrical signal, second means for calculating from each said recorded electrical output a value which is a weighted integration of radiant energy over wavelength to produce a set of weighted integration values, and third means for calculating from such set of said weighted integration values said set of multiple measurements by linear transformation with pre-determined coefficients of such set of weighted integration values.

16. Apparatus per claim 15 in which said devices for the conversion of radiant energy to electrical signal are mounted on a common substrate, which substrate provides mechanical positioning, electrical connections, and a common thermal contact.

17. Apparatus per claim 16 in which an electrical device sensitive to temperature is also mounted in thermal contact with said substrate.

18. Apparatus per claim 17 in which a device for the creation or removal of heat energy is in thermal contact with said substrate.

19. Apparatus per claim 16 in which said devices and common substrate are sealed with a material which is transparent to light energy of the wavelengths of interest in the measurements performed, but impervious to moisture.

20. Apparatus per claim 15 in which said operating means includes means for computing the coefficients of said linear transformation operation at the time of manufacture of said apparatus by recording a set of observed weighted integrations for each of a number sources with established optical characteristics and calculating the coefficients of the linear transformation using techniques of multiple regression.

21. Apparatus per claim 20 wherein said computing means including means for computing a plurality of sets of said coefficients, each of said sets while said apparatus is maintained at a temperature different from the temperature maintained during the computing of each other set, and means for incorporating into said third means a particular set of coefficients from said plurality of sets as a function of temperature at which said apparatus is operating.

22. Apparatus per claim 21 in which said operating means includes means for the selection of said coefficients of linear transformation as a function of temperature by interpolation between said sets of coefficients.

23. Apparatus per claim 15 in which radiation is directed from said sample to said devices by multiple optical fibers, which fibers have a core diameter which is at least 90% of their clad diameter.

24. Apparatus per claim 23 in which said optical fibers are rigidly positioned.