Cosmetic compositions for dyeing and for bleaching hair
First Claim
Patent Images
1. A storage stable alkaline cosmetic composition for dyeing or bleaching hair, said composition being dilutable with an oxidizing solution and comprising in an aqueous medium(a) at least one fatty acid soap present in an amount ranging from 1 to 25 weight percent based on the total weight of said composition, said fatty acid soap being selected from the group consisting of alkali metal salt of a C12 -C18 fatty acid containing a saturated or unsaturated fatty chain, an alkanolamine salt of a C12 -C18 fatty acid containing a saturated or unsaturated fatty chain and mixtures thereof,(b) at least one cationic or amphoteric silicone polymer present in an amount ranging from 0.05 to 5 weight percent based on the total weight of said composition, said cationic or amphoteric silicone polymer being selected from the group consisting of (i) a polysiloxane in which at least one silicon atom in the chain carries an aliphatic amino group, and amine group of which is primary, secondary, tertiary or quaternary, (ii) a polysiloxane in which at least one silicon atom in the chain carries an aliphatic amino group, the amine group of which has the betaine structure and (iii) a mixture of (i) and (ii);
- (c) at least one cationic surfactant present in an amount ranging from 0.05 to 5 weight percent based on the total weight of said composition, said cationic surfactant being a compound having the formula ##STR36## and being selected from the group consisting of (1) a compound of formula IV wherein R5 and R6 represent methyl and R7 and R8 have the following meanings(i) R7 and R8 represent a linear aliphatic radical containing from 12 to 22 carbon atoms, an aliphatic radical derived from tallow fatty acids and containing 14 to 22 carbon atoms, or(ii) R7 represents a linear aliphatic radical containing 14-22 carbon atoms and R8 represents methyl or benzyl, or(iii) R7 represents an alkylamidopropyl radical wherein the alkyl moiety has 14-22 carbon atoms and R8 represents an alkylacetate group wherein the alkyl moiety has 12-16 carbon atoms, or(iv) R7 represents a gamma-gluconamidopropyl radical, an aliphatic radical derived from tallow fatty acids or a C16 -C18 alkyl radical, and R8 represents hydroxyethyl, andX.sup.⊖
represents an anion,(2) a compound of formula IV whereinR5 represents alkylamidoethyl, alkenylamidoethyl or a mixture thereof, said alkyl moiety containing 14-22 carbon atoms and originating from tallow fatty acids and said alkenyl moiety containing 14-22 carbon atoms and originating from tallow fatty acids, andR6 and R7 together with the nitrogen atom to which they are attached form a 2-alkyl-4,5-dihydroimidazole heterocycle ring wherein the alkyl moiety is derived from tallow fatty acids,R8 represents methyl andX.sup.⊖
represents a methosulphate ion, and(3) a compound of formula IV wherein R5, R6, and R7 form with the nitrogen atom to which they are attached a six membered aromatic heterocyclic ring,R8 represents a C14 -C18 alkyl radical andX.sup.⊖
represents a halide anion;
(d) at least one alkalizing agent present in an amount sufficient such that the pH of said composition is higher than 7, said alkalizing agent being selected from sodium hydroxide, potassium hydroxide, aqueous ammonia and an alkanolamine;
(e) at least one cationic polymer present in an amount ranging from 0.05 to 5 weight percent based on the total weight of said composition, said cationic polymer being selected from the group consisting of;
(1) a quaternary polyammonium polymer selected from the group consisting of (a) a polymer consisting of repeating units of the formula ##STR37## wherein (i) R1, R2, R3 and R4, each independently, represent an aliphatic, alicyclic or arylaliphatic radical containing 1-20 carbon atoms or a C1 -C6 hydroxyaliphatic radical, or(ii) R1 and R2 and R3 and R4, together or separately, form with the nitrogen atoms to which they are attached a heterocyclic ring or a heterocyclic ring containing a second heteroatom other than nitrogen, or(iii) R1, R2, R3 and R4 represent a linear or branched C2 -C6 alkyl group substituted by a nitrile group, an ester group, an acyl group, an amide group, a group of the formula ##STR38## or a group of the formula ##STR39## wherein R'"'"'7 represents alkylene and D represents a quaternary ammonium group,A and B represent a linear or branched, saturated or unsaturated polymethylene group containing 2 to 20 carbon atoms or a linear or branched saturated or unsaturated polymethylene group containing 2 to 20 carbon atoms and containing in the main chain one or more of an aromatic ring, an oxygen atom, a sulphur atom, a sulphoxide group, a sulphone group, a disulphide group, an amine group, an alkylamine group, a quaternary ammonium group, a hydroxyl group, a ureido group, an amide group or an ester group, orA and R1 and R3 together with the two nitrogen atoms to which they are attached form a piperazine ring,X.sup.⊖
is an anion derived from an inorganic or organic acid, andn is such that the molecular weight of the polymer ranges from 1,000 to 100,000 and(b) a polymer consisting of repeating units of the formula ##STR40## wherein R4, R5, R6 and R7, each independently represent hydrogen, methyl, ethyl, propyl, 2-hydroxyethyl, 2-hydroxypropyl, or --CH2 --CH2 --(O--CH2 --CH2)p --OH wherein p is 0 or an integer ranging from 1 to 6, with the proviso that R4, R5, R6 and R7 do not simultaneously represent hydrogen,x and y, each independently, represent integers ranging from 1 to 6,m is 0 or an integer ranging from 1 to 34,X is a halogen atom, andA is a divalent group having the formula, --CH2 --CH2 --O--CH2 --CH2 --;
(2) a vinylpyrrolidone/dialkylaminoalkyl acrylate quaternized or not;
(3) a vinylpyrrolidone/dialkylaminoalkyl methacrylate quaternized or not;
(4) poly (methacrylamidopropyltrimethyl ammonium chloride);
(5) a cationic protein which is a chemically modified polypeptide bearing amine or quaternary ammonium groups at the end of the chain or grafted onto the chain;
(6) a polyaminoamide selected from the group consisting of(i) a water soluble polyaminoamide obtained by condensation of an acidic compound with a polyamine,(ii) a crosslinked water soluble polyaminoamide obtained by condensation of an acidic compound with a polyamine,(iii) an alkylated water soluble polyaminoamide obtained by condensation of an acidic compound with a polyamine,(iv) a polyaminoamide resulting from the condensation of a polyalkylenepolyamine with a polycarboxylic acid and alkylated with a difunctional agent, and(v) a polyaminoamide obtained by reacting a polyalkylenepolyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid, the molar ratio between the said polyalkylenepolyamine and the said dicarboxylic acid being between 0.8/1 and 1.4/1, the resulting polyaminoamide being reacted with epichlorohydrin, the molar ration of epichlorohydrin to the secondary amine groups of the polyaminoamide being between 0.5/1 and 1.8/1;
a crosslinked polyaminoamide;
an alkylated polyaminoamide; and
mixtures thereof.
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Abstract
Composition for dyeing or bleaching hair, to be mixed with an oxidizing solution at the time of use and containing:
(a) a fatty acid soap,
(b) a cationic or amphoteric silicone polymer,
(c) a cationic surface agent,
(d) an alkalifying agent, and
(e) a cationic polymer chosen from quaternary polyammonium polymers, quaternized or unquaternized vinylpyrrolidone/dialkylaminoalkyl acrylate or methacrylate copolymers, poly(methacrylamidopropyltrimethylammonium chloride), cationic proteins and polyaminoamides which may crosslinked or alkylated.
When these compositions are intended for dyeing hair, they also contain oxidation dye precursors and, if desired, couplers, as well as a reducing agent.
This composition, which foams slightly, allows a very easy distribution throughout the hair and it improves the cosmetic properties of the hair, especially its disentangling, and imparts a silky feel thereto.
82 Citations
27 Claims
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1. A storage stable alkaline cosmetic composition for dyeing or bleaching hair, said composition being dilutable with an oxidizing solution and comprising in an aqueous medium
(a) at least one fatty acid soap present in an amount ranging from 1 to 25 weight percent based on the total weight of said composition, said fatty acid soap being selected from the group consisting of alkali metal salt of a C12 -C18 fatty acid containing a saturated or unsaturated fatty chain, an alkanolamine salt of a C12 -C18 fatty acid containing a saturated or unsaturated fatty chain and mixtures thereof, (b) at least one cationic or amphoteric silicone polymer present in an amount ranging from 0.05 to 5 weight percent based on the total weight of said composition, said cationic or amphoteric silicone polymer being selected from the group consisting of (i) a polysiloxane in which at least one silicon atom in the chain carries an aliphatic amino group, and amine group of which is primary, secondary, tertiary or quaternary, (ii) a polysiloxane in which at least one silicon atom in the chain carries an aliphatic amino group, the amine group of which has the betaine structure and (iii) a mixture of (i) and (ii); -
(c) at least one cationic surfactant present in an amount ranging from 0.05 to 5 weight percent based on the total weight of said composition, said cationic surfactant being a compound having the formula ##STR36## and being selected from the group consisting of (1) a compound of formula IV wherein R5 and R6 represent methyl and R7 and R8 have the following meanings (i) R7 and R8 represent a linear aliphatic radical containing from 12 to 22 carbon atoms, an aliphatic radical derived from tallow fatty acids and containing 14 to 22 carbon atoms, or (ii) R7 represents a linear aliphatic radical containing 14-22 carbon atoms and R8 represents methyl or benzyl, or (iii) R7 represents an alkylamidopropyl radical wherein the alkyl moiety has 14-22 carbon atoms and R8 represents an alkylacetate group wherein the alkyl moiety has 12-16 carbon atoms, or (iv) R7 represents a gamma-gluconamidopropyl radical, an aliphatic radical derived from tallow fatty acids or a C16 -C18 alkyl radical, and R8 represents hydroxyethyl, and X.sup.⊖
represents an anion,(2) a compound of formula IV wherein R5 represents alkylamidoethyl, alkenylamidoethyl or a mixture thereof, said alkyl moiety containing 14-22 carbon atoms and originating from tallow fatty acids and said alkenyl moiety containing 14-22 carbon atoms and originating from tallow fatty acids, and R6 and R7 together with the nitrogen atom to which they are attached form a 2-alkyl-4,5-dihydroimidazole heterocycle ring wherein the alkyl moiety is derived from tallow fatty acids, R8 represents methyl and X.sup.⊖
represents a methosulphate ion, and(3) a compound of formula IV wherein R5, R6, and R7 form with the nitrogen atom to which they are attached a six membered aromatic heterocyclic ring, R8 represents a C14 -C18 alkyl radical and X.sup.⊖
represents a halide anion;(d) at least one alkalizing agent present in an amount sufficient such that the pH of said composition is higher than 7, said alkalizing agent being selected from sodium hydroxide, potassium hydroxide, aqueous ammonia and an alkanolamine; (e) at least one cationic polymer present in an amount ranging from 0.05 to 5 weight percent based on the total weight of said composition, said cationic polymer being selected from the group consisting of; (1) a quaternary polyammonium polymer selected from the group consisting of (a) a polymer consisting of repeating units of the formula ##STR37## wherein (i) R1, R2, R3 and R4, each independently, represent an aliphatic, alicyclic or arylaliphatic radical containing 1-20 carbon atoms or a C1 -C6 hydroxyaliphatic radical, or (ii) R1 and R2 and R3 and R4, together or separately, form with the nitrogen atoms to which they are attached a heterocyclic ring or a heterocyclic ring containing a second heteroatom other than nitrogen, or (iii) R1, R2, R3 and R4 represent a linear or branched C2 -C6 alkyl group substituted by a nitrile group, an ester group, an acyl group, an amide group, a group of the formula ##STR38## or a group of the formula ##STR39## wherein R'"'"'7 represents alkylene and D represents a quaternary ammonium group, A and B represent a linear or branched, saturated or unsaturated polymethylene group containing 2 to 20 carbon atoms or a linear or branched saturated or unsaturated polymethylene group containing 2 to 20 carbon atoms and containing in the main chain one or more of an aromatic ring, an oxygen atom, a sulphur atom, a sulphoxide group, a sulphone group, a disulphide group, an amine group, an alkylamine group, a quaternary ammonium group, a hydroxyl group, a ureido group, an amide group or an ester group, or A and R1 and R3 together with the two nitrogen atoms to which they are attached form a piperazine ring, X.sup.⊖
is an anion derived from an inorganic or organic acid, andn is such that the molecular weight of the polymer ranges from 1,000 to 100,000 and (b) a polymer consisting of repeating units of the formula ##STR40## wherein R4, R5, R6 and R7, each independently represent hydrogen, methyl, ethyl, propyl, 2-hydroxyethyl, 2-hydroxypropyl, or --CH2 --CH2 --(O--CH2 --CH2)p --OH wherein p is 0 or an integer ranging from 1 to 6, with the proviso that R4, R5, R6 and R7 do not simultaneously represent hydrogen, x and y, each independently, represent integers ranging from 1 to 6, m is 0 or an integer ranging from 1 to 34, X is a halogen atom, and A is a divalent group having the formula, --CH2 --CH2 --O--CH2 --CH2 --; (2) a vinylpyrrolidone/dialkylaminoalkyl acrylate quaternized or not; (3) a vinylpyrrolidone/dialkylaminoalkyl methacrylate quaternized or not; (4) poly (methacrylamidopropyltrimethyl ammonium chloride); (5) a cationic protein which is a chemically modified polypeptide bearing amine or quaternary ammonium groups at the end of the chain or grafted onto the chain; (6) a polyaminoamide selected from the group consisting of (i) a water soluble polyaminoamide obtained by condensation of an acidic compound with a polyamine, (ii) a crosslinked water soluble polyaminoamide obtained by condensation of an acidic compound with a polyamine, (iii) an alkylated water soluble polyaminoamide obtained by condensation of an acidic compound with a polyamine, (iv) a polyaminoamide resulting from the condensation of a polyalkylenepolyamine with a polycarboxylic acid and alkylated with a difunctional agent, and (v) a polyaminoamide obtained by reacting a polyalkylenepolyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid, the molar ratio between the said polyalkylenepolyamine and the said dicarboxylic acid being between 0.8/1 and 1.4/1, the resulting polyaminoamide being reacted with epichlorohydrin, the molar ration of epichlorohydrin to the secondary amine groups of the polyaminoamide being between 0.5/1 and 1.8/1; a crosslinked polyaminoamide; an alkylated polyaminoamide; and mixtures thereof. - View Dependent Claims (3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27)
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5. The cosmetic composition of claim 4 where in said polymer (ii) a is 0.
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6. The cosmetic composition of claim 4 where in said polymer (ii) b is 1.
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7. The cosmetic composition of claim 4 where in said polymer (ii) the sum n+m ranges from 50 to 150 wherein n represents a number ranging from 49 to 149 and m represents a number ranging from 1 to 10.
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8. The cosmetic composition of claim 4 where in said polymer (iii) r has a statistical average value ranging from 2 to 8.
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9. The cosmetic composition of claim 4 where in said polymer (iii) s has a statistical average value ranging from 20 to 50.
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10. The cosmetic composition of claim 1 wherein said amphoteric silicone polymer has the formula ##STR51## wherein p and q are integers which depend on the molecular weight of the polymer, the average molecular weight of the polymer ranging from 1,000 to 8,000.
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11. The cosmetic composition of claim 1 wherein said silicone polymer has the formula ##STR52## wherein the sum of n+m represents a number ranging from 1 to 2,000, n representing a number ranging from 1 to 1,999, and m representing a number ranging from 1 to 2,000.
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12. The cosmetic composition of claim 1 wherein said silicone polymer is an emulsion of a dimethyl polysiloxane modified by the incorporation of bis-silyl groups of the formula --OSi--C3 H6 NH--C3 H6 SiO--.
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13. The cosmetic composition of claim 1 wherein said silicone polymer is present in an amount ranging from 0.1 to 3 weight percent based on the total weight of said composition.
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14. The cosmetic composition of claim 1 wherein said cationic surface agent is selected from the group consisting of
(i) dimethyldilaurylammonium chloride, (ii) dimethyldialkylammonium chloride wherein the alkyl moiety is derived from hydrogenated tallow, (iii) dimethyldialkylammonium chloride wherein the alkyl moiety has 18 carbon atoms, (iv) trimethylalkylammonium chloride wherein the alkyl moiety has 20-22 carbon atoms, (v) cetylpyridinium chloride, (vi) dimethyldialkylammonium chloride wherein the alkyl moiety has 12-14 carbon atoms, (vii) dimethyl-gamma-gluconamidopropyl-hydroxyethylammonium chloride, (viii) dimethyldicetylammonium chloride; -
(ix) dimethylhydroxyethylalkyl ammonium chloride wherein the alkyl moiety is derived from tallow, (x) dimethylhydroxyethylcetylammonium chloride, (xi) dimethylstearylbenzylammonium chloride, and (xii) mixtures of (i)-(xi).
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15. The cosmetic composition of claim 1 wherein said alkanolamine is monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1,3-propanediol and triisopropanolamine.
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16. The cosmetic composition of claim 1 wherein said quaternary polyammonium polymer is selected from the group consisting of
(1) a polymer consisting of repeating units of the formula ##STR53## (2) a polymer consisting of repeating units of the formula ##STR54## (3) a polymer consisting of repeating units of the formula ##STR55## wherein n is equal to approximately 6, (4) a polymer consisting of repeating units of the formula ##STR56## wherein X represents halogen, (5) a polymer consisting of repeating units of the formula ##STR57## wherein X represents halogen, and (6) poly(dimethylbutenylammonium chloride)-α - -ω
-bis (triethanolammonium chloride).
- -ω
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17. The cosmetic composition of claim 1 wherein said cationic protein is selected from the group consisting of
(1) a collagen hydrolysate bearing a triethylammonium group, (2) a collagen hydrolysate bearing a trimethylammonium chloride group or a trimethylstearylammonium chloride group, (3) an animal protein hydrolysate bearing a trimethylbenzylammonium group, (4) a protein hydrolysate bearing, on the polypeptide chain, a quaternary ammonium group comprising at least one alkyl radical containing 1-18 carbon atoms and having an average molecular weight ranging from approximately 2,500 to 12,000, (5) a protein of the formula ##STR58## wherein A represents a protein residue derived from a collagen protein hydrolysate, R5 represents a lipophilic group containing up to 30 carbon atoms, and R6 represents alkylene containing 1-6 carbon atoms, said protein having a molecular weight ranging from 1,500 to 10,000, and (6) an animal protein hydrolysate bearing a dimethylamine group. -
18. The cosmetic composition of claim 17 wherein said cationic protein is selected from the group consisting of (1) a protein hydrolysate having on the polypeptide chain thereof, a quaternary ammonium group containing a C12 alkyl group and having an average molecular weight of approximately 2,500,
(2) a protein hydrolysate whose polypeptide chain has an average molecular weight of approximately 2,500 and whose quaternary ammonium group contains a C10 -C18 alkyl group, (3) a protein hydrolysate whose polypeptide chain has an average molecular weight of approximately 2,700 and whose quaternary ammonium group contains a C18 alkyl group, (4) a protein hydrolysate whose polypeptide chain has an average molecular weight of order of 12,000 and whose quaternary ammonium group contains an alkyl group containing from 1-18 carbon atoms, and (5) a protein of the formula ##STR59## wherein A, R5 and R6 are as defined in claim 46 and which has a molecular weight between 2,000 and 5,000. -
19. The cosmetic composition of claim 18 wherein said cationic copolymer is selected from the group consisting of
(i) homopolymer of dimethyldiallylammonium chloride having a molecular weight less than 100,000 and (ii) copolymer of dimethyldiallylammonium chloride and acrylamide having a molecular weight greater than 500,000. -
20. The cosmetic composition of claim 1 wherein said reducing agent is selected from the group consisting of thioglycolic acid, thiolactic acid, ammonium thiolactate and sodium metabisulfite, said reducing agent being present in an amount ranging from 0.5 to 2 percent by weight based on the total weight of said composition.
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21. The cosmetic composition of claim 1 wherein said oxidation dye precursor is
(i) an oxidation base selected from the group consisting of a diamine, a monoaminophenol and a diaminophenol, or (ii) a modifier or coupler selected from the group consisting of a meta-diamine, a meta-aminophenol, a phenol and a polyphenol, or (iii) a mixture of (i) and (ii). -
22. The cosmetic composition of claim 21 wherein said oxidation base is selected from the group consisting of
(i) a compound of the formula ##STR60## wherein R7 and R8 each independently represent hydrogen, straight or branched chain lower alkyl, monohydroxylated alkyl, polyhydroxylated alkyl, piperidinoalkyl, carbamylalkyl, dialkylcarbamylalkyl, aminoalkyl, monoalkylaminoalkyl, dialkylaminoalkyl, ω - -aminosulphonylalkyl, carboxyalkyl, alkylsulphonamidoalkyl, arylsulphonamidoalkyl, morpholinoalkyl, acylaminoalkyl, sulphoalkyl or alkoxyalkyl, wherein the alkyl moiety of each contains 1-4 carbon atoms, or
R7 and R8 together with the nitrogen atom to which they are attached form a morpholinyl or piperidinyl group, R5, R6, R9 and R10 each independently represent hydrogen, halogen, lower alkyl containing 1-4 carbon atoms or OZ wherein Z represents hydroxyalkyl, alkoxyalkyl, acylamino alkyl, carbalkoxyaminoalkyl, mesylaminoalkyl, ureidoalkyl, aminoalkyl, monoalkylaminoalkyl or dialkylaminoalkyl, and the hydrochloride, hydrobromide, sulphate or tartrate thereof, (ii) p-aminophenol and the homologue thereof whose aromatic nucleus is substituted by methyl or chlorine, (iii) N-methyl-p-aminophenol, (iv) heterocyclic derivative of pyridine, (v) heterocyclic derivative of benzomorpholine, (vi)5-aminoindole, (vii) orthoaminophenol, (viii) p-aminodiphenylamine and (ix) ortho-phenylenediamine said oxidation base being present in an amount ranging from 0.01 to 5 weight percent based on the total weight of said composition.
- -aminosulphonylalkyl, carboxyalkyl, alkylsulphonamidoalkyl, arylsulphonamidoalkyl, morpholinoalkyl, acylaminoalkyl, sulphoalkyl or alkoxyalkyl, wherein the alkyl moiety of each contains 1-4 carbon atoms, or
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23. The cosmetic composition of claim 21 which also contains at least one coupler selected from the group consisting of
(i) a compound of the formula ##STR61## wherein R11 and R12 each independently represent hydroxyl or -NHR wherein R represents hydrogen, acyl, ureido, carbalkoxy, carbamylalkyl, alkyl, dialkylcarbamylalkyl, hydroxyalkyl or mesylaminoalkyl, or R11 and R12 represent hydrogen, alkoxy or alkyl with the proviso that at least one of R11 and R12 represents OH, R13 and R14 represent hydrogen, branched or linear alkyl, halogen, amino, alkylamino, acylamino, ureido or OZ wherein Z represents hydroxyalkyl, polyhydroxyalkyl, aikoxylalkyl, mesylaminoalkyl, acylaminoalkyl, ureidoalkyl or carbalkoxyalkyl, (ii) α - -naphthol, and
(iii) heterocyclic compound derived from benzomorpholine, pyridine, pyrazolone and a diketone compound, said coupler being present in an amount ranging from 0.001 to 5 weight percent based on the total weight of said composition.
- -naphthol, and
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24. The cosmetic composition of claim 1 wherein said cationic silicone polymer is present in the form of an emulsion that also contains a nonionic or cationic surface active agent, said emulsion being selected from the group consisting of
(i) an emulsion which is a combination of (a) a polymer having the formula ##STR62## wherein the sum or m+n is a number ranging from 1 to 2,000, n representing a number ranging from 0 to 1,999 and m representing a number ranging from 1 to 2,000, (b) polyoxyethylenated octylphenol having the formula C8 H17 --C6 H4 --(OCH2 CH2)n --OH wherein n is 40 and (c) polyoxyethylenated laurylalcohol or the formula C12 H25 --(OCH2 CH2)n --OH wherein n is 6, (d) glycol, and (ii) an emulsion which is a combination of silicone polymer having the formula ##STR63## wherein x is 4 or more and y is such that the resulting polymer has an average molecular weight ranging between 5,000 and 10,000, (b) trimethylalkyl ammonium chloride wherein the alkyl moiety is derived from tallow and having the formula ##STR64## wherein R4 represents a mixture of alkenyl radicals, a mixture of alkyl radicals or a mixture of alkyl and alkenyl radicals containing 14-22 carbon atoms and being derived from tallow fatty acids and (c) polyoxyethylenated nonylphenol having the formula C9 H19 --C6 H4 --(OC2 H4)10 --OH. -
25. The cosmetic composition of claim 1 which also includes at least one of a solvent, a fatty amide, a fatty alcohol, a nonionic surface agent, an amphoteric surface agent, a sequestering agent and a perfume.
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26. A process for bleaching hair comprising applying to the hair in an amount effective to bleach said hair a hair bleaching formulation comprising an admixture of the cosmetic composition of claim 1 and 0.5 to 3 parts of the weight thereof of an oxidizing agent selected from the group consisting of hydrogen peroxide, a persalt and a mixture thereof, permitting said hair bleaching formulation to remain in contact with the hair for a time sufficient to bleach said hair, rinsing the hair with water and drying said hair.
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27. A process for dyeing hair comprising applying to the hair in an amount effective to dye the hair a hair dyeing formulation comprising an admixture of the cosmetic composition of claim 1 and 0.5 to 3 parts of the weight thereof of an oxidizing agent selected from the group consisting of hydrogen peroxide, a persalt and a mixture thereof, permitting said hair dyeing formulation to remain in contact with the hair for a time sufficient to dye said hair, rinsing the hair and drying the hair.
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2. A storage stable, alkaline cosmetic composition for dyeing hair, said composition being dilutable with an oxidizing solution and comprising in an aqueous medium
(a) at least one fatty acid soap present in an amount ranging from 1 to 25 weight percent based on the total weight of said composition, said fatty acid soap being selected from the group consisting of alkali metal salt of a C12 -C18 fatty acid containing a saturated or unsaturated fatty chain, an alkanolamine salt of a C12 -C18 fatty acid containing a saturated or unsaturated fatty chain and mixtures thereof, (b) at least one cationic or amphoteric silicone polymer present in an amount ranging from 0.05 to 5 weight percent based on the total weight of said composition, said cationic or amphoteric silicone polymer being selected from the group consisting of (i) a polysiloxane in which at least one silicon atom in the chain carries an aliphatic amino group, the amine group of which is primary, secondary, tertiary or quaternary, (ii) a polysiloxane in which at least one silicon atom in the chain carries an aliphatic amino group, the amine group of which has the betaine structure and (iii) a mixture of (i) and (ii); -
(c) at least one cationic surfactant present in an amount ranging from 0.05 to 5 weight percent based on the total weight of said composition, said cationic surfactant being a compound having the formula ##STR41## and being selected from the group consisting of (1) a compound of formula IV wherein R5 and R6 represent methyl and R7 and R8 have the following meanings (i) R7 and R8 represent a linear aliphatic radical containing from 12 to 22 carbon atoms, an aliphatic radical derived from tallow fatty acids and containing 14 to 22 carbon atoms, or (ii) R7 represents a linear aliphatic radical containing 14-22 carbon atoms and R8 represents methyl or benzyl, or (iii) R7 represents an alkylamidopropyl radical wherein the alkyl moiety has 14-22 carbon atoms and R8 represents an alkylacetate group wherein the alkyl moiety has 12-16 carbon atoms, or (iv) R7 represents a gamma-gluconamidopropyl radical, an aliphatic radical derived from tallow fatty acids or a C16 -C18 alkyl radical, and R8 represents hydroxyethyl, and X.sup.⊖
represents an anion,(2) a compound of formula IV wherein R5 represents alkylamidoethyl, alkenylamidoethyl or a mixture thereof, said alkyl moiety containing 14-22 carbon atoms and originating from tallow fatty acids and said alkenyl moiety containing 14-22 carbon atoms and originating from tallow fatty acids, and R6 and R7 together with the nitrogen atom to which they are attached form a 2-alkyl-4,5-dihydroimidazole heterocycle ring wherein the alkyl moiety is derived from tallow fatty acids, R8 represents methyl and x.sup.⊖
represents a methosulphate ion, and(3) a compound of formula IV wherein R5, R6, and R7 form with the nitrogen atom to which they are attached a six membered aromatic heterocyclic ring, R8 represents a C14 -C18 alkyl radical and X.sup.⊖
represents a halide anion;(d) at least one alkalizing agent present in an amount sufficient such that the pH of said composition is higher than 7, said alkalizing agent being selected from sodium hydroxide, potassium hydroxide, aqueous ammonia and an alkanolamine; (e) at least one cationic polymer present in an amount ranging from 0.05 to 5 percent based on the total weight of said composition, said cationic polymer being selected from the group consisting of; (1) a quaternary polyammonium polymer selected from the group consisting of (a) a polymer consisting of repeating units of the formula ##STR42## wherein (i) R1, R2, R3 and R4, each independently, represent an aliphatic, alicyclic or arylaliphatic radical containing 1-20 carbon atoms or a C1 -C6 hydroxyaliphatic radical, or (ii) R1 and R2 and R3 and R4, together or separately, form with the nitrogen atoms to which they are attached a heterocyclic ring or a heterocyclic ring containing a second heteroatom other than nitrogen, or (iii) R1, R2, R3 and R4 represent a linear or branched C2 -C6 alkyl group substituted by a nitrile group, an ester group, an acyl group, an amide group, a group of the formula ##STR43## or a group of the formula ##STR44## wherein R'"'"'7 represents alkylene and D represents a quaternary ammonium group, A and B represent a linear or branched, saturated or unsaturated polymethylene group containing 2 to 20 carbon atoms or a linear or branched saturated or unsaturated polymethylene group containing 2 to 20 carbon atoms and containing in the main chain one or more of an aromatic ring, an oxygen atom, a sulphur atom, a sulphoxide group, a sulphone group, a disulphide group, an amine group, an alkylamine group, a quaternary ammonium group, a hydroxyl group, a ureido group, an amide group or an ester group, or A and R1 and R3 together with the two nitrogen atoms to which they are attached form a piperazine ring, X.sup.⊖
is an anion derived from an inorganic or organic acid, andn is such that the molecular weight of the polymer ranges from 1,000 to 100,000 and (b) a polymer consisting of repeating units of the formula ##STR45## wherein R4, R5, R6 and R7, each independently represent hydrogen, methyl, ethyl, propyl, 2-hydroxyethyl, 2-hydroxypropyl, or --CH2 --CH2 --(O--CH2 --CH2) p --OH wherein p is 0 or an integer ranging from 1 to 6, with the proviso that R4, R5, R6 and R7 do not simultaneously represent hydrogen, x and y, each independently, represent integers ranging from 1 to 6, m is 0 or an integer ranging from 1 to 34, X is a halogen atom, and A is a divalent group having the formula, --CH2 --CH2 --O--CH2 --CH2 --; (2) a vinylpyrrolidone/dialkylaminoalkyl acrylate quaternized or not; (3) a vinylpyrrolidone/dialkylaminoalkyl methacrylate quaternized or not; (4) poly (methacrylamidopropyltrimethyl ammonium chloride); (5) a cationic protein which is a chemically modified polypeptide bearing amine or quaternary ammonium groups at the end of the chain or grafted onto the chain; (6) a polyaminoamide selected from the group consisting of (i) a water soluble polyaminoamide obtained by condensation of an acidic compound with a polyamine, (ii) a crosslinked water soluble polyaminoamide obtained by condensation of an acidic compound with a polyamine, (iii) an alkylated water soluble polyaminoamide obtained by condensation of an acidic compound with a polyamine, (iv) a polyaminoamide resulting from the condensation of a polyalkylenepolyamine with a polycarboxylic acid and alkylated with a difunctional agent, and (v) a polyaminoamide obtained by reacting a polyalkylenepolyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid, the molar ratio between the said polyalkylenepolyamine and the said dicarboxylic acid being between 0.8/1 and 1.4/1, the resulting polyaminoamide being reacted with epichlorohydrin, the molar ratio of epichlorohydrin to the secondary amine groups of the polyaminoamide being between 0.5/1 and 1.8/1; a crosslinked polyaminoamide; an alkylated polyaminoamide; a cationic cyclopolymer selected from the group consisting of (i) a cationic cyclopolymer consisting of repeating units of the formula ##STR46## (ii) a cationic cyclopolymer consisting of repeating units of the formula ##STR47## wherein l and t are equal to 0 and 1 and the sum of l+t is equal to 1, R" represents hydrogen or methyl, R and R'"'"', each independently, represent alkyl containing 1-22 carbon atoms, hydroxyalkyl containing 1-5 carbon atoms or lower amidoalkyl, or R and R'"'"' together with the nitrogen atom to which they are attached form a piperidyl or morpholinyl group, and mixtures thereof, (f) an oxidation dye precursor in an amount effective to dye the hair and (g) 0.5 to 2 percent by weight of a reducing agent.
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Specification
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Current AssigneeL'Oreal SA
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Original AssigneeL'Oreal SA
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InventorsMadrange, Annie, Canivet, Patrick
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Primary Examiner(s)Clingman, A. Lionel
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Assistant Examiner(s)PARKS, WILLIAM
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Application NumberUS07/719,366Time in Patent Office435 DaysField of Search8/405, 8/406, 8/416, 8/421, 424/70US Class Current8/405CPC Class CodesA61K 2800/5426 cationicA61K 2800/594 Mixtures of polymersA61K 8/64 Proteins; Peptides; Derivat...A61K 8/8182 Copolymers of vinyl-pyrroli...A61K 8/84 obtained by reactions other...A61K 8/88 PolyamidesA61Q 5/08 Preparations for bleaching ...A61Q 5/10 Preparations for permanentl...
