Methods of tar sand bitumen recovery

• US 5,143,598 A
• Filed: 01/14/1988
• Issued: 09/01/1992
• Est. Priority Date: 10/31/1983
• Status: Expired due to Fees

• Current Assignee: Amoco Corporation (BP PLC)
• Original Assignee: Amoco Corporation (BP PLC)
• Inventors: Stone, Richard A., Graham, Robert J., Bernier, Edward J. Jr., Helstrom, John J., Peck, Lawrence B.
• Primary Examiner(s): Pal, Asok
• Application Number:
  US07/144,248
• Time in Patent Office: 1,692 Days
• Field of Search: 208/390
• US Class Current: 208/390
• CPC Class Codes: C10G 1/04 by extraction

Abstract

Methods for the recovery of bitumen from tar sands comprising the steps of mixing tar sand, solvent and a displacing amount of aqueous medium to form a mixture, followed by separating a bitumen-rich solvent phase from the mixture and recovering bitumen from the bitumen-rich solvent phase are disclosed.

Claims

1. A method of recovery of bitumen from tar sands comprising the steps of:

mixing tar sands, an organic solvent effective in solubilizing bitumen including asphaltenes from the mineral of said tar sand and a displacing amount of no more than about one void volume of an aqueous medium effective in displacing bitumen-rich solvent from said ground tar sands and in avoiding substantially spontaneous emulsion formation to form a first mixture, said mixing being at tar sands mixing conditions including mixing intensity and duration to suspend said tar sand and provide sufficient mass transfer between phases of said first mixture without significant emulsion formation, said first mixture being readily separable to a bitumen solution and a sand-water mixture upon cessation of said mixing;

separating a bitumen-rich solvent phase from said first mixture leaving an aqueous mineral phase containing a residual amount of said solvent; and

recovering bitumen from the bitumen-rich solvent phase.

2. The method of claim 1 wherein said tar sands are at least partially consolidated and wherein prior to said mixing step said tar sands are ground to a particle size of no larger than about 1/2 inch.

3. The method of claim 2 wherein said at least partially consolidated tar sand is ground using a wet grinding technique.

4. The method of claim 3 wherein said wet grinding technique is selected from the group consisting of solvent wet grinding, water wet grinding and solvent/water wet grinding.

5. The method of claim 3 wherein said wet grinding is done in an autogeneous or semi-autogeneous mill.

6. The method of claim 1 additionally comprising the step of stripping residual solvent from said aqueous mineral phase.

7. The method of claim 6 additionally comprising the step of recovering water from the solvent stripped aqueous mineral phase.

8. The method of claim 1 additionally comprising the step of reducing the fines content of the bitumen-rich solvent phase.

9. The method of claim 8 wherein said step of reducing the fines content comprises the step of deasphaltening said bitumen-rich solvent phase prior to the recovery of the bitumen from said bitumen-rich solvent phase.

10. The method of claim 1 wherein said tar sands comprise oil wet tar sands.

11. The method of claim 1 wherein said mixing and separating steps are conducted at an operating temperature of about 110°

-130°

F.

12. The method of claim 11 wherein said operating temperature is about 120°

F.

13. The method of claim 1 wherein said first mixture comprises an aqueous phase having a pH of no greater than about 9.

14. The method of claim 1 wherein said aqueous medium consists essentially of water.

15. The method of claim 1 wherein said displacing amount of said aqueous medium comprises about 0.22-0.27 pounds of water per pound of mineral.

16. The method of claim 1 wherein said organic solvent is added in an amount of about 2-5 parts solvent per part bitumen.

17. The method of claim 1 wherein said mixing conditions comprises a mixing power input of at least one horsepower per thousand gallons of said first mixture.

18. The method of claim 17 wherein said mixing conditions comprises a mixing power input of about 1-50 horsepower per thousand gallons of said first mixture.

19. A method of recovery of bitumen from tar sand, said tar sand being at least partially consolidated, said method comprising the steps of:

solvent/water wet grinding said tar sands;

mixing the ground tar sands, an organic solvent effective in solubilizing bitumen including asphaltenes from the mineral of said tar sands and a displacing amount of no more than about one void volume of an aqueous medium effective in displacing bitumen-rich solvent from said ground tar sands and in avoiding substantially spontaneous emulsion formation to form a first mixture, said mixing being at tar sands mixing conditions including mixing intensity and duration to suspend said tar sands and provide sufficient mass transfer between phases of said first mixture without significant emulsion formation, said first mixture being readily separable to a bitumen solution and a sand-water mixture upon cessation of said mixing;

separating a bitumen-rich solvent phase from said first mixture leaving an aqueous mineral phase containing a residual amount of said solvent;

stripping residual solvent from said aqueous mineral phase;

recovering water from said solvent stripped aqueous mineral phase;

removing fines from said bitumen-rich solvent phase; and

recovering bitumen from said bitumen-rich solvent phase.

20. The method of claim 19 wherein said ground tar sands comprise tar sands ground to a particle size of no larger than about one-half inch.

21. The method of claim 19 wherein said tar sands comprise oil wet tar sands.

22. The method of claim 19 wherein said mixing and separating steps are conducted at an operating temperature of about 110°

-130°

F.

23. The method of claim 22 wherein said operating temperature is about 120°

F.

24. The method of claim 19 wherein said aqueous medium consists essentially of water.

25. The method of claim 19 wherein said displacing amount of said aqueous medium comprises about 0.22-0.27 pounds of water per pound of mineral.

26. The method of claim 19 wherein said organic solvent is added in an amount of about 2-5 parts solvent per part bitumen.

27. The method of claim 19 wherein said mixing conditions comprises a mixing power input of at least one horsepower per thousand gallons of said first mixture.

28. The method of claim 27 wherein said mixing conditions comprises a mixing power input of about 1-50 horsepower per thousand gallons of said first mixture.

29. A method of recovery of bitumen from tar sand, said tar sand being at least partially consolidated oil wet tar sand from the Sunnyside deposit in Carbon County, Utah, said method comprising the steps of:

wet grinding said tar sands to a particle size of no larger than about one-half inch;

mixing said ground tar sands, an organic solvent effective in solubilizing bitumen including asphaltenes from the mineral of said tar sands and a displacing amount of no more than about one void volume of an aqueous medium effective in displacing bitumen-rich solvent from said ground tar sands and in avoiding substantially spontaneous emulsion formation to form a first mixture, said displacing amount of said aqueous medium comprising about 0.22-0.27 pounds of water per pound of mineral, said mixing being at tar sand mixing conditions including a mixing intensity of at least about one horsepower per thousand gallons of said mixture and a mixing duration of at least one minute to suspend said tar sands and provide sufficient mass transfer between phases of the mixture without significant emulsion formation, said first mixture being readily separable to a bitumen solution and a sand-water mixture upon cessation of said mixing;

separating a bitumen-rich solvent phase from said first mixture leaving an aqueous mineral phase containing a residual amount of said solvent;

stripping residual solvent from said aqueous mineral phase;

recovering water from said solvent stripped aqueous mineral phase;

reducing the fines contents of the bitumen-rich solvent phase; and

recovering bitumen from said bitumen-rich solvent phase.

30. The method of claim 29 wherein said tar sand is ground using a grinding technique selected from the group consisting of solvent wet grinding, water wet grinding and solvent/water wet grinding.

31. The method of claim 30 wherein said grinding is conducted in an autogeneous or semi-autogeneous mill.

32. The method of claim 29 wherein said step of reducing the fines content comprises the step of deasphaltening said bitumen-rich solvent phase prior to the recovery of the bitumen from said bitumen-rich solvent phase.

33. The method of claim 29 wherein said first mixture comprises an aqueous phase having a pH of no greater than about 9.

34. The method of claim 29 wherein said aqueous medium consists essentially of water.

35. The method of claim 29 wherein said organic solvent is added in an amount of about 2-5 parts solvent per part bitumen.