Stereolithography method and apparatus

• US 5,143,663 A
• Filed: 06/12/1989
• Issued: 09/01/1992
• Est. Priority Date: 06/12/1989
• Status: Expired due to Term

• Current Assignee: 3D Systems, Inc. (3D Systems Corporation)
• Original Assignee: 3D Systems, Inc. (3D Systems Corporation)
• Inventors: Almouist, Thomas A., Lewis, Mark A., Leyden, Richard N., Nguyen, Hop D.
• Primary Examiner(s): Tentoni, Leo B.
• Application Number:
  US07/365,444
• Time in Patent Office: 1,177 Days
• Field of Search: 264/22, 264/23, 264/69, 264/232, 264/233, 264/236, 264/255, 264/298, 264/308, 264/340, 264/344, 264/347, 425/174, 425/174.2, 425/174.4, 425/404, 425/445, 156/273.3, 156/273.5, 156/275.5, 156/307.1, 156/379.6, 427/53.1, 427/54.1, 427/57, 427/335, 427/346, 118/57, 118/402, 118/423, 118/425, 118/429, 118/620, 364/468, 364/474.05, 364/474.24, 364/476, 365/107, 365/119, 365/120, 365/127, 34/4, 34/9, 34/12, 34/22, 34/33, 34/36, 34/37, 34/69, 34/148, 34/149, 34/164, 34/179, 34/180, 34/189, 34/236, 134/1, 134/12, 134/31, 134/32, 134/61, 134/63, 134/82, 134/83, 134/137, 134/184, 134/186, 134/195
• US Class Current: 264/401
• CPC Class Codes: B29C 64/135 the energy source being concentrated, e.g. scanning lasers or focused light sources
• CPC Class Codes: B29C 71/0009 using liquids, e.g. solvents, swelling agents spectacle cases, e.g. for cleaning contact lenses A45C11/04; disinfecting or sterilising contact lenses A61L12/00, using liquid substances A61L2/20; cleaning involving the use of liquid in general B08B3/00; for hydrating contact lenses B29D11/00067
• CPC Class Codes: B29C 71/04 by wave energy or particle radiation , e.g. for curing or vulcanising preformed articles during moulding, e.g. in a mould B29C35/08
• CPC Class Codes: B33Y 40/20 Post-treatment, e.g. curing, coating or polishing

Abstract

An improved stereolithographic apparatus and method is described. In one embodiment, the improvement includes immersing at least a portion of a part in a volume of a liquid solvent in a vapor degreaser while subjecting the portion to ultrasonic agitation to substantially remove excess resin. Several examples of solvents are provided, including ethanol, and Freon TMS. In a second embodiment, the improvement includes building the part on a layer of liquid resin supported by a volume of a dense, immiscible, and UV transparent intermediate liquid, and integratably immersing at least a portion of the built part in the intermediate liquid, and then either subjecting the immersed portion to ultrasonic agitation to substantially remove excess resin, or subjecting the immersed portion to UV light. Several examples of intermediate liquids are provided, including perfluorinated fluids, such as Fluorinert FC-40, and water-based salt solutions, such as solutions of magnesium sulfate or sodium chloride in water.

Claims

1. An improved stereolithography apparatus of the type for building a part at a surface of a volume of material capable of selective physical transformation upon exposure to prescribed synergistic stimulation including means for exposing successive cross-sectional patterns of said part on a selected surface of said material capable of selective physical transformation and successively forming a coating of said material on cross-sections of a determined thickness to form a laminate composite of said part, the improvement comprising means for building the part at the surface of a layer of said material capable of selective physical transformation supported on a volume of a dense, immiscible, intermediate liquid, at least partially transparent to said synergistic stimulation and means for immersing at least a portion of the part into the intermediate liquid and means for integratably performing additional stereolithographic processing on at least a portion of the part while immersed in the intermediate liquid.

2. The apparatus of claim 1 wherein the additional stereolithographic processing means comprises at least one source of synergistic stimulation for subjecting the immersed portion of the built part to said synergistic stimulation, and isolating means for substantially isolating the layer of material capable of selective physical transformation from the synergistic stimulation.

3. The apparatus of claim 1 wherein the additional stereolithographic processing means comprises at least one ultrasonic transducers which ultrasonically agitate the immersed portion of the part.

4. The apparatus of claim 2 wherein the isolating means comprises a dual chamber vat having a first chamber containing the layer of material capable of selective physical transformation supported by the volume of the intermediate liquid and a second chamber containing a second volume of the intermediate liquid, a movable platform on which the part is built for moving the part along a predetermined path from the first to the second chambers, and a shutter placed along the predetermined path between the first and second chambers having an open and a closed position, wherein the part is moved from the first chamber to the second chamber by means of the platform when the shutter is open, wherein the second chamber has a periphery and an interior, and sources of synergistic stimulation are spaced around the periphery, wherein the shutter is closed after the part is moved to the second chamber, and wherein said synergistic stimulation thereafter impinges upon the part.

5. The apparatus of claim 2 wherein the isolating means is a pump for pumping off the material capable of selective physical transformation before post-curing.

6. The apparatus of claim 2 wherein the isolating means is a scoop for scooping off the material capable of selective physical transformation before post-curing.

7. The apparatus of claim 2 wherein the isolating means comprises a single chamber vat containing the layer of material capable of selective physical transformation supported by the volume of the intermediate liquid, a movable platform on which the part is built for moving the built part to a predetermined location, a hinged shutter having an open and a closed position, wherein the built part is moved by means of the platform to the predetermined location when the hinged shutter is open, wherein the vat has a periphery around which sources of synergistic stimulation are spaced wherein the shutter is closed after the built part is moved to the predetermined location, and wherein synergistic stimulation thereafter impinges upon the part.

8. An improved stereolithography apparatus according to claim 1 wherein the means for integratably performing additional stereolithographic processing further comprises means for integrating part building, cleaning and post-curing, including means for building the part by directing the synergistic stimulation to impinge upon the surface of a layer of the material capable of selective physical transformation floating on a volume of an intermediate liquid having a density which is at least about 5% greater than a density of the material capable of selective physical transformation floating on a volume of an intermediate liquid having a density which is at least about 5% greater than a density of the material capable of selective physical transformation, a solubility which is in a range from less than about 7 (cal./cm³)^1/2 to at least about 20 (cal./cm³)^1/2, and wherein the intermediate liquid has a surface, and at least about 80% of synergistic stimulation having a wavelength in a range of between about 330 to about 390 nm. penetrates to at least about six inches into the intermediate liquid beyond the surface;

means for at least partially immersing the part into the intermediate liquid to remove excess material; and

means for subjecting at least some of the immersed portion to sufficient synergistic stimulation to effect post curing.

9. The apparatus of claim 8 wherein the intermediate liquid has a density of at least about 1.2 g/ml.

10. The apparatus of claim 8 wherein the intermediate liquid is maintained at a predetermined temperature during part building, and the intermediate liquid is a perfluorinated liquid having a boiling point approximately greater than this temperature.

11. The apparatus of claim 8 wherein the intermediate liquid is a water-based salt solution.

12. An improved method of the type for building a part on a surface of a volume of material capable of selective physical transformation upon exposure to synergistic stimulation by exposing to synergistic stimulation successive cross-sectional patterns of said part on a selected surface of said material capable of selective physical transformation to form a laminate composite of said part, the improvement comprising the steps of building the part on the surface of a layer of the material capable of selective physical transformation supported by a volume of a dense, immiscible, intermediate liquid, at least partially transparent to said synergistic stimulation and then integratably performing additional stereolithographic processing on at least a portion of the part while it is immersed in the intermediate liquid.

13. The method of claim 12 wherein the additional stereolithographic processing comprises subjecting the immersed portion of the part to synergistic stimulation while substantially isolating the layer of the material capable of selective physical transformation from the synergistic stimulation.

14. The method of claim 12 wherein the additional stereolithographic processing comprises subjecting the immersed portion of the part to ultrasonic agitation.

15. A method according to claim 12 further comprising the step of building the part by directing synergistic stimulation to impinge upon a surface of a layer of the material and integrating building, cleaning and post-curing functions by supporting said material on a volume of an intermediate liquid having a density which is at least about 5% greater than a density of the working material, having a solubility which is in a range from less than about 7 (cal./cm³)^1/2, to at least about 20 (cal./cm³)^1/2, and wherein the intermediate liquid has a surface, and wherein at least about 80% of synergistic stimulation having a wavelength in a range of between about 330-390 nm, penetrates to at least about six inches into the liquid beyond the surface;

at least partially immersing the part into the intermediate liquid to remove excess material; and

subjecting at least some of the immersed portion to sufficient synergistic stimulation to effect post-curing.

16. The method of claim 15 wherein the intermediate liquid is maintained at a predetermined temperature during part building, and the intermediate liquid is a perfluorinated liquid having a boiling point approximately greater than this temperature.

17. The method of claim 15 wherein the intermediate liquid is a water-based salt solution.

28. The method of claim 16 wherein the intermediate liquid is a perfluorinated liquid.

18. An improved stereolithographic apparatus, for generating a part by forming successive cross-sectional patterns of the part at a selected surface of a material capable of selective physical transformation upon exposure to prescribed synergistic stimulation, including means for forming a coating on said cross-sections as they are formed with said material and for building up said part in step-wise fashion and thereafter cleaning and post-curing the part in separate apparatus, the improvement comprising means for integrating part cleaning and post-curing including means for immersing at least a portion of the part in a volume of liquid stripping medium to substantially remove the excess material from the portion prior to exposing at least some of the immersed portion to synergistic stimulation, means for exposing at least some of said immersed portion to synergistic stimulation while surrounded by the liquid stripping medium.

19. The apparatus of claim 18 comprising means for subjecting the immersed portion to ultrasonic agitation to assist in substantially removing the excess material from the portion.

20. The apparatus of claim 18 wherein the liquid stripping medium is a liquid solvent and wherein the portion of the part is immersed in the liquid solvent in a range of from less than about 10 minutes to less than about two minutes.

21. An improved stereolithographic apparatus, for generating a part by forming successive cross-sectional patterns of said part at a selected surface of a material capable of selective physical transformation upon exposure to prescribed synergistic stimulation including means for forming a coating on said cross-sections with said material as they are formed and for building up said part in step-wise fashion, and thereafter cleaning and post-curing the part in separate apparatus the improvement comprising means for integrating part cleaning and post-curing including means for immersing at least a portion of the part in solvent vapor of a vapor degreaser to substantially remove excess material from the portion and means for post-curing, including means for exposing at least some of said immersed portion to synergistic stimulation while surrounded by the solvent vapor.

22. An improved stereolithographic apparatus for producing a part by forming successive cross-sectional patterns of said part at a selected surface of a material capable of selective physical transformation upon exposure to prescribed synergistic stimulation including means for forming coatings of said material on said cross-sections as they are formed and for building up said part in a step-wise fashion, the improvement comprising means for integrating part cleaning and post-curing in the same apparatus with part building, including means for building the part, means for immersing at least a portion of the part in a volume of liquid stripping medium, and means for supplying synergistic stimulation to at least some of the immersed portion of the part to effect post-curing after substantially removing the excess material from the portion.

23. The apparatus of claim 23 including additional stereolithographic processing means comprising at least one physical agitation means for agitating the liquid stripping medium.

24. The apparatus of claim 23 wherein the liquid stripping medium medium is a solvent such as isopropanol, ethanol, propylene carbonate, water based cleaners.

25. An improved stereolithographic method, for forming a part from a material capable of selective physical transformation upon exposure to prescribed synergistic stimulation including forming successive cross-sectional patterns of the part on a selected surface of the material, forming a coating of said material on said cross-sections as they are formed and building up the part in a step-wise fashion, the improvement comprising the steps of integrating part cleaning and post-curing including immersing at least a portion of the part in a volume of solvent vapor of a vapor degreaser, and subjecting the immersed portion to synergistic stimulation after substantially removing excess material from the portion.

26. An improved stereolithographic method for forming a part from a material capable of selective physical transformation upon exposure to prescribed synergistic stimulation including forming successive cross-sectional patterns of the part on a selected surface of the material, forming a coating of said material on said cross-sections as they are formed and building up the part in a step-wise fashion, the improvement comprising the steps of integratably performing part cleaning and post-curing in the same apparatus with part building including the step of forming the part, the step of immersing at least a portion of the part in a volume of liquid stripping medium, and the step of exposing at least some of the immersed portion of the part to synergistic stimulation to effect post-curing after substantially removing excess material from the portion.

37. The method of claim 26, including the step of providing a solvent as the liquid stripping medium.

38. The method of claim 26, including the step of providing a non-solvent as the liquid stripping medium.

27. An improved stereolithographic method of the type for forming a part from a working material capable of physical transformation upon exposure to synergistic stimulation by using a source of synergistic stimulation to form successive cross-sectional patterns of the part on a selected surface of the working material, forming a coating of said material on the cross-sections as they are formed and building up the part in a step-wise fashion and thereafter cleaning and post-curing the part in separate apparatus, the improvement comprising integratably performing the steps of immersing at least a portion of the part in a volume of a liquid stripping medium to substantially remove excess material from the portion and subjecting the immersed portion to synergistic stimulation.

34. The method of claim 27, including the step of providing a solvent as the liquid stripping medium.

35. The method of claim 27, including the step of providing a non-solvent as the liquid stripping medium.

36. The method of claim 27, including the step of agitating the excess material while the portion is immersed in the liquid stripping medium.

39. The method of claim 27, including the step of agitating the excess material while the portion is immersed int he liquid stripping medium.

29. An improved stereolithographic apparatus for producing a part by forming successive cross-sectional patterns of said part at a selected surface of a material capable of selective physical transformation upon exposure to prescribed synergistic stimulation including means for forming a coating of said material on said cross-sections as they are formed and for building up said part in a step-wise fashion, the improvement comprising means for building the part cross-section by cross-section and means integral with the means for building for immersing at least a portion of the part in a liquid stripping medium to substantially remove excess material from the portion.

31. The apparatus of claim 29 wherein the liquid stripping medium is a solvent.

32. The apparatus of claim 29 wherein the liquid stripping medium is a non-solvent.

33. The apparatus of claim 29, including means for agitating the excess material while the portion is immersed in the liquid stripping medium.

30. An improved stereolithographic apparatus for producing a part by forming successive cross-sectional patterns of said part at a selective surface of a material capable of selective physical transformation upon exposure to prescribed synergistic stimulation including means for forming a coating of said material on said cross-sections as they are formed and for building up said part in a step-wise fashion, the improvement comprising means for building the part cross-section by cross-section and means integral with the means for building for immersing at least a portion of the part in solvent vapor of a vapor degreaser to substantially remove excess material from the portion.