Antimicrobial rinse cycle additive

• US 5,145,596 A
• Filed: 08/07/1989
• Issued: 09/08/1992
• Est. Priority Date: 08/07/1989
• Status: Expired due to Term

• Current Assignee: Dow, Inc.
• Original Assignee: Dow, Inc.
• Inventors: White, William C., Blank, Lynne M. B.
• Primary Examiner(s): Clingman, A. Lionel
• Assistant Examiner(s): Parks, William S.
• Application Number:
  US07/390,050
• Time in Patent Office: 1,128 Days
• Field of Search: 252/106, 252/DIG. 14, 252/8.6, 252/8.7, 252/8.75, 252/8.8, 252/8.9
• US Class Current: 510/513
• CPC Class Codes: C11D 17/0021 Aqueous microemulsions
• CPC Class Codes: C11D 3/162 containing Si
• CPC Class Codes: C11D 3/48 Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
• CPC Class Codes: D06M 13/513 with at least one carbon-silicon bond
• CPC Class Codes: D06M 16/00 Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic

Abstract

A method of treating fabrics in order to eliminate odor caused by microbial growth by adding an antibacterially effective amount of an organosilicon quaternary ammonium compound to the rinse cycle of a textile laundering operation containing the fabrics in order to destroy bacteria and fungi. The organosilicon quaternary ammonium compound is the silane 3-(trimethoxysilyl) propyldimethyloctadecyl ammonium chloride of the formula ##STR1##

Claims

1. A rinse cycle fabric laundering additive composition comprising a mixture of at least one nonsilicon organic quaternary ammonium compound, and at least one organosilicon quaternary ammonium compound, the organosilicon quaternary ammonium compound being an organosilane having the formula selected from the group consisting of ##STR11## wherein, in each formula, Y is R or RO where each R is an alkyl radical of 1 to 4 carbon atoms or hydrogen;

a has a value of 0, 1 or 2;

R'"'"' is a methyl or ethyl radical;

R" is an alkylene group of 1 to 4 carbon atoms;

R'"'"'", R"" and R^v are each independently selected from a group consisting of alkyl radicals of 1 to 18 carbon atoms, --CH₂ C₆ H₅, --CH₂ CH₂ OH, --CH₂ OH, and --(CH₂)_x NHC(O)R^vi, wherein x has a value of from 2 to 10 and R^vi is a perfluoroalkyl radical having from 1 to 12 carbon atoms; and

X is chloride, bromide, fluoride, iodide, acetate or tosylate.

2. The composition of claim 1 in which the organosilane and the organic quaternary ammonium compound are each present in the mixture in a ratio of about 5:

1.

3. A method of treating fabrics in a fabric laundering operation which includes a wash cycle followed by a rinse cycle in order to eliminate odor caused by microbial growth comprising the step of adding an antibacterially effective amount of an organosilicon quaternary ammonium compound to the rinse cycle of the laundering operation containing the fabrics in order to destroy bacteria and fungi causing the odor, the organosilicon quaternary ammonium compound being an organosilane having the formula selected from the group consisting of ##STR12## wherein, in each formula, Y is R or RO where each R is an alkyl radical of 1 to 4 carbon atoms or hydrogen;

a has a value of 0, 1 or 2;

R'"'"' is a methyl or ethyl radical;

R" is an alkylene group of 1 to 4 carbon atoms;

R'"'"'", R"" and R^v are each independently selected from a group consisting of alkyl radicals of 1 to 18 carbon atoms, --CH₂ CH₆ H₅, --CH₂ CH₂ OH, --CH₂ OH, and --(CH₂)_x NHC(O)R^vi wherein x has a value of from 2 to 10 and R^vi is a perfluoroalkyl radical having from 1 to 12 carbon atoms; and

X is chloride, bromide, fluoride, iodide, acetate or tosylate.

4. The method of claim 3 in which the organosilane is added to the rinse cycle in the form of an emulsion containing the organosilane active ingredient.

5. The method of claim 3 in which the organosilane is added to the rinse cycle in the form of a microemulsion containing the organosilane active ingredient.

6. The method of claim 3 in which the organosilane is added to the rinse cycle in admixture with a nonsilicon organic quaternary ammonium compound, the organosilane and the organic quaternary ammonium compound being added to the rinse cycle in an amount of about 0.01 percent by weight of the admixture based on the weight of the fabrics.

7. The method of claim 6 in which the organosilane and the organic quaternary ammonium compound are each present in the admixture in a ratio of about 5:

1.