Reference electrode and a pair of electrodes for detecting the acidity or basicity of oil

• US 5,146,169 A
• Filed: 09/13/1990
• Issued: 09/08/1992
• Est. Priority Date: 09/13/1989
• Status: Expired due to Term

• Current Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho (Toyota Motor Corporation), Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho (Toyota Motor Corporation), Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Inventors: Nakada, Masahiko, Oohori, Masae, Suzuki, Kenichi, Morishita, Shinya
• Primary Examiner(s): Harvey, Jack B.
• Application Number:
  US07/582,425
• Time in Patent Office: 726 Days
• Field of Search: 324/425, 324/438, 324/439, 324/71.1, 204/433
• US Class Current: 324/438
• CPC Class Codes: G01N 33/2876 Total acid number

Abstract

A reference electrode is formed of lead, zinc, tin, indium, cadmium, magnesium, or any alloy thereof. A pair of electrodes comprising the reference electrode and a responding electrode made of a conductive solid, when placed in oil, develop a potential difference varying with the acidity or basicity of the oil and thus enable the efficient determination of the acidity or basicity.

Claims

1. A pair of electrodes for detecting the acidity or basicity of oil in which a potential difference varies in response to the acidity or basicity of oil, comprising a reference electrode exhibiting no or little potential change in response to the acidity or basicity of oil and a responding electrode exhibiting potential change in response to the acidity or basicity of oil, said reference electrode being a metallic electrode formed of a base metal material selected from the group consisting of lead, zinc, tin, indium, cadmium, magnesium and an alloy thereof, and said responding electrode being a conductive solid electrode of a base metal material which is different from that of said reference electrode.

2. The pair of electrodes according to claim 1, wherein said conductive solid electrode has such a conductivity that an electromotive force between said conductive solid electrode and said reference electrode is detected by an external circuit.

3. The pair of electrodes according to claim 1, wherein said conductive solid electrode is formed of at least one material selected from the group consisting of a metal, carbon and a semiconductor.

4. The pair of electrodes according to claim 1, wherein said conductive solid electrode is formed of a metallic substrate with at least one of an oxide film and a nitride film formed thereon.

5. The pair of electrodes according to claim 4, wherein said oxide film and said nitride film have a thickness of at least 0.1 micron.

6. The pair of electrodes according to claim 4, wherein said metallic substrate is formed of at least one material selected from the group consisting of stainless steel, nickel, titanium, niobium, tantalum, zirconium and an alloy thereof.

7. The pair of electrodes according to claim 1, wherein said metallic electrode if formed of a material selected from the group consisting of lead, magnesium and an alloy thereof, said metallic electrode having a relationship between pH and the potential difference with an inclination opposite to that of the relationship in said responding electrode.

8. A method for detecting the acidity or basicity of oil in which a potential difference varies in response to the acidity or basicity of oil, comprising:

measuring the potential difference developed between a reference electrode and a responding electrode,

wherein said reference electrode is a metallic electrode formed of a base metal material selected from the group consisting of lead, zinc, tin, indium, cadmium, magnesium and an alloy thereof;

wherein said reference electrode exhibits little or no potential change in response to the acidity or basicity of oil; and

wherein said responding electrode is a conductive solid electrode of a base metal material which is different from that of said reference electrode.