Apparatus for pyrolysis of hydrocarbons

• US 5,147,511 A
• Filed: 11/29/1990
• Issued: 09/15/1992
• Est. Priority Date: 11/29/1990
• Status: Expired due to Fees

• Current Assignee: Stone & Webster Engineering Corporation (Brookfield Asset Management Incorporated)
• Original Assignee: Stone & Webster Engineering Corporation (Brookfield Asset Management Incorporated)
• Inventors: Woebcke, Herman N.
• Primary Examiner(s): Woodard, Joye L.
• Application Number:
  US07/619,740
• Time in Patent Office: 656 Days
• Field of Search: 196/110, 196/116, 196/134, 196/136, 196/138, 196/98, 422/188, 422/193, 422/196-198, 422/204
• US Class Current: 196/110
• CPC Class Codes: C10G 9/002 Cooling of cracked gases
• CPC Class Codes: C10G 9/20 Tube furnaces
• CPC Class Codes: F28D 2021/0075 for syngas or cracked gas cooling systems
• CPC Class Codes: F28D 7/12 the surrounding tube being closed at one end, e.g. return type F28D7/14 takes precedence

Abstract

An improved hydrocarbon pyrolysis process and apparatus for the production of ethylene comprising a novel furnace comprised of an unfired superheater radiant section and a fired radiant section, adiabatic tube reactor and quench boiler is provided.

Claims

1. A furnace for cracking hydrocarbon feed to produce olefins comprising:

an unfired radiant superheater chamber;

a fired radiant chamber;

radiant burners in the fired radiant chamber;

means for passing the flue gases from the radiant burners from the radiant chamber to the superheater chamber;

at least one process coil having an inlet in the superheater zone and extending continuously to an outlet located in the fired radiant chamber;

a convection chamber in direct communication with the radiant superheater chamber;

a flue for discharging the flue gas located at the top of said convection chamber;

convection tubes in the convection chamber upstream of and in direct communication with the inlet of the process coil; and

an adiabatic reactor located directly on top of said fired radiant chamber and having an inlet in direct communication with the process outlet in the fired radiant chamber.

2. A furnace as in claim 1 further comprising a single common wall between the superheater chamber and the radiant chamber and wherein the means for the gases to pass from the radiant chamber to the superheater chamber is an opening in the bottom of the wall between the superheater chamber and the radiant chamber.

3. A furnace as in claim 2 wherein the radiant burners are an array of radiant burners arranged along longitudinal walls of the radiant chamber and extending downwardly form a roof thereof.

4. A furnace as in claim 1 wherein a portion of said adiabatic reactor is configured in the form of a venturi.

5. A furnace as in claim 4 comprising wherein said at least one process coil comprises a plurality of process coils in adjacent relationship;

and said process coil outlet comprise means for manifolding the plurality of process coils into a single header at the inlet of the adiabatic reactor.

6. A furnace as in claim 4 further comprising an indirect quench boiler closely coupled to an exit of the adiabatic reactor.

7. A furnace as in claim 6 wherein the quench boiler is comprised of an annular outer cold chamber, a centrally disposed inner cold chamber and a hot chamber for the cracked product located therebetween.

8. A cracking furnace comprised of

a radiant chamber;

an adiabatic reactor downstream of and located directly on top of the radiant chamber;

a process coil means extending through the radiant chamber;

a process tube means within the adiabatic reactor; and

means for connecting the process coil means within the radiant chamber to the process tube means within the adiabatic reactor.

9. A cracking furnace as in claim 8 wherein the process coil means comprises a plurality of process coils;

and wherein the means for connecting the process coil means to the process tube means comprises a manifold comprising a means for pairing the process coils into single common conduits and manifolding the single common conduits into a header at an entry of the adiabatic reactor.

10. A cracking furnace as in claim 9 wherein said adiabatic reactor is configured whole or in part in the form of a venturi. PG,29

11. A cracking furnace as in claim 9 further comprising an indirect quench boiler closely coupled to the adiabatic reactor downstream of the adiabatic reactor.

12. A cracking furnace as in claim 11 wherein said quench boiler comprises an outer annular cold chamber, an internal cold chamber and an annular hot chamber for the cracked product located between the outer annular cold chamber and the internal cold chamber;

and further comprising a venturi between the exit of the adiabatic reactor and the annular hot chamber of the quench boiler.