Colorant based on carminic acid, method of preparation, and method of coloring a foodstuff

• US 5,147,673 A
• Filed: 08/16/1989
• Issued: 09/15/1992
• Est. Priority Date: 08/16/1989
• Status: Expired due to Term

• Current Assignee: Sensient Colors, LLC (Sensient Technologies Corporation)
• Original Assignee: Quimica Universal, S.A.
• Inventors: Schul, Jose
• Primary Examiner(s): Weinstein, Steven
• Assistant Examiner(s): Aberle, J.
• Application Number:
  US07/394,572
• Time in Patent Office: 1,126 Days
• Field of Search: 426/250, 426/540, 8/438
• US Class Current: 426/250
• CPC Class Codes: A23L 5/47 using synthetic organic dyes or pigments not covered by groups A23L5/43 - A23L5/46
• CPC Class Codes: A61K 2800/43 Pigments; Dyes
• CPC Class Codes: A61K 8/602 Glycosides, e.g. rutin
• CPC Class Codes: A61Q 1/02 Preparations containing skin colorants, e.g. pigments preparations in powder form A61Q1/12
• CPC Class Codes: C09B 61/00 Dyes of natural origin prepared from natural sources , e.g. vegetable sources

Abstract

A red colorant based on carminic acid which is substantially stable against color changes when exposed to acidic media and a method for preparing the same is disclosed wherein carminic acid is reacted with effective amounts of a nitrogenous base and an organic acid. In preferred embodiments, the colorant composition is edible and may be used in conjunction with pharmaceuticals, foods, and cosmetics.

Claims

1. A red colorant composition comprising the reaction product of carminic acid, an organic acid and a nitrogenous base, reacted to produce a colorant which is substantially stable against color changes when exposed to acidic media having a pH of about 1.74 or higher, said colorant having absorption wavelength peaks at about 567 and 538 nanometers when placed in a solution at a pH of about 9.5 and having absorption wavelength peaks at about 562, 560 and 529 nanometers when placed in a solution at a pH of about 1.74.

2. The colorant of claim 1 wherein the composition contains about 100 parts of carminic acid, from about 5 to about 30 parts nitrogenous base, and about 40 to about 180 parts organic acid.

3. The colorant of claim 2 wherein the composition contains about 100 parts of carminic acid, from about 10 to about 20 parts nitrogenous base and about 70 to 130 parts organic acid.

4. The colorant of claim 2 wherein said nitrogenous base comprises ammonium hydroxide, an amine or a mixture thereof.

5. The colorant of claim 4 wherein the organic acid comprises fumaric acid, citric acid, tartaric acid, malic acid, acetic acid, propionic acid, sorbic acid, lactic acid, succinic acid, adipic acid or a mixture thereof.

6. The colorant of claim 4 wherein said nitrogenous base comprises ammonium hydroxide and said organic acid comprises citric acid.

7. The colorant of claim 1 wherein the composition is essentially aluminum-free.

8. A colored food comprising a foodstuff in combination with an amount of the colorant of claim 1 effective for rendering said foodstuff red when at acid pH.

9. A colored beverage product comprising a drinkable liquid in combination with the colorant of claim 1 present in an amount effective for rendering the liquid red when at acid pH.

18. The method of claim 19 wherein the polyalcohol comprises propylene glycol.

19. A method of coloring a food comprising adding to a foodstuff a red colorant as described in claim 1 in an amount effective for coloring the foodstuff at acid pH having a pH of about 1.74 or higher, said colorant having absorption wavelength peaks at about 567 and 538 nanometers when placed in a solution at a pH of about 9.5 and having absorption wavelength peaks at about 562, 560 and 529 nanometers when placed in a solution at a pH of about 1.74.

23. The product of claim 18.

24. The product of claim 19.

10. An edible colorant for coloring a food or a drug comprising the reaction product of about 3 to 30% carminic acid, about 5 to 30% ammonium hydroxide and about 12% citric acid, said colorant being essentially free of aluminum.

11. A method for making a red colorant based on carminic acid, comprising reacting an aqueous solution of carminic acid with sufficient quantities of an organic acid and a nitrogenous base at a temperature and for a time period effective for forming a red colorant which is substantially stable against color change when exposed to acidic media having a pH of about 1.74 or higher, said colorant having absorption wavelength peaks at about 567 and 538 nanometers when placed in a solution at a pH of about 9.5 and having absorption wavelength peaks at about 562, 560 and 529 nanometers when placed in a solution at a pH of about 1.74.

12. The method of claim 11 wherein the carminic acid comprises from about 3 to about 30 percent w/w, the organic acid comprises from about 40 to about 180 percent w/w based on the quantity of carminic acid, and the nitrogenous base comprises from about 5 to about 30 percent w/w based on the quantity of carminic acid.

13. The method of claim 12 further comprising heating the carminic acid, organic acid and nitrogenous base at a temperature of about 80°

C. to about 120°

C. for about 10 to about 60 minutes.

14. The method of claim 13 wherein said organic acid comprises fumaric acid, citric acid, tartaric acid, malic acid, acetic acid, propionic acid, sorbic acid, lactic acid, succinic acid, adipic acid or a mixture thereof.

15. The method of claim 14 wherein said nitrogenous base comprises ammonium hydroxide, an amine, an amide or a mixture thereof.

16. The method of claim 15 further comprising spray drying the composition to form a powder.

17. The method of claim 16 further comprising mixing the powder with a suitable polyalcohol.

20. The product of claim 12.

21. The product of claim 14.

22. The product of claim 15.

25. A method of coloring a foodstuff comprising adding to the foodstuff a red colorant composition comprised of the reaction product of carminic acid, an organic acid and a nitrogenous base, said colorant being substantially color stable upon exposure to acidic media having a pH of about 1.74 or higher, said colorant having absorption wavelength peaks at about 567 and 538 nanometers when placed in a solution at a pH of about 9.5 and having absorption wavelength peaks at about 562, 560 and 529 nanometers when placed in a solution at a pH of about 1.74.