Method for bonding silicone rubber and polyurethane materials and articles manufactured thereby

• US 5,147,725 A
• Filed: 07/03/1990
• Issued: 09/15/1992
• Est. Priority Date: 07/03/1990
• Status: Expired due to Term

• Current Assignee: Corvita Corporation (Boston Scientific Corporation)
• Original Assignee: Corvita Corporation (Boston Scientific Corporation)
• Inventors: Pinchuk, Leonard
• Primary Examiner(s): LUSIGNAN, MICHAEL R
• Application Number:
  US07/548,285
• Time in Patent Office: 805 Days
• Field of Search: 428/425.5, 428/447, 427/387, 427/393.5
• US Class Current: 428/425.5
• CPC Class Codes: A61L 27/18 obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: A61L 27/34 Macromolecular materials
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 2483/00 Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
• CPC Class Codes: C08J 5/12 Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: Y10T 428/31598 Next to silicon-containing [silicone, cement, etc.] layer
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

A method for applying a silicone rubber material to polyurethane is described wherein a previously processed polyurethane material can be strongly bonded to a silicone rubber material. The silicone rubber material is applied to the polyurethane in a solution and is preferably an acetoxyterminated silicone material, a halogen-terminated silicone material or a combination thereof. The polyurethane and the silicone rubber material are heated at a temperature above about 70° C. to bond the two materials together more strongly than would otherwise occur in the absence of heat.

Claims

1. A method for applying a silicone rubber material, comprising:

supplying a base material having an exposed surface which includes a polyurethane;

applying an uncured silicone rubber material to said exposed polyurethane surface of the base material, said silicone rubber material being an acetoxy-terminated siloxane, a halogenterminated siloxane or a combination thereof said acetoxy and halogen moieties being bonded directly to silicon in said rubber material;

heating said base material at a temperature above about 70°

C. to condition said polyurethane surface for bonding said silicone rubber material to said polyurethane; and

curing said silicone rubber material;

whereby said heating of said base material provides a bond between said silicone rubber material and said polyurethane which is stronger than a bond which occurs between said polyurethane and said silicone rubber material in the absence of said heating step.

2. The method as defined in claim 1 wherein said heating of at least said base material is accomplished by heating above the second glass transition temperature of said polyurethane.

3. The method as defined in claim 1 wherein said silicone rubber material is applied to said base material as a solution consisting essentially of about 10% by weight of said silicone rubber material in a solvent, said solvent being formulated as a blend of about 90% fluorinated hydrocarbon and about 10% 1,1,1-trichloroethane.

4. The method as defined in claim 1 wherein said heating of said base material and said silicone rubber material is carried out at a temperature between about 100°

C. and about 130°

C. for a period of time between about 0.5 minutes and about 15 minutes.

5. The method as defined in claim 1 wherein said curing of said silicone rubber material is accomplished during said heating of said base material and said silicone rubber material.

6. The method as defined in claim 1 further comprising:

blowing air on said base material and silicone rubber material during said heating thereof.

7. A product including a polyurethane bonded to a silicone rubber material obtained by the method of claim 1.

8. A method for applying a silicone rubber material to a polyurethane surface, comprising:

supplying a base material having an exposed surface which includes a polyurethane;

applying a silicone rubber material to said base material, said silicone rubber material being an acetoxyterminated siloxane, a halogen-terminated siloxane or a combination thereof, said acetoxy and said halogen moieties are bonded to a silicon in said rubber material;

heating said base material at a temperature above about 70°

C. to condition said base material to bond said silicone rubber material to said polyurethane; and

whereby said heating of at least said base material provides a bond between said silicone rubber material and said polyurethane which is stronger than a bond which occurs between said polyurethane and said silicone rubber material in the absence of said heating step.

9. The method as defined in claim 8 wherein said silicone rubber material is applied to said base material as a solution consisting essentially of about 10% by weight of said silicone rubber material and a solvent, said solvent being formulated as a blend of about 90% fluorinated hydrocarbon and about 10% 1,1,1-trichloroethane.

10. The method as defined in claim 8 wherein said heating of said base material and said silicone rubber material is carried out at a temperature between about 100°

C. and about 130°

C. for a period of time between about 0.5 minutes and about 15 minutes.

11. The method as defined in claim 8 wherein said curing of said silicone rubber material is accomplished during said heating of said base material and said silicone rubber material.

12. The method as defined in claim 8 further comprising:

blowing air on said base material and said silicone rubber material during said heating thereof.

13. A product including a polyurethane bonded to a silicone rubber material obtained by the method of claim 9.

14. The method as defined in claim 8 wherein said heating of at least said base material is accomplished by heating above the second glass transition temperature of said polyurethane.

15. In a method for applying a solution containing a silicone rubber material to a polyurethane to bond the silicone rubber material to the polyurethane, the improvement comprising:

heating a polyurethane material at a temperature above about 70°

C. to bond the silicone rubber material to said polyurethane, said heating of said polyurethane, said heating of said polyurethane providing a bond between said silicone rubber material and said polyurethane which is stronger than a bond between said polyurethane and said silicone rubber material which occurs in the absence of said heating step, said silicone rubber material being an acetoxy-terminated siloxane, a halogen-terminated siloxane or a combination thereof, said acetoxy and halogen moieties being bonded directly to silicon in said rubber materials; and

blowing hot air on said base material and said rubber material during said heating step.

16. The method as defined in claim 15 wherein said silicone rubber material is applied to said base material as a solution consisting essentially of about 10% by weight of said silicone rubber material in a solvent, said solvent being formulated as a blend of about 90% fluorinated hydrocarbon and about 10% 1,1,1-trichloroethane.

17. The method as defined in claim 15 wherein said heating of said base material and said silicone rubber material is carried out at a temperature between about 100°

C. and about 130°

C. for a period of time between about 0.5 minutes and about 15 minutes.

18. A product including a polyurethane bonded to a silicone rubber material obtained by the method of claim 15.

19. The method as defined in claim 15 wherein said heating of said polyurethane material is accomplished by heating above the second glass transition temperature of said polyurethane.