Method for determining the end of useful life of an inert gas purifier and apparatus therefore

• US 5,150,604 A
• Filed: 11/13/1990
• Issued: 09/29/1992
• Est. Priority Date: 01/05/1990
• Status: Expired due to Fees

• Current Assignee: SAES Getters SpA (SAES Getters S)
• Original Assignee: SAES Getters SpA (SAES Getters S)
• Inventors: Succi, Marco, Doni, Fabrizio
• Primary Examiner(s): Williams, Hezron E.
• Assistant Examiner(s): ROSKOS, JOSEPH
• Application Number:
  US07/611,652
• Time in Patent Office: 686 Days
• Field of Search: 73/19.05, 73/38, 73/31.04, 73/861.63, 116/268, 116/DIG. 25, 340/611
• US Class Current: 73/38
• CPC Class Codes: B01D 53/0454 Controlling adsorption controlling temperature swing adsorption B01D53/0462, controlling pressure swing adsorption B01D53/047
• CPC Class Codes: Y10S 116/25 Air filter condition indicator

Abstract

The present invention provides a process, and an apparatus for accomplishing that process, for indicating when an inert gas purifier is about to loose its required level of purification efficiency. The inert gas purifier can therefore be replaced before the impurity levels of its purified output gas reach undesirably high values.

Claims

1. An apparatus for determining the end of useful life of an inert gas purifier (104) having an impure inert gas inlet (106) in fluid communication with a housing (108) containing a gas sorbing material (110), said housing being in fluid communication with a purified gas outlet (112), said apparatus comprising:

A. a means (114) for measuring the gas pressure (P1) at the inlet (106), and

B. a means (116) for measuring the gas pressure (Po) at the outlet (112); and

C. a means (118) for determining the gas pressure difference (Pd=P1-Po) between the inlet (106) and the outlet (112); and

D. a means (120) for comparing (Pd) with a predetermined pressure value (Pp) and indicating when Pd is greater than Pp thus indicating that the inert gas purifier (104) has reached the end of useful life

in which the predetermined pressure value (Pp) is that value corresponding to the pressure difference (Pd) when the impurity level of the purified gas reaches a critical value above which the purified gas is considered insufficiently pure.

2. An apparatus of claim 1 in which the means (114) for measuring the gas pressure (P₁) at the inlet (106) indicates the pressure in terms of an electric signal.

3. An apparatus of claim 1 in which the means (116) for measuring the gas pressure (P_o) at the outlet (112) indicates the pressure in terms of an electric signal.

4. An apparatus of claim 1 in which the means (118) for determining the gas pressure difference (P_d) gives a measurement of the difference in terms of an electric signal.

5. An apparatus of claim 1 in which the means (120) for comparing (P_d) with the predetermined pressure value (P_p) indicates when P_d >

P_p in terms of an electric signal.

7. An apparatus of claim 1 in which the predetermined pressure value (P_p) is chosen to be between that value at which the impurity level of the purified gas starts to increase and that value corresponding to the pressure difference (P_d) when the impurity level of the purified gas reaches a critical value above which the purified gas is considered insufficiently pure.

8. An apparatus of claim 1 in which the gas sorbing material (110) is chosen from the group consisting of zirconium based alloys and titanium based alloys.

9. An apparatus of claim 1 in which the gas sorbing material (110) is an alloy of Zr-V-Fe when the inert gas is He, Ne, Ar, Kr or Xe.

10. An apparatus of claim 1 in which the gas sorbing material (110) is an alloy of Zr-Fe when the inert gas is N₂.

6. An apparatus of claim 6 in which the predetermined pressure value (P_p) is a value less than that corresponding to the pressure difference (P_d) when the impurity level of the purified gas reaches a critical value above which the purified gas is considered insufficiently pure.

11. An apparatus for determining the end of useful life of an inert gas purifier (104) having an impure inert gas inlet (106) in fluid communication with a housing (108) containing an alloy of Zr-V-Fe when the inert gas to be purified is He, Ne, Ar, Kr or Xe or an alloy of Zr-Fe when the inert gas to be purified is in N₂ , said housing (108) being in fluid communication with a purified gas outlet (112) said apparatus comprising:

A. means (114) for measuring the gas pressure (P₁) at the inlet (106) said means indicating the pressure in terms of an electric signal; and

B. means (116) for measuring the gas pressure (P_p) at the outlet (112) said means indicating the pressure in terms of an electric signal; and

C. means (118) for determining the gas pressure difference (P_d =P_i -P_o) between the inlet (106) and the outlet (112) in terms of an electric signal; and

D. means (120) for comparing P_d with a predetermined pressure value (P_p) and indicating when P_d >

P_p in terms of an electric signal which indicates that the inert gas purifier (104) has reached the end of useful life where (P_p) is chosen to be between that value at which the impurity level of the purified gas starts to increase and that value corresponding to the pressure difference (P_d) when the impurity level of the purified gas reaches a critical value above which the purified gas is considered insufficiently pure.

12. A method for determining the end or useful life of an inert gas purifier having an impure inert gas inlet in fluid communication with a housing containing a gas sorbing material, said housing being in fluid communication with a purified gas outlet said method comprising the steps of:

A. measuring the gas pressure (P1) at the inlet; and

B. measuring the gas pressure (Po) at the outlet; and

C. determining the gas pressure difference (Pd=P1-Po) between the inlet and the outlet; and

D. comparing Pd with a predetermined pressure value Pp and indicating when Pd is greater than Pp to indicate that the inert gas purifier has reached the end of useful life

in which the predetermined pressure value (Pd) when the impurity level of the purified gas reaches a critical value above which the purified gas is considered insufficiently pure.

13. A method of claim 12 in which measuring of the gas pressure (P₁) at the inlet indicates the pressure in terms of an electric signal.

14. A method of claim 12 in which the measuring of the gas pressure (P_o) at the inlet indicates the pressure in terms of an electric signal.

15. A method of claim 12 in which the determining of the gas pressure difference gives measurement of the difference in terms of an electric signal.

16. A method of claim 12 in which comparing (P_d) with the predetermined pressure value (P_p) indicates when P_d >

P_o in terms of an electric signal.

17. A method of claim 12 in which the predetermined pressure value (P_p) is a value less than that corresponding to the pressure difference (P_d) when the impurity level of the purified gas reaches a critical value above which the purified gas is considered insufficiently pure.

18. A method of claim 12 in which the predetermined pressure value (P_p) is chosen to be between that value at which the impurity level of the purified gas starts to increase and that value corresponding to the pressure difference (P_d) when the impurity level of the purified gas reaches a critical value above which the purified gas is considered insufficiently pure.

19. A method of claim 12 in which the gas sorbing material in an alloy of Zr-V-Fe when the inert gas is He, Ne, Ar, Kr or Xe.

20. A method of claim 12 in which the gas sorbing material is an alloy of Zr-Fe when the inert gas is N₂.

21. A method for determining the end of useful life of an inert gas purifier having an impure inert gas inlet in fluid communication with a housing containing an alloy of Zr-V-Fe when the inert gas to be purified is He, Ne, Ar, Kr or Xe or an alloy of Zr-Fe when the inert gas to be purified is N₂, said housing being in fluid communication with a purified gas outlet said method comprising the steps of:

A. measuring he gas pressure (P₁) at the inlet by a means which indicates the pressure in terms of an electric signal; and

B. measuring the gas pressure (P_p) at the outlet by a means which indicates the pressure in terms of an electric signal; and

C. determining the gas pressure difference (P_d =P₁ -P_o) between the inlet and the outlet in terms of an electric signals; and

D. comparing P_d with a predetermined pressure value (P_p) which when P_d >

P_p in terms of an electric signal which indicates that the inert gas purifier has reached the end of useful life where P_p is chosen to be between that value at which the impurity level of the purified gas starts to increase and that value corresponding to the pressure difference when the impurity level of the purified gas reaches a critical value above which the purified gas is considered insufficiently pure.