Amine-based consistency reducers for gypsum stucco slurries

• US 5,151,130 A
• Filed: 01/23/1991
• Issued: 09/29/1992
• Est. Priority Date: 01/23/1991
• Status: Expired due to Fees

• Current Assignee: Huntsman Ethyleneamines LLC (Huntsman Corporation)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Croft, Alan P., Koblinski, Brian D.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): Marcheschi, Michael A.
• Application Number:
  US07/644,727
• Time in Patent Office: 615 Days
• Field of Search: 106/772, 106/775, 106/778, 106/802, 106/819, 106/823, 106/827, 501/141, 524/446, 524/447, 156/39, 156/40, 156/42, 156/43, 156/44, 156/46
• US Class Current: 106/778
• CPC Class Codes: C04B 2103/302 Water reducers
• CPC Class Codes: C04B 24/121 Amines, polyamines
• CPC Class Codes: C04B 28/14 containing calcium sulfate cements gypsum-paper plates E04C

Abstract

A method for reducing the consistency of a water and gypsum stucco slurry comprising admixing water, stucco, and an additive, the additive in an amount effective to reduce the consistency of the admixed slurry as compared to a slurry containing only water and stucco, and the additive selected from the group consisting of one or more polyalkylene polyamines having a molecular weight below 1,000.

Claims

1. A method for reducing the consistency of a water and stucco slurry comprising admixing water, stucco, and an additive, the additive in an amount effective to reduce the consistency of the admixed slurry as compared to a slurry containing only water and stucco, and the additive comprising one or more polyalkylene polyamines having a molecular weight below 1,000.

2. The method of claim 1 wherein the amount is between about 0.01 ppm and about 10,000 ppm.

3. The method of claim 1 wherein the amount of additive is between about 750 ppm and about 6,000 ppm.

4. The method of claim 1 wherein the additive is selected from the group consisting of ethylene-diamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, piperazine, and mixtures thereof.

5. The method of claim 4 wherein the amount is between about 0.01 ppm and about 10,000 ppm.

6. The method of claim 4 wherein the amount is between about 750 ppm and about 6,000 ppm.

7. The method of claim 1 wherein the additive comprises piperazine.

8. The method of claim 7 wherein the amount of additive is between about 0.01 ppm and about 10,000 ppm.

9. The method of claim 7 wherein the amount of additive is between about 750 ppm and about 6,000 ppm.

10. In a method of making gypsum wallboard wherein (1) water and stucco are admixed to produce a slurry, (2) the slurry is deposited between two barriers to produce a board, and (3) the board is heated after the slurry begins to set, the improvement which comprises

admixing an additive with the water and stucco in step (1), the additive in an amount effective to reduce the consistency of the admixed slurry as compared to a slurry containing only water and stucco, and the additive comprising one or more polyalkylene polyamines having a molecular weight below 1,000.

11. The method of claim 10 wherein the amount is between about 0.01 ppm and about 10,000 ppm.

12. The method of claim 10 wherein the amount of additive is between about 750 ppm and about 6,000 ppm.

13. The method of claim 10 wherein the additive is selected from the group consisting of ethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, piperazine, and mixtures thereof.

14. The method of claim 13 wherein the amount is between about 0.01 ppm and about 10,000 ppm.

15. The method of claim 14 wherein the amount is between about 750 ppm and about 6,000 ppm.

16. The method of claim 10 wherein the additive comprises piperazine.

17. The method of claim 16 wherein the amount of additive is between about 0.01 ppm and about 10,000 ppm.

18. The method of claim 16 wherein the amount of additive is between about 750 ppm and about 6,000 ppm.

19. A method for reducing the consistency of a water and stucco slurry comprising admixing water, stucco, and an additive, the additive in an amount between about 0.01 ppm and about 10,000 ppm, and the additive comprising piperazine, ethylenediamine, ethanolamine, triethylenediamine, and diethylenetriamine.