Adhesive composition having improved cutting properties

• US 5,154,974 A
• Filed: 09/29/1989
• Issued: 10/13/1992
• Est. Priority Date: 06/23/1986
• Status: Expired due to Term

• Current Assignee: Alfred W. Norman, Carolyn M. Ricci
• Original Assignee: Alfred W. Norman, Carolyn M. Ricci
• Inventors: Ricci, Carolyn M., Norman, Alfred W.
• Primary Examiner(s): Davis, Jenna L.
• Application Number:
  US07/415,421
• Time in Patent Office: 1,110 Days
• Field of Search: 524/267, 524/269, 524/272, 525/106
• US Class Current: 428/355.00R
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C09J 133/06 of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
• CPC Class Codes: C09J 2301/302 the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
• CPC Class Codes: C09J 7/385 Acrylic polymers
• CPC Class Codes: Y10T 428/2852 Adhesive compositions
• CPC Class Codes: Y10T 428/2891 including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

Adhesives compositions having improved cutting properties described herein. Compositions comprise a normally tacky, pressure sensitive acrylic adhesive containing, as an additive to reduce edge flow, from about 2 to about 10 percent by weight dry basis, preferably from about 5 to about 8 percent by weight dry basis based on the weight of polymer solids, of a polydimethylsiloxane having a number average molecular weight of about 1300 to about 15000. Also disclosed are laminates comprising a facing layer coated on one side with the aforedescribed adhesive composition, and optionally a release liner. These adhesive laminates exhibit substantially reduced tendency of the adhesive to ooze at the edge when cut, without material decrease in other adhesive properties, when a multiplicity of laminate sheets is stacked and cut by means of a guillotine. Laminates herein are especially useful as drum and carton labels.

Claims

1. A water emulsion pressure sensitive adhesive exhibiting quick tack and 30 minute peel adhesion sufficient to adhere to a fiber or corrugated container and freedom from adhesive edge flow and undesired slippage comprising:

(a) a water dispersible pressure sensitive adhesive acrylic polymer;

(b) a first surfactant system having at least one surfactant adapted to stabilize a dispersion of said acrylic polymer being selected from the class consisting of cationic, anionic and nonionic surfactants;

(c) an emulsifiable polydimethylsiloxane in an amount of from about 2 to about 10 percent by weight on the dry basis, based on the weight of acrylic polymer solids, said polydimethylsiloxane having a number average molecular weight in the range of about 1,300 to about 15,000;

(d) a second surfactant system having at least one surfactant adapted to stabilize an emulsion of said polydimethylsiloxane and being selected from the class consisting of cationic, anionic and nonionic surfactants; and

(e) water;

wherein the polydimethylsiloxane is compatible with the acrylic polymer and the surfactant systems,

said adhesive emulsion, when coated onto a facing layer and dried, forming a normally tacky essentially pinhole free adhesive film having reduced tendency to flow when cut and about the same quick tack adhesion as the same acrylate adhesive film in which the polydimethylsiloxane is absent.

2. An adhesive emulsion according to claim 1 in which said polydimethylsiloxane has a number average molecular weight in the range of about 4,000 to about 11,000.

3. An adhesive emulsion according to claim 1 in which said polydimethylsiloxane has the formula ##STR2## where R is a methyl or a hydroxyl radical and n is from about 11 to about 200.

4. An adhesive emulsion according to claim 3 in which n is from about 50 to about 150.

5. An adhesive emulsion according to claim 1 in which the amount of said polydimethylsiloxane is from about 5 to about 8 percent by weight on the dry basis, based on the weight of polymer solids.

6. An adhesive emulsion according to claim 1 in which said acrylic polymer is not water soluble.

7. An adhesive emulsion according to claim 1 in which said acrylic polymer on drying gives a permanent adhesive.

8. An adhesive laminate comprising a facing layer having a dry normally tacky pressure sensitive acrylic adhesive coating on at least one surface thereof, said coating comprising a water dispersible pressure sensitive adhesive acrylic polymer, a first surfactant system to stabilize a dispersion of said polymer, an emulsifiable polydimethylsiloxane in an amount of from about 2 to about 10 percent by weight on the dry basis, based on the weight of acrylic polymer solids which is compatible with said adhesive acrylic polymer and which has a number average molecular weight in the range of about 1,300 to about 15,000, and a second surfactant system to stabilize an emulsion of said polydimethylsiloxane, said coating having a reduced tendency to flow when cut and about the same initial peel adhesion as the same acrylic adhesive coating in which said polydimethylsiloxane is absent, wherein the polydimethylsiloxane is compatible with the acrylic polymer and the surfactant systems and said first and second surfactants being selected from the class of cationic, anionic nonionic surfactants.

9. A laminate according to claim 8 in which said polydimethylsiloxane has a number average molecular weight in the range of about 4,000 to about 11,000.

10. A laminate according to claim 8 in which said polydimethylsiloxane has the formula ##STR3## where R is a methyl or a hydroxyl radical and n is from about 11 to about 200.

11. A laminate according to claim 10 in which n is from about 50 to about 150.

12. A laminate according to claim 8 in which said acrylic polymer is a permanent adhesive.

13. A laminate according to claim 8 in which said first surfactant systems comprises at least one surfactant.

14. A laminate according to claim 8 in which said second surfactant systems comprises at least one surfactant.

15. A dry, normally tacky adhesive film derived from an aqueous emulsion that exhibits quick tack and 30 minute peel adhesion sufficient to adhere to a fiber drum and freedom from adhesive edge flow, said film comprising:

(a) a water dispersible pressure sensitive acrylic polymer which is water insoluble;

(b) a first surfactant system having at least one surfactant adapted to stabilize the dispersion of said polymer;

(c) an emulsifiable polydimethylsiloxane in an amount of from about 2 to about 10 percent by weight on the dry basis, based on the weight of acrylic polymer solids which is compatible with said acrylic polymer, said polydimethylsiloxane having a number average molecular weight in the range from about 1,300 to about 15,000; and

(d) a second surfactant system having at least one surfactant to stabilize the emulsion of said polydimethylsiloxane which is compatible with said first surfactant system said surfactants being selected from the class of cationic, anionic and nonionic surfactants;

wherein the polydimethylsiloxane is compatible with the acrylic polymer and the surfactant systems; and

said film having reduced tendency to flow when cut and about the same initial adhesion and 30 minute peel adhesion as the same acrylate adhesive film in which said polydimethylsiloxane is absent.

16. A film according to claim 15 in which said film is deposited as a substantially homogeneous coating on at least one surface of a facing layer.

17. A film according to claim 15 in which said film is adhered to a facing layer.