Process for starting-up an ethylene oxide reactor

• US 5,155,242 A
• Filed: 12/05/1991
• Issued: 10/13/1992
• Est. Priority Date: 12/05/1991
• Status: Expired due to Term

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Patel, Jitendra G., Johnson, Beamon M., Shankar, Pettai K.
• Primary Examiner(s): EVANS, JOSEPH
• Application Number:
  US07/802,574
• Time in Patent Office: 313 Days
• Field of Search: 549/534
• US Class Current: 549/534
• CPC Class Codes: B01J 19/0006 Controlling or regulating processes controlling or regulating in general G05
• CPC Class Codes: B01J 2208/00548 Flow
• CPC Class Codes: B01J 8/02 with stationary particles, e.g. in fixed beds
• CPC Class Codes: C07D 301/10 with catalysts containing silver or gold

Abstract

This invention relates to a process for starting up a fixed bed ethylene oxide reactor containing a supported silver catalyst promoted with one or more alkali metal promoter(s) which involves heating the reactor to slightly below normal operating conditions, passing an ethylene containing gas over the catalyst, adding a chlorohydrocarbon moderator to the gas passing over the catalyst and after approximately 0.1-5 milliliters of moderator (basis liquid) per cubic foot of catalyst has been added, then adding oxygen to the gas passing over the catalyst to initiate the ethylene oxidation reaction and subsequently raising the reactor temperature and gas flow rates to operating conditions.

Claims

1. A process for starting up a fixed bed ethylene oxide reactor containing a catalyst consisting essentially of silver and one or more alkali metal promoter(s) supported on an alumina carrier, which process comprises:

a) heating the reactor to a temperature between about 350°

F. and 475°

F.,

b) passing an ethylene-containing gas over the catalyst in the reactor,

c) adding a chlorohydrocarbon moderator to the gas passing over the catalyst and after an amount of moderator containing the chlorine equivalent found in about 0.1 to about 5 milliliters (basis liquid) of ethyl chloride per cubic foot of the catalyst has been added, then

d) adding oxygen to the gas passing over catalyst, and adjusting the reactor temperature and gas flow rates to operating design conditions.

2. The process of claim 1 wherein in step b) the ethylene-containing gas is passed over the reactor at a flow rate above 5 percent of the design flow rate.

3. The process of claim 2 wherein in step b) the ethylene-containing gas is passed over the reactor at a flow rate above 15 percent of the design flow rate.

4. The process of claim 1 wherein in step b) the ethylene-containing gas also contains nitrogen or methane.

10. The process of claim 1 wherein in step c) from about, 0.5 to about 2 milliliters of moderator per cubic feet of catalyst been added.

11. The process of claim 10 wherein from about 1 to about 1.5 milliliters of moderator per cubic feet of catalyst has been added.

12. The process of claim 1 wherein in step c) the moderator is added over a period of time ranging from about 0.5 to about 15 hours.

13. The process of claim 1 wherein in step c) the moderator is added at a rate sufficient to maintain a concentration of about 1-10 ppmv in the gas passing over the catalyst.

14. The process of claim 1 wherein in step d) the reactor temperature and gas flow rates are raised to operating conditions over a period of time after the start of the oxygen addition ranging from about 24 hours to about 60 hours.

15. The process of claim 1 wherein nitrogen gas is passed over the catalyst prior to passing ethylene-containing gas of step b) over the catalyst.

16. The process of claim 15 wherein the nitrogen is passed over the catalyst for a period of time ranging from about 1/2 to about 7 days.

5. The process of claim wherein the chlorohydrocarbon moderator is a C₁ to C₈ chlorohydrocarbon.

6. The process of claim 5 wherein the chlorohydrocarbon moderator is a C₁ to C₄ chlorohydrocarbon.

7. The process of claim 6 wherein the chlorohydrocarbon moderator is a C₁ or C₂ chlorohydrocarbon.

8. The process of claim 7 wherein the chlorohydrocarbon moderator is selected from the group consisting of methyl chloride, ethyl chloride, ethylene dichloride, vinyl chloride and mixtures thereof.

9. The process of claim 8 wherein the chlorohydrocarbon moderator is ethyl chloride.