Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index

• US 5,157,191 A
• Filed: 09/09/1991
• Issued: 10/20/1992
• Est. Priority Date: 01/03/1986
• Status: Expired due to Fees

• Current Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Shihabi, David S., Bowes, Emmerson
• Primary Examiner(s): PAL, ASOKKUMAR
• Application Number:
  US07/756,668
• Time in Patent Office: 407 Days
• Field of Search: 585/533
• US Class Current: 585/533
• CPC Class Codes: B01J 2229/16 to increase the Si/Al ratio; Dealumination
• CPC Class Codes: B01J 2229/36 Steaming
• CPC Class Codes: B01J 2229/37 Acid treatment
• CPC Class Codes: B01J 29/40 of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
• CPC Class Codes: B01J 29/65 of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
• CPC Class Codes: B01J 29/70 of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
• CPC Class Codes: C10G 50/02 of hydrocarbon oils for lubricating purposes

Abstract

The catalytic activity of a crystalline aluminosilicate zeolite having a Constraint Index of from about 1 to about 12 for a variety of hydrocarbon conversions including the oligomerization of olefins to provide high viscosity index lubes is significantly enhanced by modifying the catalyst to reduce surface acid sites. This is accomplished by contacting the zeolite with a fluorosilicate salt to extract surface zeolitic aluminum which is replaced by silicon.

Claims

1. A process for the production of high viscosity index lubricating oils in high yields from lower olefin, said process comprising the steps of:

(i) contacting said olefin with a modified crystalline aluminosilicate zeolite catalyst under conditions sufficient to provide a product comprising a lubricating oil; and

(ii) recovering said lubricating oil, said modified crystalline aluminosilicate zeolite being prepared by contacting aluminosilicate zeolite with aqueous fluorosilicate salt to extract external zeolitic aluminum therefrom, without affecting the internal structure of the zeolite, said zeolite being selected from the group consisting of ZSM=5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, ZSM-35, ZSM-38 and ZSM-48.

2. The process of claim 1, wherein the zeolite is in the ammonium form.

3. The process of claim 2, wherein the thus-contacted zeolite is further treated to provide the hydrogen form.

4. The process of claim 1, wherein the fluorosilicate salt is represented by the formula:

space="preserve" listing-type="equation">(A).sub.2/b SiF.sub.6

wherein A is a metallic or non-metallic cation other than H⁺ having the valence b.

5. The process of claim 4, wherein A is alkylammonium, NH₄⁺, Mg⁺⁺, Li⁺, Na⁺, K⁺, Ba⁺⁺, Cd⁺⁺, Cu⁺, Ca⁺⁺, Cs⁺, Fe⁺⁺, Co⁺⁺, Pb⁺⁺, Mn⁺⁺, Rb⁺, Ag⁺, Sr⁺⁺, Tl⁺ and Zn⁺⁺.

6. The process of claim 1, wherein the fluorosilicate salt is (NH₄)₃ SiF₆.

7. The process of claim 1, wherein the olefin is selected from the group consisting of propylene and butylene.

8. The process of claim 1, wherein said lubricating oil is a 650°

F.⁺ lubricating oil.

9. The process of claim 8 further comprising the step of determining the viscosity index of said lubricating oil.

10. The process of claim 1, wherein said zeolite has a silica to alumina mole ratio of 100 or less.

11. The process of claim 1, wherein said zeolite has a silica to alumina mole ratio of 20 or more.

12. The process of claim 1, wherein said contacting takes place in the absence of an aluminum-containing binder material.

13. The process of claim 1, wherein said zeolite is binder-free.