Thermoplastic resin composition

• US 5,159,004 A
• Filed: 11/17/1989
• Issued: 10/27/1992
• Est. Priority Date: 11/18/1988
• Status: Expired due to Fees

• Current Assignee: Sumitomo Chemical Company Limited
• Original Assignee: Sumitomo Chemical Company Limited
• Inventors: Harada, Hiroyuki, Maruyama, Takashi, Furuta, Motonobu
• Primary Examiner(s): Ziegler, Jacob
• Application Number:
  US07/437,894
• Time in Patent Office: 1,075 Days
• Field of Search: 525/68, 525/92, 525/93, 525/905, 525/70, 524/508, 524/490, 524/504, 524/506
• US Class Current: 524/390
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/06 grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
• CPC Class Codes: C08L 59/00 Compositions of polyacetals; Compositions of derivatives of polyacetals of polyvinyl acetals C08L29/14
• CPC Class Codes: C08L 61/06 of aldehydes with phenols
• CPC Class Codes: C08L 67/00 Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08L77/12; of polyester-imides C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• CPC Class Codes: C08L 71/123 not modified by chemical after-treatment
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 81/02 Polythioethers; Polythioether-ethers
• CPC Class Codes: C08L 81/06 Polysulfones; Polyethersulfones
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: Y10S 525/905 Polyphenylene oxide

Abstract

Disclosed herein is a thermoplastic resin composition which comprises:

(a) polyphenylene ether or a composition containing polyphenylene ether,

(b) (i) a modified propylene polymer grafted with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with the styrene-based monomer, or (ii) a composition containing said modified propylene polymer and a propylene polymer,

(c) a rubbery substance, and at least one component selected from the following three components;

(d) a styrene resin having a melt index of 8 or above (at 250° C. under a load of 5 kg),

(e) a low-molecular weight hydrocarbon resin, and

(f) white oil and/or liquid paraffin.

This thermoplastic resin composition exhibits not only good moldability but also well-balanced physical properties and heat resistance, and can be easily processed into molded articles having outstanding physical properties.

Claims

1. A thermoplastic resin composition which comprises:

(a) polyphenylene ether or a composition containing polyphenylene ether,

(b) (i) a modified propylene polymer grafted with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with said styrene-based monomer, or (ii) a composition containing said modified

propylene polymer and a propylene polymer,

(c) a rubbery substance, wherein said substance is a natural or synthetic polymeric material which is elastic at room temperature, and at least one component selected from the group consisting of

(d) a styrene-based resin having a melt index of 8 or above (at 250°

C. under a load of 5 kg),

(e) a low-molecular weight hydrocarbon resin,

(f) white oil, and

(g) liquid paraffin.

7. A thermoplastic resin composition as claimed in claim 1, 2, 3, 4, or 6, wherein said low-molecular weight hydrocarbon resin component (e) is at least one member selected from the group consisting of rosin resin, terpene resin, coumarone-indene resin, alicyclic saturated hydrocarbon resin, aromatic hydrocarbon resin, and hydrogenated or modified products thereof.

8. A thermoplastic resin composition as claimed in claim 7, wherein said low-molecular weight hydrocarbon resin component (e) is one which has a molecular weight of 200 to 5000.

10. A thermoplastic resin composition as claimed in claim 1, 2, 3, 4, or 9, wherein component (f) and component (g) are white oil and liquid paraffin, respectively, having a viscosity of 40 to 400 (SUS second) at 37.8°

C. conforming to JIS K-2283.

11. A thermoplastic resin composition as claimed in anyone of claims 1-6 o r 9, wherein said propylene polymer is a highly crystalline propylene homopolymer or block copolymer wherein the fraction of propylene homopolymer contains boiling heptane insolubles whose isotactic pentad ratio is higher than 0.970.

12. A thermoplastic resin composition as claimed in any one of claims 1-6 or 9, wherein said propylene polymer is a highly crystalline propylene homopolymer or block copolymer wherein the fraction of propylene homopolymer contains boiling heptane insolubles whose isotactic pentad ratio is higher than 0.970 and also contains less than 5.0 wt% of boiling heptane solubles and less than 2.0 wt% of xylene (20°

C.) solubles.

13. A thermoplastic resin composition as claimed in any one of claims 1-6 or 9, wherein said propylene polymer composition is one which is obtained by blending a propylene polymer with a vinylcycloalkane polymer having 6 or more carbon atoms and contains 0.05 to 10000 ppm (by weight) of vinylcycloalkane units.

14. A thermoplastic resin composition as claimed in any one of claims 1-6 or 9, wherein said rubbery substance component (c) is one which contains at least one component selected from the group consisting of ethylene-α

-olefin copolymers and modified products thereof, ethylene-propylene-unsaturated diene rubbers and modified products thereof, butadiene-styrene copolymers and hydrogenated products thereof, and epoxy group-containing copolymers.

15. A thermoplastic resin composition as claimed in claim 14, wherein said ethylene-α

-olefin copolymer rubber is one which contains 15 to 85 wt% of ethylene and has a Mooney viscosity ML₁₊₄ (121°

C.) of 5 to 120 and a glass transition point lower than -10°

C.

16. A thermoplastic resin composition as claimed in any one of claim 1-6 or 9, wherein said polyphenylene ether component (a) is one which is obtained by the oxidative coupling polymerization of one or more than one phenol compound represented by the general formula below, ##STR11## where R₁, R₂, R₃, R₄, and R₅ each independently denotes a hydrogen atom, a halogen atom, a hydrocarbon group or substituted hydrocarbon group, or a hydrocarbyloxy group or substituted hydrocarbyloxy group;

and at least one of R₁ to R₅ is invariably a hydrogen atom.

17. Automotive parts which are made of the thermoplastic resin composition claimed in claim 1.

18. Automotive parts as claimed in claim 17 which include those selected from the group consisting of a bumper, instrument panel, fender, trim, door panel, wheel cap, side protector, side seal garnish, trunk lid, hood, quarter panel, air intake, lower apron, spoiler, front grille, radiator grille, mirror housing, air cleaner, core material of seat, glove box, console box, cooling fan, sirocco fan, brake oil tank, lamp housing, and roof.

2. A thermoplastic resin composition which comprises:

(a) polyphenylene ether or a composition containing polyphenylene ether,

(b) (i) a modified propylene polymer grafted with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with said styrene-based monomer, or (ii) a composition containing said modified propylene polymer and a propylene polymer,

(c) a rubbery substance, wherein said substance is a natural or synthetic polymeric material which is elastic at room temperature, and at least one component selected from the group consisting of

(d) A styrene-based resin having a melt index of 8 or above (at 250°

C. under a load of 5 kg),

(e) a low-molecular weight hydrocarbon resin,

(f) white oil, and

(g) liquid paraffin, the ratio of component (a) to component (b) being 1-90 wt% to 99-10 wt%, the amount of component (c) being 1-50 parts by weight per 100 parts by weight of the total amount of components (a) and (b), and the total amount of components (d), (e), and (f) being 0.1-50 parts by weight per 100 parts by weight of the total amount of components (a), (b), and (c).

3. A thermoplastic resin composition which comprises:

(a) polyphenylene ether or a composition containing polyphenylene ether,

(b) (i) a modified propylene polymer grafted with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with said styrene-based monomer, or (ii) a composition containing said modified propylene polymer and a propylene polymer,

(c) a rubbery substance, wherein said substance is a natural or synthetic polymeric material which is elastic at room temperature, and at least one component selected from the group consisting of

(e) a low-molecular weight hydrocarbon resin,

(f) white oil, and

(g) liquid paraffin.

4. A thermoplastic resin composition which comprises:

(a) polyphenylene ether or a composition containing polyphenylene ether,

(b) (i) a modified propylene polymer grafted with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with said styrene-based monomer, or (ii) a composition containing said modified propylene polymer and a propylene polymer,

(c) a rubbery substance, wherein said substance is a natural or synthetic polymeric material which is elastic at room temperature, and at least one component selected from the group consisting of

(e) a low-molecular weight hydrocarbon resin,

(f) white oil, and

(g) liquid paraffin, the ratio of component (a) to component (b) being 1-90 wt% to 99-10 wt%, the amount of component (c) being 1-50 parts by weight per 100 parts by weight of the total amount of components (a) and (b), and the total amount of components (e) and (f) being 0.1-50 parts by weight per 100 parts by weight of the total amount of components (a), (b), and (c).

5. A thermoplastic resin composition which comprises:

(a) polyphenylene ether or a composition containing polyphenylene ether,

(b) (i) a modified propylene polymer grafted with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with said styrene-based monomer, or (ii) a composition containing said modified propylene polymer and a propylene polymer,

(c) a rubbery substance, wherein said substance is a natural or synthetic polymeric material which is elastic at room temperature, and

(d) a styrene-based resin having a melt index of 8 or above (at 250°

C. under a load of 5 kg), the ratio of component (a) to component (b) being 1-90 wt% to 99-10 wt%, the amount of component (c) being 1-50 parts by weight per 100 parts by weight of the total amount of components (a) and (b), and the amount of component (d) being 1-30 part by weight per 100 parts by weight of the total amount of components (a), (b), and (c).

6. A thermoplastic resin composition which comprises:

(a) polyphenylene ether or a composition containing polyphenylene ether,

(b) (i) a modified propylene polymer grafted with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with said styrene-based monomer, or (ii) a composition containing said modified propylene polymer and a propylene polymer,

(c) a rubbery substance, wherein said substance is a natural or synthetic polymeric material which is elastic at room temperature, and

(e) a low-molecular weight hydrocarbon resin, the ratio of component (a) to component (b) being 1-90 wt% to 99-10 wt%, the amount of component (c) being 1-50 parts by weight per 100 parts by weight of the total amount of components (a) and (b), and the amount of component (e) being 0.1-50 parts by weight per 100 parts by weight of the total amount of components (a), (b), and (c).

9. A thermoplastic resin composition which comprises:

(a) polyphenylene ether or a composition containing polyphenylene ether,

(b) (i) a modified propylene polymer grafted with a styrene-based monomer or a mixture of a styrene-based monomer and a monomer copolymerizable with said styrene-based monomer, or (ii) a composition containing said modified propylene polymer and a propylene polymer,

(c) a rubbery substance, wherein said substance is a natural or synthetic polymeric material which is elastic at room temperature, and at least one component selected from the group consisting of

(f) white oil, and

(g) liquid paraffin, the ratio of component (a) to component (b) being 1-90 wt% to 99-10 wt%, the amount of component (c) being 1-70 parts by weight per 100 parts by weight of the total amount of components (a) and (b), and the amount of component (f) being 0.1-30 parts by weight per 100 parts by weight of the total amount of components (a), (b), and (c).