Explosive detection method and apparatus using selective gamma ray resonance absorption

• US 5,159,617 A
• Filed: 11/13/1991
• Issued: 10/27/1992
• Est. Priority Date: 11/13/1991
• Status: Expired due to Fees

• Current Assignee: Southwest Research Institute
• Original Assignee: Southwest Research Institute
• Inventors: Nicholls, Colin, King, J. Derwin
• Primary Examiner(s): Fields, Carolyn E.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US07/791,873
• Time in Patent Office: 349 Days
• Field of Search: 250/358.1, 250/390.04, 378/57, 378/53, 324/320, 324/321, 324/322, 324/307, 376/159, 376/159, 376/161, 376/165, 376/166
• US Class Current: 378/57
• CPC Class Codes: G01R 33/44 using nuclear magnetic resonance [NMR] G01R33/24, G01R33/62 take precedence
• CPC Class Codes: G01V 5/22 Active interrogation, i.e. by irradiating objects or goods using external radiation sources, e.g. using gamma rays or cosmic rays

Abstract

An apparatus and method for determining the presence of certain elements or compounds within an object, wherein the object under examination contains both nuclei of a first type which exhibit nuclear magnetic resonance and nuclei of a second type which exhibit nuclear quadrupolar resonance. The apparatus and method involve subjecting the object to a magnetic field and to a radiation beam whose characteristics in the presence of a magnetic field and in the absence of a magnetic field can be measured. The radiation transmission and/or absorption "fingerprint" of a particular substance is experimentally determined and recorded in the presence of a magnetic field calculated to optimize a cross coupling between nuclei of the first (NMR) type and nuclei of the second (NQR) type. This reference is then utilized later as a basis on which to identify an unknown compound exhibiting the same radiation absorption and/or transmission characteristics in response to the same or similar magnetic field intensity. Specific types of radiation and specific magnetic field intensities are pre-selected as optimizing the detectability of specific NMR/NQR element pairs.

Claims

1. A method of detecting the presence of a compound containing both nuclei of a first kind which exhibit NMR (nuclear magnetic resonance) behavior and nuclei of a second kind which exhibit NQR (nuclear quadrupole resonance) comprising the steps of:

subjecting a first material known to contain said compound to radiation;

subjecting said first material known to contain said compound to a magnetic field;

measuring a reference change in the absorption and/or transmission of said radiation through said first material in the presence and in the absence of said magnetic field;

subjecting a second material suspected of containing said compound to radiation;

subjecting said second material suspected of containing said compound to a magnetic field;

measuring a test change in the absorption and/or transmission of said radiation through said second material in the presence and in the absence of said magnetic field;

comparing said test change with said reference change; and

using the results of the said comparing step to determine the presence or absence of said compound in said second material.

2. A method for determining the presence of specific elements and/or compounds within an object comprising the steps of:

subjecting said object to electromagnetic or particulate radiation;

measuring first characteristics of electromagnetic or particulate radiation absorbed and/or transmitted by said object;

subjecting said object to a magnetic field of a specific intensity predetermined to create a change in said radiation absorbed and/or transmitted by said object if said specific elements and/or compounds are present;

measuring second characteristics of electromagnetic or particulate radiation absorbed and/or transmitted by said object;

comparing the second measured characteristics of radiation absorbed and/or transmitted with the first measured characteristics of said radiation absorbed and/or transmitted, and identifying a change between said measured characteristics;

comparing said change between said measured characteristics with predetermined radiation changes characteristic of said specific elements and/or compounds; and

using the results of the said comparing step to identify elements and/or compounds;

wherein said magnetic field of a specific intensity has been predetermined to effect a cross coupling between nuclei of a first element exhibiting nuclear magnetic resonant behavior and nuclei of a second element exhibiting nuclear quadrupole resonant behavior.

3. A method claimed in claim 2 in which the step of subjecting said object to radiation comprises exposing said object to a thermal neutron beam generated from a thermal neutron source, wherein an emission of gamma radiation from said object as a result of neutron capture by atomic nuclei of said compound will occur.

4. The method of claim 2, wherein said step of subjecting said object to radiation comprises the steps of:

accelerating protons in a particle accelerator;

directing said accelerated protons at a carbon-13 target, whereby gamma radiation of an appropriate energy level is emitted;

directing said gamma radiation at said object.

5. The method of claim 2 further comprising the step of determining the presence of nitrogen in said object prior to said step of subjecting said object to a magnetic field of specific intensity.

6. An apparatus for determining the presence of specific elements and/or compounds within an object comprising:

a radiation source, said radiation source directing radiation at said object;

a radiation detector, said radiation detector detecting radiation from said object;

an electromagnet capable of generating a varying magnetic field about said object;

means for detecting a change in said radiation detected from said object, both in the presence of said magnetic field and in the absence of said magnetic field;

means for storing reference characteristic changes in said radiation previously identified with said specific elements and/or compounds; and

means for correlating said change in said radiation with said reference characteristic identifying said specific elements and/or compounds as being present within said object.

7. The apparatus of claim 6, wherein said radiation source comprises a thermal neutron source, wherein said thermal neutron source directs a thermal neutron beam at said object and an emission of gamma radiation from said object as a result of neutron capture by atomic nuclei of said compound will occur.

8. The apparatus of claim 6, wherein said radiation source comprises:

a particle accelerator capable of accelerating protons with energy levels sufficient to excite a carbon-13 target to emit gamma radiation; and

a carbon-13 target;

wherein said particle accelerator accelerates protons and directs them at said carbon-13 target, said carbon-13 target thereby emitting gamma radiation of an appropriate energy level and directing said gamma radiation at said object.

9. The apparatus of claim 6 further comprising means for determining the presence of nitrogen in said object, wherein the failure to detect the presence of nitrogen in said object confirms the absence of said specific elements and/or compounds within said object.