Fe-base soft magnetic alloy and method of producing same

• US 5,160,379 A
• Filed: 01/22/1991
• Issued: 11/03/1992
• Est. Priority Date: 12/15/1986
• Status: Expired due to Term

• Current Assignee: Hitachi Metals (Thailand) Ltd.
• Original Assignee: Hitachi Metals (Thailand) Ltd.
• Inventors: Oguma, Shigeru, Yoshizawa, Yoshihito, Yamauchi, Kiyotaka
• Primary Examiner(s): Sheehan, John P.
• Application Number:
  US07/643,104
• Time in Patent Office: 651 Days
• Field of Search: 148/108, 148/121, 164/463, 164/477
• US Class Current: 148/108
• CPC Class Codes: C21D 1/04 with simultaneous application of supersonic waves, magnetic or electric fields
• CPC Class Codes: C22C 45/02 with iron as the major constituent
• CPC Class Codes: H01F 1/15308 based on Fe/Ni H01F1/15325 takes precedence

Abstract

An Fe-base soft magnetic alloy having the composition represented by the general formula:

(Fe.sub.1-a M.sub.a).sub.100-x-y-z-α-β-γ Cu.sub.x Si.sub.y

B_z M'"'"'.sub.α M".sub.β X.sub.γ

wherein M is Co and/or Ni, M'"'"' is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, M" is at least one element selected from the group consisting of V, Cr, Mn, Al, elements in the platinum group, Sc, Y, rare earth elements, Au, Zn, Sn and Re, X is at least one element selected from the group consisting of C, Ge, P, Ga, Sb, In, Be and As, and a, x, y, z, α, β and γ respectively satisfy 0≦a≦0.5, 0.1≦x≦3, 0≦y≦30, 0≦z≦25, 5≦y+z≦30, 0.1≦α≦30, β≦10 and γ≦10, at least 50% of the alloy structure being fine crystalline particles having an average particle size 1000 Å or less. This alloy has low core loss, time variation of core loss, high permeability and low magnetostriction.

Claims

1. A method of producing a Fe-base soft magnetic alloy having the composition represented by the general formula:

space="preserve" listing-type="equation">(Fe.sub.1-a M.sub.a).sub.100-x-y-z-α

Cu.sub.x Si.sub.y B.sub.z M'"'"'.sub.α

wherein M is Co and/or Ni, M'"'"' is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, and a, x, y, z and α

respectively satisfy 0≦

a≦

0.5, 0.1≦

x≦

3, 0≦

y≦

30, 0≦

z≦

25, 5≦

y+z≦

30 and 0.1≦

a≦

30, at least 50% of the alloy structure being occupied by fine crystalline particles having an average particle size of 1,000Å

or less, comprising the steps of;

(a) rapidly quenching a melt of the above composition to provide an amorphous alloy; and

(b) heat-treating said amorphous alloy at 450-700°

C. for 5 minutes to 24 hours to generate fine crystalline particles having an average particle size of 1000Å

or less in the alloy structure.

2. The method of according to claim 1, wherein said heat treatment is carried out in a magnetic field.

3. The method according to claim 1, wherein said amorphous alloy is heat-treated at 500-650°

C. for 5 minutes to 6 hours.

4. A method of producing an Fe-base soft magnetic alloy having the composition represented by the general formula:

space="preserve" listing-type="equation">(Fe.sub.1-a M.sub.a).sub.100-x-y-z-α

-β

-γ

Cu.sub.x Si.sub.y B.sub.z M'"'"'.sub.α

M".sub.β

X.sub.γ

wherein M is Co and/or Ni, M'"'"' is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti and Mo, M'"'"' is at least one element selected from the group consisting of V, Tr, M, Al, elements in the platinum group, Sc, Y, rare earth elements, Au, Zn, Sn and Re, X is at least one element selected from the group consisting of C, Ge, P, Ga, Sb, In, Be and As, and a, x, y, z, α

, β and

γ

respectively satisfy 0≦

a≦

0.5, 0.1≦

x≦

3, 0≦

y≦

30, 0≦

z≦

25, 5≦

y+z≦

30, 0.1≦

α

≦

30, β

≦

10 and γ

≦

10, at least 50% of the alloy structure being occupied by fine crystalline particles having an average particle size of 1,000Å

or less, comprising the steps of;

(a) rapidly quenching a melt of the above composition to provide an amorphous alloy; and

(b) heat-treating said amorphous alloy of 450-700°

C. for 5 minutes to 24 hours to generate fine crystalline particles having an average particle size of 1,000Å

or less in the alloy structure.

5. The method according to claim 4, wherein said heat treatment is carried out in a magnetic field.

6. The method according to claim 4, wherein said amorphous alloy is heat-treated at 500-650°

C. for 5 minutes to 6 hours.