Joining metal-polymer-metal laminate sections

• US 5,160,771 A
• Filed: 09/27/1990
• Issued: 11/03/1992
• Est. Priority Date: 09/27/1990
• Status: Expired due to Term

• Current Assignee: Structural Laminates Company
• Original Assignee: Structural Laminates Company
• Inventors: Lambing, Cynthia L. T., Colpo, James A., Herbein, William C.
• Primary Examiner(s): Thibodeau, Paul J.
• Assistant Examiner(s): KILIMAN, LESZEK B
• Application Number:
  US07/588,752
• Time in Patent Office: 768 Days
• Field of Search: 428/33, 428/57, 428/58, 428/60, 428/77, 428/189, 428/192, 428/458, 156/157, 156/182
• US Class Current: 428/57
• CPC Class Codes: B29C 65/483 Reactive adhesives, e.g. chemically curing adhesives
• CPC Class Codes: B29C 66/1248 Interpenetrating groove joints interpenetrating fingered joints B29C66/139
• CPC Class Codes: B29C 66/12821 comprising at least two overlap joint-segments
• CPC Class Codes: B29C 66/12822 comprising at least three overlap joint-segments
• CPC Class Codes: B29C 66/1284 comprising at least one butt joint-segment
• CPC Class Codes: B29C 66/12841 comprising at least two butt joint-segments
• CPC Class Codes: B29C 66/12842 comprising at least three butt joint-segments
• CPC Class Codes: B29C 66/14 the joint having the same thickness as the thickness of the parts to be joined B29C66/1142 takes precedence
• CPC Class Codes: B29C 66/43 Joining a relatively small portion of the surface of said articles B29C66/45 takes precedence
• CPC Class Codes: B29C 66/45 Joining of substantially the whole surface of the articles methods or apparatus for laminating B32B37/00
• CPC Class Codes: B29C 66/472 said single elements being substantially flat
• CPC Class Codes: B29C 66/71 characterised by the composition of the plastics material of the parts to be joined welding bar compositions B29C65/125
• CPC Class Codes: B29C 66/721 Fibre-reinforced materials B29C66/729 takes precedence
• CPC Class Codes: B29C 66/7212 characterised by the composition of the fibres
• CPC Class Codes: B29C 66/72321 consisting of metals or their alloys
• CPC Class Codes: B29C 66/7392 characterised by the material of at least one of the parts being a thermoplastic
• CPC Class Codes: B29C 66/7394 characterised by the material of at least one of the parts being a thermoset
• CPC Class Codes: B29K 2063/00 Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2277/10 Aromatic polyamides [Polyaramides] or derivatives thereof
• CPC Class Codes: B29K 2307/04 Carbon
• CPC Class Codes: B29K 2309/08 : Glass
• CPC Class Codes: B29L 2009/00 : Layered products
• CPC Class Codes: Y10T 428/19 : Sheets or webs edge spliced or joined
• CPC Class Codes: Y10T 428/192 : Sheets or webs coplanar
• CPC Class Codes: Y10T 428/195 : Beveled, stepped, or skived in thickness
• CPC Class Codes: Y10T 428/24752 : Laterally noncoextensive components
• CPC Class Codes: Y10T 428/24777 : Edge feature
• CPC Class Codes: Y10T 428/31678 : Of metal
• CPC Class Codes: Y10T 428/31681 : Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]

Abstract

A metal-polymer-metal laminate is made by joining adjacent laminate sections in a staggered relationship. Terminal portions of metal layers in a first laminate section are opposed to ends of fiber-reinforced polymer layers in a second laminate section. End portions of fiber-reinforced polymer layers in the first laminate section are opposed to ends of metal layers in a second laminate section. The two laminate sections are then joined by an adhesive layer.

Claims

1. A metal-polymer-metal laminate (45) made by adhesively joining adjacent laminate sections, said laminate (45) comprising:

(a) a first laminate section (10) comprising;

(i) a first metal layer (11);

(ii) a second metal layer (15) having a lateral end (16), said second metal layer (15) being laterally non-coextensive with the first metal layer (11); and

(iii) a fiber-reinforced first polymer layer (20) between said first metal layer (10) and second metal layer (15), said first polymer layer (20) having a lateral end (21);

(b) a second laminate section (30) comprising;

(i) a first metal layer (31) opposed to a metal layer (15);

(ii) a second metal layer (35) having a lateral end (36) opposed to the lateral end (21) of a polymer layer (20), said second metal layer (35) being laterally non-coextensive with the first metal layer (31); and

(iii) a fiber-reinforced first polymer layer (40) between said first metal layer (31) and second metal layer (35), said first polymer layer (40) having a lateral end (41) opposed to the lateral end (16) of a metal layer (15) in the first laminate section (10); and

(c) an adhesive layer (50) interposed between said first and second laminate sections (10,

     30) and adhesively joining them together.

2. The laminate of claim 1 wherein said lateral end (16) of the second metal layer (15) and said lateral end (21) of the first polymer layer (20) extend generally transverse to said first metal layer (11) in the first laminate section (10).

3. The laminate of claim 1 wherein said lateral end (36) of the second metal layer (35) and said lateral end (41) of the first polymer layer (40) extend generally transverse to said first metal layer (31) in the second laminate section (30).

4. The laminate of claim 1 wherein said first laminate section (10) further comprises:

(iv) a third metal layer (60) having a lateral end (61); and

(v) a fiber-reinforced second polymer layer (65) between said second metal layer (15) and third metal layer (60), said second polymer layer (65) having a lateral end (66); and

said second laminate section (30) further comprises;

(iv) a third metal layer (80) having a lateral end (81) opposed to a lateral end (21) of a polymer layer (20) in the first laminate section (10); and

(v) a fiber-reinforced second polymer layer (85) between said second metal layer (35) and third metal layer (30), said second polymer layer (85) having a lateral end (86) opposed to a lateral end (16) of a metal layer (15) in the first laminate section (10).

5. The laminate of claim 4 wherein said first laminate section (10) further comprises:

(vi) a fourth metal layer (101) having a lateral end (102); and

(vii) a fiber-reinforced third polymer layer (105) between said third metal layer (60) and fourth metal layer (101), said third polymer layer (105) having a lateral end (106); and

said second laminate section (30) further comprises;

(vi) a fourth metal layer (120) having a lateral end (121) opposed to a lateral end (21) of a polymer layer (20) in the first laminate section (10); and

(vii) a fiber-reinforced third polymer layer (130) between said third metal layer (80) and fourth metal layer (120), said third polymer layer (130) having a lateral end (131) opposed to a lateral end (16) of a metal layer (15) in the first laminate section (10).

6. The laminate of claim 1 wherein said adhesive layer (50) joins said first metal layer (11) in the first laminate section (10) to said second metal layer (35) in the second laminate section (30).

7. The laminate of claim 4 wherein said adhesive layer (50) joins said first metal layer (11) in the first laminate section (10) to said third metal layer (80) in the second laminate section (30).

8. The laminate of claim 5 wherein said adhesive layer (50) joins said first metal layer (11) in the first laminate section (10) to said fourth metal layer (120) in the second laminate section (30).

9. The laminate of claim 1 wherein said metal layers (11, 15, 31, 35) each comprise an aluminum alloy.

10. The laminate of claim 1 wherein said polymer layers (20, 40) each comprise a thermosetting epoxy resin.

11. The laminate of claim 1 wherein said adhesive layer (50) comprises a thermosetting epoxy resin.

12. The laminate of claim 1 wherein said polymer layers (20, 40) are reinforced with fibers comprising a material selected from the group consisting of aramids, polyolefins, glass, carbon and ceramics.

13. The laminate of claim 1 wherein said polymer layers (20, 40) are reinforced with poly-p-phenylene terephthalamide fibers.

14. The laminate of claim 1 wherein said polymer layers (20, 40) each have lesser thickness than each said metal layers (11, 15, 31, 35).

15. A metal-polymer-metal laminate (400) made by joining adjacent laminate sections, said laminate (400) comprising:

(a) a first laminate section (200) comprising;

(i) a first metal layer (201) having a lateral edge (202);

(ii) a second metal layer (211) spaced from said first metal layer (201) and having a lateral edge (212);

(iii) a third metal layer (221) intermediate said first metal layer (201) and second metal layer (211), said third metal layer (221) having a lateral edge (222) spaced laterally inwardly of the lateral edges (202,

     212) of said first and second metal layers (201,

     211);

(iv) a fiber-reinforced first polymer layer (231) between the first and third metal layers (201,

     221), said first polymer layer (231) having a lateral edge (232) spaced laterally inwardly of the lateral edges (202,

     212) on said first and second metal layers (201,

     211); and

(v) a fiber-reinforced second polymer layer (241) between the second and third metal layers (211,

     221), said second polymer layer (241) having a lateral edge (242) spaced laterally inwardly of the lateral edges (202,

     212) on said first and second metal layers (201,

     211);

said first, second and third metal layers (201, 211,

     221) and said first and second polymer layers (231,

     241) defining a slot (245);

(b) a second laminate section (250) comprising;

(i) first, second, third and fourth metal layers (251, 261, 271,

     281), said second and third metal layers (261,

     271) each having a lateral edge (262,

     272) opposed to a lateral edge (232,

     242) of a polymer layer (231,

     241) in the first laminate section (200); and

(ii) fiber-reinforced first, second and third polymer layers (301, 311,

     321) between the metal layers (251, 261, 271,

     281), said polymer layers (301, 311,

     321) each having a lateral edge (302, 312,

     322) opposed to a lateral edge (202, 222,

     212) of a metal layer (201, 221,

     211) in the first laminate section (200); and

(c) an adhesive layer (350) joining said first laminate section (200) to the second laminate section (250).

16. The laminate of claim 15 wherein said second laminate section (250) defines a key (345) fitted within said slot (245).

17. The laminate of claim 15 wherein said polymer layers (231, 241, 301, 311, 321) each have lesser thickness than each said metal layers (201, 211, 221, 251, 261, 271, 281).