Toner image pressure transfer method and toner useful therefor

• US 5,162,189 A
• Filed: 07/01/1991
• Issued: 11/10/1992
• Est. Priority Date: 12/27/1989
• Status: Expired due to Term

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Tyagi, Dinesh, Sorriero, Louis J., Pierce, Zona R.
• Primary Examiner(s): McCamish, Marion E.
• Assistant Examiner(s): RODEE, CHRISTOPHER D
• Application Number:
  US07/723,590
• Time in Patent Office: 498 Days
• Field of Search: 430/126, 430/109, 430/98
• US Class Current: 430/123.41
• CPC Class Codes: B01J 13/06 by phase separation
• CPC Class Codes: G03G 9/08728 Polymers of esters
• CPC Class Codes: G03G 9/09321 obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: G03G 9/09357 Macromolecular compounds
• CPC Class Codes: G03G 9/09371 obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds

Abstract

Pressure-sensitive, heat-fusible, encapsulated toner particles are provided which have very uniform size and physical characteristics. A method for making the particles is provided wherein a latex copolymer functions as a stabilizer controlling particle size of the core composition of the toner particles. The latex copolymer becomes the shell composition thereof. The particles are particularly useful in a process for transferring a toned image comprised of such particles from a photoconductor to a receiver.

Claims

1. A method for producing a toned image upon a receiver comprising the steps of:

(a) applying a thin coating of a fatty acid metal salt wherein said metal is selected from the group consisting of zinc and cadmium upon the imagable surface of a photoconductor element;

(b) forming a transferable toner powder image upon said coating by electrostatically charging said surface, exposing the charged surface to a light image of a graphic original to produce a latent image of such original, and applying toner powder to the imaged surface to produce a developed image;

(c) rolling a pressure roller over said toner powder image with said receiver positioned between said roller and said toner powder image while maintaining a pressure between said surface and the nip region of said roller in the range of about 5 to about 30 pounds per lineal inch; and

(d) separating said receiver from said surface with said toner powder image adhered thereto;

wherein said toner powder comprises particles having average particle diameters in the range of about 1 to about 20 microns, said particles each having a core and a highly uniform enclosing shell, said core comprising on a total core composition basis an admixture of about 0 to about 20 weight percent of colorant, about 0.05 to about 5 weight percent of charge control agent, and about 80 to about 99.95 weight percent of thermoplastic polymer having a melting temperature in the range of about 40°

to about 150°

C., a degree of crystallization in the range of about 5 to about 80 percent; and

said shell comprises colloidal sized particles of a copolymer comprising about 25 to about 80 weight percent of an addition polymerizable nonionic oleophilic monomer;

about 5 to about 45 weight percent of an addition polymerizable nonionic hydrophilic monomer;

about 1 to about 50 weight percent of an addition polymerizable ionic monomer; and

abut 8 to about 20 weight percent of a crosslinking monomer having at least two addition polymerizable groups.

2. The method of claim 1 wherein said fatty acid metal salt comprises zinc stearate.

3. The method of claim 1 wherein said photoconductor element is in sheet form and said receiver is a paper sheet.

4. The method of claim 3 wherein said photoconductor element and said paper sheet are continuously passed through the nip region between a pair of adjacent rollers which have spaced, parallel axes, one of said rollers being in contact with the opposed face of said paper sheet and having an elastomeric circumferential surface, the other of said rollers being in contact with the opposed face of said photoconductor and having a non-adhering circumferential surface.

5. The method of claim 4 wherein said non-adhering surface is comprised of polytetrafluoroethylene.

6. The method of claim 1 wherein said toner of powder image on said receiver is heat fused by exposing said receiver and said toner powder image to a temperature in the range of about 60°

to about 120°

C.