Silicone rubber sealant composition

• US 5,162,407 A
• Filed: 03/06/1991
• Issued: 11/10/1992
• Est. Priority Date: 03/06/1990
• Status: Expired due to Term

• Current Assignee: Investors Diversified Capital Inc.
• Original Assignee: Investors Diversified Capital Inc.
• Inventors: Turner, Ronald L.
• Primary Examiner(s): Hoke, Veronica P.
• Application Number:
  US07/665,419
• Time in Patent Office: 615 Days
• Field of Search: 524/588, 524/490, 524/491, 524/376, 524/377, 524/385, 524/188, 524/266, 524/462, 524/89, 524/102, 524/108, 523/169, 525/477, 428/319.3, 428/447
• US Class Current: 524/108
• CPC Class Codes: C04B 41/4966 containing silicon bound to hydroxy groups, i.e. OH-blocked polysiloxanes
• CPC Class Codes: C04B 41/64 Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
• CPC Class Codes: C09K 2003/1056 Moisture-curable materials
• CPC Class Codes: C09K 3/1018 Macromolecular compounds having one or more carbon-to-silicon linkages
• CPC Class Codes: Y10T 428/249991 Synthetic resin or natural rubbers
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

A sealant composition especially useful for porous materials such as wood, concrete and mansonry is provided comprising: (a) a silanol-terminated polysiloxane having a molecular weight greater than about 2000; (b) a multifunctional silane having functional groups which condense with silanol groups in the presence of atmospheric moisture at room temperature to form a cross-linked polymer; and (c) a nonaqueous volatile solvent which is non-reactive with components (a) and (b).

The sealant composition renders said materials waterproof by coating and filling in the pores of said material with cured silicone rubber product.

In a preferred embodiment the composition also contains a metal-containing curing catalyst and a volatile or subliming chelating agent in an amount sufficient to prevent cure of the composition in the storage container prior to or during use.

The composition may also comprise adhesion agents, surfactants and pigments.

Claims

1. A sealant composition for porous materials comprising:

(a) a silanol-terminated polysiloxane having a molecular weight greater than about 2000;

(b) a multifunctional silane having functional groups which condense with silanol groups in the presence of atmospheric moisture at room temperature to form a cross-linked polymer wherein said silane is selected from the group consisting of an acetoxysilane, an enoxy silane and an oxime silane in an amount sufficient to crosslink said polysiloxane;

(c) a metal-containing catalyst in an amount sufficient to cause said condensation of said mixture in the presence of atmospheric moisture;

(d) a non aqueous volatile solvent which is non reactive with the remaining components at a concentration of at least about 85% weight percent of the silane/polysiloxane/solvent mixture.

2. A sealant composition for porous materials comprising:

(a) a silanol-terminated polysiloxane having a molecular weight greater than about 2000;

(b a multifunctional silane having functional groups which condense with silanol groups in the presence of atmospheric moisture at room temperature to form a cross-linked polymer;

(c) a metal-containing catalyst in an amount sufficient to cause said condensation of said mixture in the presence of atmospheric moisture;

(d) a nonaqueous volatile solvent which is nonreactive with the remaining components at a concentration of at least about 85 weight percent of the silane/polysiloxane/solvent mixture; and

(e) a volatile or subliming chelating agent in an amount sufficient to prevent activity of said catalyst.

3. The composition of claim 2 wherein said polysiloxane has a molecular weight greater than about 26,000.

4. The composition of claim 2 wherein said chelating agent is selected from the group consisting of 1,4-dioxane, α

-α

'"'"'dipyridyl, orthophenanthroline, and mixtures of two or more of said chelating agents.

5. The composition of claim 2 wherein said chelating agent comprises 1,4-dioxane.

6. The composition of claim 4 wherein said chelating agents is present in at least an amount equimolar to the metal atoms in said catalyst.

7. The composition of claim 2, wherein said volatile solvent comprises stoddard solvent.

8. The composition of claim 2 wherein said volatile solvent comprises an alcohol.

9. The composition of claim 2 wherein said volatile solvent comprises 1,1,1-trichloroethane.

10. The composition of claim 2 wherein said volatile solvent comprises an aliphatic hydrocarbon.

11. The composition of claim 2 wherein said volatile solvent comprises a glycol ether.

12. The composition of claim 2, wherein said solvent is at a concentration between about 85 and about 97 weight percent of the silane/polysiloxane/solvent mixture.

13. The composition of claim 2 also comprising an organofunctional silane adhesion enhancer.

14. The composition of claim 2 also comprising surfactant.

15. A sealant composition for porous materials comprising:

(a) silanol-terminated polydimethylsiloxane;

(b methyltriacetoxysilane in an amount sufficient to crosslink said silanol-terminated polydimethylsiloxane;

(c) a metal-containing catalyst in an amount sufficient to cause said condensation of said mixture in the presence of atmospheric moisture;

(d) a volatile or subliming chelating agent comprising 1,4-dioxane in an amount equimolar to the metal ions in said catalyst; and

(e) a non aqueous volatile solvent selected from the group consisting of compositions which are non reactive with components (a) and (b) consisting of C₁ -C₅ alcohols, glycol ethers, stoddard solvent, aliphatic hydrocarbons at a concentration of at least about 85 weight percent of the silane/polysiloxane/solvent mixture.

16. A method for waterproofing a porous material comprising:

(a) applying to said material at room temperature and in the presence of atmospheric moisture, a sealant composition comprising;

(1) a silanol-terminated polysiloxane having a molecular weight greater than about 2000;

(2) a multifunctional silane having functional groups which condense with silanol groups in the presence of atmospheric moisture at room temperature to form a cross-linked polymer;

(3) a metal-containing catalyst in an amount sufficient to cause said condensation of said mixture in the presence of atmospheric moisture;

(4) a non-aqueous volatile solvent which is non-reactive with the remaining components at a concentration of at least about 85 weight percent of the silane/polysiloxane/solvent mixture;

(b) allowing said solvent to evaporate and said composition to cross-link such that a waterproof seal of said material is formed.

17. The method of claim 16 wherein said volatile or subliming chelating agent comprises 1,4-dioxane in an amount equimolar to the metal ions in said catalyst and allowing said chelating agent to evaporate after application of said sealant to said material, whereby said condensation is prevented prior to said application, and is permitted after evaporation of said chelating agent.

18. A method for temporarily preventing curing of the one-component room temperature vulcanizable silicone rubber sealant composition prior to application thereof to a substrate, and permitting curing of said composition following application to said substrate wherein said silicone rubber sealant composition comprises:

(a) a silanol-terminated polysiloxane having a molecular weight greater than about 2000;

(b) a multifunctional silane having functional groups which condense with silanol groups in the presence of atmospheric moisture at room temperature to form a cross-linked polymer;

(c) a metal-containing catalyst in an amount sufficient to cause said condensation of said mixture in the presence of atmospheric moisture;

p1 (d) a non-aqueous volatile solvent which is non-reactive with the remaining components at a concentration of at least about 85 weight percent of the silane/polysiloxane/ solvent mixture;

said method comprising adding to said composition a volatile or subliming chelating agent in an amount sufficient to prevent activity of said catalyst, whereby curing of said composition occurs upon evaporation of said chelating agent and consequent release of said catalyst after application to said substrate.

19. The method of claim 18 wherein said chelating agent comprises 1,4-dioxane.