Fluorine-containing AB-type block copolymer

• US 5,162,444 A
• Filed: 11/21/1990
• Issued: 11/10/1992
• Est. Priority Date: 05/13/1987
• Status: Expired due to Fees

• Current Assignee: Mitsubishi Petrochemical Co., Ltd. (Mitsubishi Chemical Group Corp.)
• Original Assignee: Mitsubishi Petrochemical Co., Ltd. (Mitsubishi Chemical Group Corp.)
• Inventors: Himori, Shunichi
• Primary Examiner(s): Carrillo, Ana L.
• Assistant Examiner(s): JAGANNATHAN, VASUDEVAN SALEM
• Application Number:
  US07/616,750
• Time in Patent Office: 720 Days
• Field of Search: 522/57, 522/124, 525/259, 525/261, 525/267, 525/276
• US Class Current: 525/276
• CPC Class Codes: C08F 293/00 Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule on to polymers modified by introduction of unsaturated end groups C08F290/02
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 57/00 Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds

Abstract

An AB type-block copolymer of the formula: ##STR1## wherein R¹ is a hydrocarbon group having 1 to 10 carbon atoms; R² is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; R³ is a benzyl group, an alkyl group having 1 to 18 carbon atoms or ##STR2## wherein R⁴ is an alkyl group having 1 to 18 carbon atoms; M represents a fluorine-containing AB-type block copolymer having a fluorine-containing polymer chain and a polymer chain having affinity for a resin.

Claims

1. An AB-diblock copolymer represented by the following formula (I):

##STR29## wherein R¹ represents a hydrocarbon group having 1 to 10 carbon atoms;

R² represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms;

R³ represents a benzyl group, ##STR30## (wherein R⁴ represents an alkyl group having 1 to 18 carbon atoms) or an alkyl group having 1 to 18 carbon atoms;

M represents a group represented by the formula (M²)_m (M¹)_n or (M¹)_m (M²)_n, each of m and n being a natural number of 20 to 5000;

M¹ represents a (meth)acrylate residue represented by the formula;

##STR31## (wherein R⁵ represents a hydrogen atom or a methyl group, and R⁶ represents a hydrocarbon group having 1 to 18 carbon atoms or a hydrocarbon group having 1 to 18 carbon atoms substituted with an alkoxy group or a hydroxyl group) or an aromatic vinyl residue represented by the formula;

##STR32## (wherein R⁷ represents a hydrogen atom or a methyl group, R⁸ represents a phenyl group or an alkylphenyl group) or a fatty acid vinyl ester residue represented by the formula;

##STR33## (wherein R⁹ represents a hydrocarbon group having 1 to 18 carbon atoms);

M² represents a fluorine-containing vinyl residue represented by the formulae (II) to (VI);

##STR34## wherein R¹⁰ represents a hydrogen atom, a methyl group, a fluorine atom or a fluorine-substituted alkyl group having 1 to 16 carbon atoms, and R¹¹ represents a fluorine-substituted alkyl group having 1 to 16 carbon atoms, ##STR35## wherein R¹⁰ and R¹¹ have the same meanings as those in the formula (II), R¹² represents an alkylene group having 1 to 10 carbon atoms and R¹³ represents an alkyl group having 1 to 10 carbon atoms, ##STR36## wherein R¹⁰, R¹¹, R¹², R¹³ have the same meanings as those in the formula (III), ##STR37## wherein R¹⁰ have the same meaning as that in the formula (IV), R¹⁴ is an alkylene group having 1 to 10 carbon atoms or a fluorine-substituted alkylene group having 1 to 10 carbon atoms, R¹⁵ is an alkyl group having 1 to 10 carbon atoms or a fluorine-substituted alkyl group having 1 to 10 carbon atoms;

at least one of R¹⁰, R¹⁴ and R¹⁵ being required to contain fluorine, ##STR38## wherein R¹⁶, R¹⁷, R¹⁸, R¹⁹ each represent a hydrogen atom, a chlorine atom, a fluorine atom, a phenyl group, a substituted phenyl group, a fluorine-substituted alkyl group having 1 to 6 carbon atoms, at least one of R¹⁶ to R¹⁹ being required to contain fluorine.

2. The block copolymer according to claim 1, wherein the residue M¹ is formed from a (meth)acrylate monomer selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, hexyl (meth)acrylate, isooctyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, isononyl (meth)acrylate, decyl (meth)acrylate, stearyl (meth)acrylate, hydroxyethyl (meth)acrylate, 2-methoxyethyl (meth)acrylate, 2-ethoxyethyl (meth)acrylate, 2-butoxyethyl (meth)acrylate, (meth)acrylic acid pentaethylene glycol monomethyl ether, (meth)acrylic acid diethylene glycol monoethyl ether and (meth)acrylic acid diethylene glycol monobutyl ether.

3. The block copolymer according to claim 1, wherein the residue M¹ is formed from an aromatic vinyl monomer selected from the group consisting of styrene, p-methylstyrene, o-methylstyrene, α

-methylstyrene and β

-methylstyrene.

4. The block copolymer according to claim 1, wherein the residue M¹ is formed from an aliphatic vinyl ester monomer selected from the group consisting of vinyl acetate, vinyl propionate, vinyl butyrate, vinyl caproate, vinyl 2-ethylhexanoate, vinyl laurate and vinyl stearate.

5. The block copolymer according to claim 1, wherein the residue M² is formed from a fluorine-containing vinyl monomer selected from the group consisting of:

##STR39##

6. The block copolymer according to claim 1, wherein the residue M² is formed from a fluorine-containing vinyl monomer selected from the group consisting of:

##STR40##

7. The block copolymer according to claim 1, wherein the residue M² is formed from a fluorine-containing monomer selected from the group consisting of:

##STR41##

8. The block copolymer according to claim 1, wherein the residue M² is formed from a fluorine-containing monomer selected from the group consisting of:

##STR42##

9. The block copolymer according to claim 1, wherein the residue M² is formed from a fluorine-containing monomer selected from the group consisting of:

CCl₂ ═

CFCl, CFCl═

CFCl, CF₂ ═

CCl₂, CClF═

CF₂, CF₂ ═

CF₂, CHCl═

CFCl, CHF═

CCl₂, CHCl═

CF₂, CHF═

CClF, CHF═

CF₂, CHF═

CHCl, CH₂ ═

CClF, CHF═

CHF, CH₂ ═

CF₂, CH₂ ═

CFH, CF₂ ═

C(CF₃)₂, CF₃ -CF═

CF₂, CF₃ -CH═

CHF, CF₃ -CH═

CH₂, C₃ F₇ (CH₃)C═

CH₂, CF₃ CF₂ CF═

C(CF₃)₂, (CF₃)₂ CFCF═

CF--CF₃, and ##STR43##

10. The block copolymer according to claim 1, wherein said block copolymer has a weight average molecular weight of about 5,000 to 100,000 and contains 5 to 75% by weight of a fluorine-containing block.

11. A polymer composition comprising a polymeric material and the block copolymer according to claim 1.

12. The polymer composition according to claim 11, wherein the amount of the block copolymer added is 0.01 to 30 parts by weight based on 100 parts by weight of the polymeric material.

13. A heterogeneous process for producing the block copolymer according to claim 1, comprising the steps of:

a first step of polymerizing either one of a monomer for forming M₁ block or a monomer for forming M₂ block in the presence of a sulfur-containing compound having the following formula (VII);

##STR44## wherein R¹ represents a hydrocarbon group having 1 to 10 carbon atoms;

R² represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms;

R³ represents a benzyl group, ##STR45## (wherein R⁴ represents an alkyl group having 1 to 18 carbon atoms), or an alkyl group having 1 to 18 carbon atoms;

so as to synthesize a polymer initiator having 20 to 5,000 monomer units and a dithiocarbamate group at the polymer terminal end; and

a second step of polymerizing the other monomer in the presence of said polymer initiator obtained in the first step;

wherein polymerizations in the first step and the second step are carried out with the irradiation of ultraviolet rays and wherein polymerization of the fluorine-containing monomer is carried out in a heterogeneous medium.

14. The process of claim 13 wherein the second step is polymerization of a fluorine-containing vinyl residue which is sparingly soluble in the reaction solvent.