Method and apparatus for rapid detection of contraband and toxic materials by trace vapor detection using ion mobility spectrometry

• US 5,162,652 A
• Filed: 08/07/1991
• Issued: 11/10/1992
• Est. Priority Date: 08/07/1991
• Status: Expired due to Term

• Current Assignee: PCP, Inc.
• Original Assignee: PCP, Inc.
• Inventors: Wernlund, Roger F., Stimac, Robert M., Cohen, Martin J.
• Primary Examiner(s): Berman, Jack I.
• Application Number:
  US07/742,646
• Time in Patent Office: 461 Days
• Field of Search: 250/288, 73/864.62, 73/863.21, 73/863.12, 73/864.83, 73/864.84, 73/863.33, 73/863.83, 73/863.84
• US Class Current: 250/288
• CPC Class Codes: G01N 1/2214 by sorption
• CPC Class Codes: G01N 1/24 Suction devices G01N1/22 - G01N1/2294 take precedence
• CPC Class Codes: G01N 1/405 by adsorption or absorption
• CPC Class Codes: G01N 2001/022 sampling for security purposes, e.g. contraband, warfare agents
• CPC Class Codes: G01N 2001/245 Fans
• CPC Class Codes: G01N 27/622 Ion mobility spectrometry
• CPC Class Codes: G01N 30/08 using an enricher
• CPC Class Codes: G01V 9/007 by detecting gases or particles representative of underground layers at or near the surface analysing earth materials G01N33/24; analysing gases per se G01N

Abstract

An apparatus and method for the detection and identification of the presence of chosen molecules, typically toxic or contraband located within sealed luggage and the like, comprises subjecting the sealed luggage to a process whereby a portion of the enclosed atmosphere within the luggage is extracted and combined with the surrounding atmosphere in a closed chamber. The extracted, combined sample is passed to a collector, typically a molecule adsorber, which concentrates the chosen molecules by collection on a collecting surface. After the end of a collection period, the adsorbed molecules are released from the surface and passed to an identifier, such as an ion mobility spectrometer. By use of appropriate collection and valving elements, analysis can be accomplished quickly and accurately for a large number of luggage items or the like subject to examination.

Claims

1. Apparatus for the detection of the presence of selected materials in an object by the extraction and analysis of vapor samples therefrom, comprising a sampling chamber adapted to accept the object;

means for removing a portion of the vapor contents from the object and blending said removed portion with the surrounding atmosphere in said sampling chamber;

means for collecting the molecules of the selected materials from said mixture to create a test sample wherein the concentration of said molecules is substantially above the initial vapor concentration thereof; and

means for performing an analysis upon said test sample whereby the presence of said selected material is determined.

2. The apparatus of claim 1, wherein said sampling chamber comprises a sealed chamber of variable volume.

3. The apparatus of claim 1, wherein said vapor contents removing means comprises means for varying the pressure within said chamber.

4. The apparatus of claim 3, wherein said blending means comprises said means for varying the pressure within said chamber.

5. The apparatus of claim 4, wherein said means for varying the pressure varies the pressure between about ten percent above and below ambient.

6. The apparatus of claim 4, wherein said means for varying the pressure comprise means for varying the volume of said chamber.

7. The apparatus of claim 6 further comprising means for coupling said collection means to said sampling chamber solely during the time said blending means is in operation.

8. The apparatus of claim 6, wherein said coupling means includes means for circulating the atmospheric contents of said sampling chamber through said collection means during the time said blending means is in operation.

9. The apparatus of claim 5, wherein said means for varying the volume of said chamber comprise a chamber wall in the form of a bellows.

10. The apparatus of claim 9, wherein said bellows is operated pneumatically.

11. The apparatus of claim 8, wherein said collection means comprises an adsorbent for the molecules sought to be sensed.

12. The apparatus of claim 9, further comprising means for decoupling said collection means from said chamber at the end of the blending cycle and for coupling said collection means to said analysis means.

13. The apparatus of claim 12 further comprising means for removing said molecules from said adsorbent and transferring said molecules to said analysis means.

14. The apparatus of claim 12, wherein said removal means comprises an adsorbent heater to evaporate said molecules from said adsorbent and blower means for transferring said evaporated molecules to said analysis means.

15. A method for determining the presence of vapors a selected substance within closed baggage and the like, comprising the steps of

a) placing the baggage item within a sealed sampling chamber;

b) extracting at least a portion of the gaseous contents of the baggage to the exterior of the baggage, whereby such contents is mixed with the atmosphere within said chamber;

c) collecting the molecules of the desired substance from said mixture to create a sample, wherein the concentration of said molecules is substantially above the initial vapor concentration thereof; and

d) analyzing said sample to determine the presence of said selected molecule.

16. The method of claim 15, wherein said extraction step comprises lowering the pressure within said chamber to cause the passage of a portion of the vapor-containing gaseous contents of the baggage to the exterior of the baggage.

17. The method of claim 15, wherein said lowering of pressure is part of a pressure cycle including a step wherein the pressure within said chamber is increased above ambient.

18. The method of claim 17, wherein said pressure cycle is repeated on a periodic basis.

19. The method of claim 17, wherein said pressure cycle is performed by oscillation of a wall of the chamber.

20. The method of claim 15, wherein said collection step is performed concurrently with said extraction step.

21. The method of claim 20, wherein said mixing step includes the continuous circulation of the contents of said chamber between said chamber and a remote molecule adsorber.

22. The method of claim 21 further including the steps of isolating said molecule adsorber from said chamber then transferring said molecules from said adsorber to an analysis means before said analysis is performed.

23. The method of claim 21, wherein said transfer from said adsorber is performed by heating said adsorber and creating an air flow between said adsorber and said analysis means.

24. The method of claim 15, wherein said sample collection step comprises collecting the molecules on a first adsorbent within a first volume, desorbing the adsorbed molecules and adsorbing them on a second adsorbent within a second volume less than said first volume to provide a more concentrated molecule sample.

25. A vapor collector comprising a housing having an inlet at a first side and an outlet, a ribbon-like molecule collector means arranged within said housing in a layered manner, and means for circulating vapor-containing gas across the molecule collector means.

26. The vapor collector of claim 25, wherein said ribbon molecule collector means is formed of nichrome sheets coated with silicon dioxide.

27. The vapor collector of claim 26, wherein said ribbons are arranged in 20 layers, each of said layers comprising 4 parallel ribbons.

28. The vapor collector of claim 27, wherein each of said ribbons is spring-mounted to said chamber.

29. The vapor collector of claim 26 further including means for heating said nichrome sheets to a temperature in excess of about 150 degrees C. to desorb collected molecules from said sheets.

30. The vapor collector of claim 26, wherein said heating means is an electric power source connected to said nichrome sheets.

31. The vapor collector of claim 29 further including means for transferring said desorbed molecules to a remote detector.

32. The vapor collector of claim 31, wherein said transfer means comprises a blower.

33. The vapor collector of claim 25 wherein said molecule collector is in the form of a spiral winding of an electrically conductive material, the turns of said winding being spaced from each other.

34. The vapor collector of claim 33 wherein said spiral winding is of foil.

36. The vapor collector of claim 34 wherein the turns of said spiral winding are separated by an insulating medium.

37. The vapor collector of claim 36 when said insulating medium is a mesh adapted to permit said vapor-coating gas to pass between said turns.

38. The vapor collector of claim 37 where said mesh comprises a plurality of parallel strands aligned with the axis of said spiral winding.

35. The vapor collector of class 34 wherein said foil is of stainless steel.

39. Apparatus for the analysis of baggage and the like for the presence of predetermined vapors, comprising

a baggage-analysis module comprising a first baggage-acceptance compartment and a second compartment, said first and second compartments being joined by a flexible, piston-forming wall;

means for loading baggage into said first compartment for analysis and subsequently removing it therefrom;

means for transferring at least a portion of the air from said first compartment to a vapor collector chamber;

a vapor collector array located with said vapor collector chamber for collecting molecules of the predetermined vapors;

means for removing the molecules of the predetermined vapors from said collector and transferring same to a vapor sensor;

a vapor sensor for the analysis of said molecules; and

means for varying the pressure within said second compartment whereby said piston-forming wall is driven to cause pressure variation within said first compartment to extract vapors from the interior of baggage placed therein and combine said vapors with the air of said first compartment.

40. The apparatus of claim 39, wherein said transfer means comprise a blower and valve operatively connected to said first compartment.

41. The apparatus of claim 39, wherein said vapor collector array comprises adsorbant sheets for the molecules of the predetermined vapors and said means for removing the molecules from said collector comprises means for raising the temperature of said adsorbant to cause the release of the vapor molecules therefrom.

42. The apparatus of claim 41, wherein said adsorbant sheets comprise a silicon dioxide coating applied to a substrate.

43. The apparatus of claim 42, wherein said substrate is nichrome.

44. The apparatus of claim 42, wherein said means for raising the temperature of said adsorbant comprises means for applying an electric potential across said nichrome sheets.