Laminated composite

• US 5,164,267 A
• Filed: 05/22/1990
• Issued: 11/17/1992
• Est. Priority Date: 05/24/1989
• Status: Expired due to Fees

• Current Assignee: Solvay SA (Solvac SA)
• Original Assignee: Solvay & CIE
• Inventors: Grobelny, Roland, D'Heur, Jacques, Michel, Claude
• Primary Examiner(s): HERBERT JR, THOMAS
• Application Number:
  US07/526,627
• Time in Patent Office: 910 Days
• Field of Search: 428/474.4, 428/476.3, 428/507, 428/516, 156/244.11, 427/365, 427/366
• US Class Current: 428/474.4
• CPC Class Codes: B32B 2323/046 LDPE, i.e. low density polyethylene
• CPC Class Codes: B32B 2377/00 Polyamides
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/34 comprising polyamides
• CPC Class Codes: B32B 37/153 at least one layer is extruded and immediately laminated while in semi-molten state
• CPC Class Codes: Y10T 428/31725 Of polyamide
• CPC Class Codes: Y10T 428/3175 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/3188 Next to cellulosic
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer

Abstract

Laminated composite consisting of a substrate sheet coated with a film (A) comprising at least one layer based on a polyamide resulting from the polycondensation of an aliphatic α, ω-dicarboxylic acid with xylylenediamines.

Claims

1. Laminated composite consisting of a substrate sheet based on cellulosic material laminated with a film (A) comprising at least one layer based on a polyamide (P) resulting from the polycondensation of an aliphatic α

, ω

-dicarboxylic acid with xylylenediamine, said film (A) comprising, in the following order;

(i) a layer (D) in contact with the substrate sheet, said layer (D) based on a thermoplastic polymer whose processing temperature is compatible with that of the polyamide (P);

(ii) a layer ()C based on a modified polyolefin which is polyolefin modified by grafting with a polar monomer; and

(iii) the polyamide layer (P).

2. Laminated composite according to claim 1, characterized in that the aliphatic α

, ω

-dicarboxylic acid is adipic acid.

3. Laminated composite according to claim 1, characterized in that the polar monomer is an unsaturated carboyxlic acid or the anhydride derived from this acid.

4. Laminated composite according to claim 1, characterized in that the modified polyolefin is an ethylene - acrylic acid - maleic anhydride terpolymer.

5. Laminated composite according to claim 1, characterized in that the thermoplastic polymer comprises low density polyethylene.

6. Laminated composite according to claim 1, characterized in that the film (A) comprises, in this order:

a layer (D), in contact with the substrate sheet,

a layer (C),

a polyamide-based layer (P),

a layer (C).

7. Laminated composite according to claim 1, characterized in that the film (A) comprises, in this order:

a layer (D) in contact with the substrate sheet,

a layer (C),

a polyamide layer (P),

a layer (C),

a layer (D).

8. Laminated composite according to claim 1, characterized in that the film (A) is produced by coextrusion.

9. Process for manufacturing the laminated composite according to any one of claims 1, 2, 3, 4, 5, 6, 7 or 8, characterized in that the film (A) is produced by coextrusion at between approximately 270°

and approximately 290°

C. and is laminated by calendaring with the substrate sheet based on cellulosic material.

10. Laminated composite consisting of a substrate sheet based on cellulosic material laminated with a film (A) comprising at least one layer based on a polyamide (P) resulting from the polycondensate of an aliphatic α

, ω

-dicarboxylic acid with xylylenediamine, said film (A) comprising, in the following order;

(i) a layer (D) in contact with the substrate sheet, said layer (D) based on a thermoplastic polymer whose processing temperature is compatible with that of the polyamide (P);

(ii) a layer (C) based on a modified polyolefin which comprises polar monomers in addition to monomeric units derived from alpha-olefins; and

(iii) the polyamide layer (P).

11. Laminated composite consisting of a substrate sheet based on cellulosic material laminated with a film (A) comprising one layer based on a polyamide (P) resulting from the polycondensation of an aliphatic α

, ω

-dicarboxylic acid with xylylenediamine, said film (A) consisting essentially of, in the following order;

(i) a layer (D) is contact with substrate sheet, said layer (D) based on a thermoplastic polymer whose processing temperature is compatible with of the polyamide (P);

(ii) a layer (C) based on a modified polyolefin which comprises polar monomers in addition to monomeric units derived from alpha-olefins; and

(iii) the polyamide layer (P).