Catalyst for the hydrogenation of hydrocarbon material

• US 5,166,118 A
• Filed: 04/19/1989
• Issued: 11/24/1992
• Est. Priority Date: 10/08/1986
• Status: Expired due to Fees

• Current Assignee: Intevep, S.A. (PDVSA Gas SA)
• Original Assignee: VEBA OEL Technologie GmbH
• Inventors: Guitian, Jose, Krasuk, Julio, Kretschmar, Klaus, Marruffo, Franzo, Kurzeja, Klaus, Merz, Ludwig, Niemann, Klaus
• Primary Examiner(s): MCFARLANE, ANTHONY R
• Application Number:
  US07/340,535
• Time in Patent Office: 1,315 Days
• Field of Search: 208/112, 208/143, 208/146, 208/108, 208/111 MC, 208/216 PP, 208/419, 208/423, 208/124
• US Class Current: 502/185
• CPC Class Codes: C10C 1/205 refining in the presence of hydrogen
• CPC Class Codes: C10G 1/086 Characterised by the catalyst used
• CPC Class Codes: C10G 47/26 suspended in the oil, e.g. slurries
• CPC Class Codes: C10M 175/0041 by hydrogenation processes

Abstract

A catalyst for the hydrogenation of a hydrocarbon material which is a member selected from the group consisting of red mud, iron oxides, iron ores, hard coals, lignites impregnated with heavy metal salts, carbon black, soots from gasifiers, and cokes produced by the hydrogenation of virgin residues, the catalyst being comprised of at least two separate particle size fractions such that the combined fractions have a particle size distribution between 0.1 and 2,000 microns with 10-40 wt. % of the particles having a particle size greater than 100 microns, and the mixture of fractions not being represented by a straight line when the accumulative weight of the particles vs. particle size which is plotted on log (minus log) vs. log graph paper has a correlation coefficient R² less than 0.96 as determined from the equation: ##EQU1## wherein n is the number of experimental points, y is ln [-ln (n/1000)] and x is ln (dp), wherein dp is the particle size (μm) of the particles.

Claims

1. A catalyst for the hydrogenation of a hydrocarbon material, said catalyst being a member selected from the group consisting of red mud, iron oxides, iron ores, hard coals, lignites impregnated with heavy metal salts, carbon black, soots from gasifiers, and cokes produced by the hydrogenation of virgin residues and said catalyst comprised of at least two separate particle size fractions such that the combined fractions have a particle size distribution between 0.1 and 2,000 microns with 10-40 wt. % of the particles having a particle size greater than 100 microns, and the mixture of fractions not being represented by a straight line when the accumulative weight of the particles versus particle size which is plotted on log (-log) versus log graph paper has a correlation coefficient (R²) less than 0.96 as determined from the equation:

##EQU4## wherein n is the number of experimental points, y is 1n and x is 1n (dp), wherein dp is the particle size (μ

m) of the particles.

2. The catalyst of claim 1, wherein said combined fractions have a particle size distribution between 0.1-1000 microns.

3. The catalyst of claim 1, wherein 10-30 wt % of said catalyst has a particle size greater than 100 microns.

4. The catalyst of claim 1, wherein said 10-40 wt. % particle size fraction has a particle size of greater than 100 to 1000 microns.

5. The catalyst of claim 1, wherein said 10-40 wt % particle fraction ranges in an amount of from 20-40 wt %.

6. The catalyst of claim 5, wherein said 20-40 wt. % particle fraction contains ground lignite or hard coal.

7. The catalyst of claim 1, wherein said 10-40 wt. % particle fraction comprises different materials.

8. The catalyst of claim 1, wherein said at least two particle fractions are selected from the group consisting of red mud/hard coal, carbon black/hard lignite, ground lignite/ground lignite, iron ores/hard coal-ground lignite, iron ores/iron ores, iron ores/cokes from hard coal or residues, and iron ores/soots from gasification processes.

9. The catalyst of claim 1, wherein said 10-40 wt % particle fraction further comprises calcium or magnesium compounds which improve the hydrogenation activity of the catalyst.