Bismaleimide-triazine resin bonded superabrasive wheels

• US 5,167,674 A
• Filed: 04/13/1992
• Issued: 12/01/1992
• Est. Priority Date: 04/13/1992
• Status: Expired due to Fees

• Current Assignee: Norton Company (Compagnie De Saint-Gobain)
• Original Assignee: Norton Company (Compagnie De Saint-Gobain)
• Inventors: Ika, Prasad V.
• Primary Examiner(s): Beck, Shrive
• Assistant Examiner(s): THOMPSON, WILLIE
• Application Number:
  US07/867,942
• Time in Patent Office: 232 Days
• Field of Search: 51/295, 51/298, 51/309, 526/262, 544/3,7
• US Class Current: 51/298
• CPC Class Codes: B24D 3/28 Resins or natural or synthetic macromolecular compounds B24D3/22 takes precedence
• CPC Class Codes: C08G 73/06 Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
• CPC Class Codes: C08G 73/0638 with at least three nitrogen atoms in the ring
• CPC Class Codes: C08G 73/0672 with only one nitrogen atom in the ring
• CPC Class Codes: C08G 73/0688 with only one nitrogen atom in the ring, e.g. polyquinolines
• CPC Class Codes: C08G 73/0694 with only two nitrogen atoms in the ring, e.g. polyquinoxalines
• CPC Class Codes: C08G 73/128 the unsaturated precursors containing heterocyclic moieties in the main chain
• CPC Class Codes: C09K 3/1418 obtained by division of a mass agglomerated by sintering

Abstract

An improved superabrasive composition for grinding applications comprising a superabrasive material, a bismaleimide-triazine addition copolymer resin which as a cured polymer exhibits (i) a glass transition temperature (Tg) of at least about 280° C. and (ii) a long term thermal resistance of at least about 180° C., a free radical generating initiator, and preferably a catalyst, is disclosed. The superabrasive abrasive composition is particularly useful as a cutting edge in a high performance cutting wheel.

Claims

1. An abrasive composition which comprises a superabrasive material, a bismaleimide-triazine addition copolymer resin which as a cured polymer exhibits (i) a glass transition temperature (Tg) of at least about 280°

C. and (ii) a long term thermal resistance of at least about 180°

C., and a free radical generating initiator.

2. The composition of claim 1, wherein the superabrasive has a Knoop hardness of at least about 3000 kg/mm².

3. The abrasive composition of claim 1, wherein the superabrasive material is selected from the group consisting of diamond, cubic boron nitride, and mixtures thereof.

4. The abrasive composition of claim 3, wherein the superabrasive material is metal coated.

5. The abrasive composition of claim 4, wherein the coating is nickel.

6. The abrasive composition of claim 3, additionally containing a secondary abrasive.

7. The abrasive composition of claim 6, wherein the secondary abrasive is a sintered alumina.

8. The abrasive composition of claim 1, wherein the superabrasive material is present in an amount of from about 5 to 40% by volume of he composition.

9. The abrasive composition of claim 1, wherein the bismaleimide-triazine resin is present in an amount of from about 35 to 60% by volume of the composition.

10. The abrasive composition of claim 9, wherein the bismaleimide-triazine resin is present in an amount of from about 45 to 55% by volume.

11. The abrasive composition of claim 1, wherein the initiator is selected from the group consisting of peroxide and azo initiators.

12. The abrasive composition of claim 10, wherein the peroxide is selected from the group consisting o dicumyl peroxide.

13. The abrasive composition of claim 1, wherein the composition further includes a catalyst for accelerating the curing of the resin.

14. The abrasive composition of claim 13, wherein the catalyst is selected from the group consisting of an organic metal salt, an amine, or a combination thereof.

15. The abrasive composition of claim 14, wherein the catalyst is an organic metal salt selected from the group consisting of zinc octoate and ferric acetyl acetonate.

16. The abrasive composition of claim 14, wherein the catalyst is an amine selected from the group consisting of triethylene diamine, and N,N-dimethylbenzylamine.

17. The abrasive composition of claim 1, additionally containing a filler material.

18. The abrasive composition of claim 16, wherein the filler material is selected from the group consisting of polytetrafluoroethylene, silicon carbide, graphite, and molybdenum disulphide.

19. The abrasive composition of claim 17, wherein the filler material is present in an amount of from about 20 to 40% by volume of the composition.

20. The abrasive composition of claim 17 wherein the filler material is a secondary abrasive.

21. The abrasive composition of claim 20, wherein the secondary abrasive is a sintered alumina.

22. The abrasive composition of claim 1, additionally containing a material for absorbing water.

23. The abrasive composition of claim 22, wherein the water-absorbing material is lime.

24. The abrasive composition of claim 23, wherein the lime is present in an amount of from about 1 to 5% by volume of the composition.

28. A cutting wheel having an inner core section and an outer annular cutting edge section, said cutting edge being composed of the abrasive composition of claim 1.

30. A grinding wheel having an inner core section and an outer annular grinding section, said grinding section being composed of the abrasive composition of claim 1.

25. An abrasive composition comprising a superabrasive selected from either diamond or cubic boron nitride, a bismaleimide-triazine addition copolymer resin, a free-radical generating initiator, a catalyst for curing said resin, and a filler.

26. The abrasive composition of claim 25, wherein the superabrasive material is present in an amount of from about 5 to 40% by volume of the composition, the bismaleimide-triazine resin is present in an amount of from about 35 to 60% by volume, the initiator is present in an amount of from about 0.01 to 1% by weight of the resin, the catalyst is present in an amount of about 0.01 to 1% by weight of the resin, and the filler is present in an amount of from about 20 to 40 % by volume.

27. The abrasive composition of claim 25, wherein the superabrasive material is present in an amount of from about 10 to 25% by volume of the composition, the bismaleimide-triazine resin is present in an amount of from about 45 to 55% by volume, the initiator is a peroxide, the catalyst is an organic metal salt, and the filler is present in an amount of from about 25 to 35% by volume.

29. A cutting wheel having an inner core portion and an outer annular cutting edge portion, said cutting edge portion being composed of the abrasive composition of claim 25.

31. A grinding wheel having an inner core portion and an outer annular grinding section, said grinding section being composed of the abrasive composition of claim 25.