Method and apparatus for monitoring fuel cell performance

• US 5,170,124 A
• Filed: 01/16/1991
• Issued: 12/08/1992
• Est. Priority Date: 06/08/1990
• Status: Expired due to Term

• Current Assignee: Her Majesty The Queen In Right of Canada As Represented By The Minister of National Defence
• Original Assignee: Her Majesty The Queen As Represented By The Minister of National Defence of Her Majesty's Canadian Government
• Inventors: Blair, James D., Dircks, Kenneth
• Primary Examiner(s): Harvey, Jack B.
• Assistant Examiner(s): Regan, Maura K.
• Application Number:
  US07/642,052
• Time in Patent Office: 692 Days
• Field of Search: 324/433, 324/434, 324/435, 340/636, 320/48
• US Class Current: 324/434
• CPC Class Codes: G01R 31/396 Acquisition or processing of data for testing or for monitoring individual cells or groups of cells within a battery
• CPC Class Codes: H01M 8/04223 during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
• CPC Class Codes: H01M 8/04228 during shut-down
• CPC Class Codes: H01M 8/04303 applied during shut-down
• CPC Class Codes: H01M 8/04552 of the individual fuel cell
• CPC Class Codes: H01M 8/04559 of fuel cell stacks
• CPC Class Codes: H01M 8/04671 of the individual fuel cell
• CPC Class Codes: H01M 8/04753 of fuel cell reactants
• CPC Class Codes: H01M 8/04768 of the coolant
• CPC Class Codes: H01M 8/04955 Shut-off or shut-down of fuel cells
• CPC Class Codes: H01M 8/241 with solid or matrix-supported electrolytes
• CPC Class Codes: H01M 8/2457 with both reactants being gaseous or vaporised
• CPC Class Codes: H01M 8/2465 Details of groupings of fuel cells
• CPC Class Codes: H01M 8/249 comprising two or more groupings of fuel cells, e.g. modular assemblies
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A method and apparatus for monitoring the performance of fuel cells arranged in series. More particularly, the method and apparatus involve the measurement and comparison of fuel cell performance indicators, such as voltage, in groups of cells connected in series. In a first embodiment, the voltage across each fuel cell group is compared to a reference voltage equal to a predetermined minimum voltage. In a second embodiment, the voltage across each group is compared to a reference voltage equal to the average across all fuel cell groups. In a third embodiment, a reference voltage equal to the voltage across one group is compared to the voltage across each of the other fuel cell groups. In a fourth embodiment, the voltage across each group is compared as a reference voltage to the voltage across an adjacent fuel cell group. Other embodiments comprising various combinations of the first, second, third and fourth embodiments are also provided. An alarm is activated, and supply of fuel to the cells discontinued, when the measured voltage for a fuel cell group varies from the reference voltage by more than a predetermined voltage differential.

Claims

1. A method of monitoring the performance of a plurality of series connected fuel cells comprising:

a. dividing the fuel cells into at least three groups,

b. measuring the voltage across each fuel cell group, and

c. comparing the normalized measured voltage of one fuel cell group as a reference voltage with the normalized measured voltage of each of the other fuel cell groups.

2. The method of claim 1 further comprising:

d. activating an alarm when the normalized measured voltage across a fuel cell group varies from said reference voltage by a predetermined voltage differential.

3. The method of claim 2 wherein said predetermined voltage differential is between about 20 millivolts per cell and about 200 millivolts per cell.

4. The method of claim 2 wherein said predetermined voltage differential is about 100 millivolts per cell.

5. The method of claim 2 further comprising:

e. performing steps (a) through (d) repeatedly and discontinuing the supply of fuel to the fuel cells upon continuous activation of said alarm for a predetermined time period.

6. The method of claim 5 wherein said predetermined time period is between about 0.5 seconds and about 2.0 seconds.

7. The method of claim 1 wherein said comparison is performed iteratively, said one fuel cell group in the first iteration being selected from the plurality of fuel cell groups, said one fuel cell group in succeeding iterations being selected from the remaining, previously unselected fuel cell groups, said iterations being performed until each of the said fuel cell groups has been selected as said one fuel cell group for said comparison, the number of iterations required for each of said fuel cell groups to be selected as said one fuel cell group for said comparison constituting a comparison cycle.

8. The method of claim 7 wherein said fuel cells are divided into at least three groups including a first outer fuel cell group, at least one inner fuel cell group, and a second outer fuel cell group, said first outer group being selected as said one fuel cell group in the first iteration, the adjacent inner group being selected as said one fuel cell group in the second iteration, the next adjacent inner groups, if any, being selected in sequence as said one fuel cell group in succeeding iterations, and said second outer group being selected as said one fuel cell group in the final iteration.

9. The method of claim 8 wherein said comparison cycle is performed repeatedly.

10. A method of monitoring the performance of a plurality of series connected fuel cells comprising:

a. dividing the fuel cells into at least three groups including a first outer fuel cell group, at least one inner fuel cell group, and a second outer fuel cell group,

b. measuring the voltage across each fuel cell group,

c. comparing the normalized measured voltage of said first outer fuel cell group as a reference voltage with the normalized measured voltage of the adjacent inner fuel cell group,

d. comparing in sequence the normalized measured voltage of each inner fuel cell group as a reference voltage with the normalized measured voltage of the next adjacent fuel cell group, and

e. comparing the normalized measured voltage of said second outer fuel cell group as a reference voltage with the normalized measured voltage of said first outer fuel cell group.

11. The method of claim 10 further comprising:

f. activating an alarm when the normalized measured voltage across a fuel cell group varies from said reference voltage by a predetermined voltage differential.

12. The method of claim 11 wherein said predetermined voltage differential is between about 20 millivolts per cell and about 200 millivolts per cell.

13. The method of claim 11 wherein said predetermined voltage differential is about 100 millivolts per cell.

14. The method of claim 11 further comprising:

g. performing steps (a) through (f) repeatedly and discontinuing the supply of fuel to the fuel cells upon continuous activation of said alarm for a predetermined time period.

15. The method of claim 14 wherein said predetermined time period is between about 0.5 seconds and about 2.0 seconds.

16. A method of monitoring the performance of a plurality of electrical series connected fuel cells comprising:

a. dividing the fuel cells into at least three groups,

b. measuring the voltage across each fuel cell group,

c. comparing the normalized measured voltage of each fuel cell group with a first reference voltage equal to a predetermined minimum voltage, and

d. comparing the normalized measured voltage of one fuel cell group as a second reference voltage with the normalized measured voltage of each of the other fuel cell groups.

17. The method of claim 16 further comprising:

e. activating an alarm when the normalized measured voltage across a fuel cell group is less than said first reference voltage or when the normalized measured voltage across a fuel cell group varies from said second reference voltage by a predetermined voltage differential.

18. The method of claim 17 wherein said predetermined minimum voltage is about 0.5 volts per cell and said predetermined voltage differential is between about 20 millivolts per cell and about 200 millivolts per cell.

19. The method of claim 17 wherein said predetermined minimum voltage is about 0.5 volts per cell and said predetermined voltage differential is about 100 millivolts per cell.

20. The method of claim 17 further comprising:

f. performing steps (a) through (e) repeatedly and discontinuing the supply of fuel to the fuel cells upon continuous activation of said alarm for a predetermined time period.

21. The method of claim 20 wherein said predetermined time period is between about 0.5 seconds and about 2.0 seconds.

22. A method of monitoring the performance of a plurality of electrical series connected fuel cells comprising:

a. dividing the fuel cells into at least three groups including a first outer fuel cell group, at least one inner fuel cell group, and a second outer fuel cell group,

b. measureing the voltage across each fuel cell group,

c. comparing the normalized measured voltage of each fuel cell group with a first reference voltage equal to a predetermined minimum voltage,

d. comparing the normalized measured voltage of said first outer fuel cell group as a second reference voltage with the normalized measured voltage of the adjacent inner fuel cell group,

e. comparing in sequence the normalized measured voltage of each inner fuel cell group as a second reference voltage with the normalized measured voltage of the next adjacent fuel cell group, and

f. comparing the normalized measured voltage of said second outer fuel cell group as a second reference voltage with the normalized measured voltage of said first outer fuel cell group.

23. The method of claim 22 further comprising:

g. activating an alarm when the normalized measured voltage across a fuel cell group is less than said first reference voltage or when the normalized measured voltage across a fuel cell group varies from said second reference voltage by a predetermined voltage differential.

24. The method of claim 23 wherein said predetermined minimum voltage is about 0.5 volts per cell and said predetermined voltage differential is between about 20 millivolts per cell and about 200 millivolts per cell.

25. The method of claim 23 wherein said predetermined minimum voltage is about 0.5 volts per cell and said predetermined voltage differential is about 100 millivolts per cell.

26. The method of claim 23 further comprising:

h. performing steps (a) through (g) repeatedly and discontinuing the supply of fuel to the fuel cells upon continuous activation of said alarm for a predetermined time period.

27. The method of claim 26 wherein said predetermined time period is between about 0.5 seconds and about 2.0 seconds.

28. A method of monitoring the performance of a plurality of electrical series connected fuel cells comprising:

a. dividing the fuel cells into at least three groups,

b. measuring the voltage across each fuel cell group,

c. comparing the normalized measured voltage of each fuel cell group with a first reference voltage equal to a predetermined minimum voltage,

d. comparing the normalized measured voltage of each fuel cell group with a second reference voltage equal to the normalized total voltage across the plurality of series connected fuel cells, and

e. comparing the normalized measured voltage of one fuel cell group as a third reference voltage with the normalized measured voltage of each of the other fuel cell groups.

29. The method of claim 28 further comprising:

f. activating an alarm when the normalized measured voltage across a fuel cell group is less than said first reference voltage or when the normalized measured voltage across a fuel cell group varies from said second reference voltage or said third reference voltage by a predetermined voltage differential.

30. The method of claim 29 wherein said predetermined minimum voltage is about 0.5 volts per cell and said predetermined voltage differential is between about 20 millivolts per cell and about 200 millivolts per cell.

31. The method of claim 29 wherein said predetermined minimum voltage is about 0.5 volts per cell and said predetermined voltage differential is about 100 millivolts per cell.

32. The method of claim 29 further comprising:

g. performing steps (a) through (f) repeatedly and discontinuing the supply of fuel to the fuel cells upon continuous activation of said alarm for a predetermined time period.

33. The method of claim 32 wherein said predetermined time period is between about 0.5 seconds and about 2.0 seconds.

34. A method of monitoring the performance of a plurality of electrical series connected fuel cells comprising:

a. dividing the fuel cells into at least three groups including a first outer fuel cell group, at least one inner fuel cell group, and a second outer fuel cell group,

b. measuring the voltage across each fuel cell group,

c. comparing the normalized measured voltage of each fuel cell group with a first reference voltage equal to a predetermined minimum voltage,

d. comparing the normalized measured voltage of each fuel cell group with a second reference voltage equal to the normalized total voltage across the plurality of series connected fuel cells,

e. comparing the normalized measured voltage of said first outer fuel cell group as a third reference voltage with the normalized measured voltage of the adjacent inner fuel cell group,

f. comparing in sequence the normalized measured voltage of each inner fuel cell group as a third reference voltage with the normalized measured voltage of the next adjacent fuel cell group, and

g. comparing the normalized measured voltage of said second outer fuel cell group as a third reference voltage with the normalized measured voltage of said first outer fuel cell group.

35. The method of claim 34 further comprising:

h. activating an alarm when the normalized measured voltage across a fuel cell group is less than said first reference voltage or when the normalized measured voltage across a fuel cell group varies from said second reference voltage or said third reference voltage by a predetermined voltage differential.

36. The method of claim 35 wherein said predetermined minimum voltage is about 0.5 volts per cell and said predetermined voltage differential is between about 20 millivolts per cell and about 200 millivolts per cell.

37. The method of claim 35 wherein said predetermined minimum voltage is about 0.5 volts per cell and said predetermined voltage differential is about 100 millivolts per cell.

38. The method of claim 35 further comprising:

i. performing steps (a) through (h) repeatedly and discontinuing the supply of fuel to the fuel cells upon continuous activation of said alarm for a predetermined time period.

39. The method of claim 38 wherein said predetermined time period is between about 0.5 seconds and about 2.0 seconds.