Composite catalytic converter

• US 5,170,624 A
• Filed: 04/05/1991
• Issued: 12/15/1992
• Est. Priority Date: 04/05/1991
• Status: Expired due to Fees

• Current Assignee: Engelhard Corporation (BASF SE)
• Original Assignee: W R Grace & Company - CONN (Standard Industries Holdings, Inc.)
• Inventors: Whittenberger, William A., Cornelison, Richard C.
• Primary Examiner(s): Hart, Douglas
• Application Number:
  US07/680,763
• Time in Patent Office: 620 Days
• Field of Search: 60/299, 60/300, 422/180, 422/174, 502/527
• US Class Current: 60/300
• CPC Class Codes: F01N 13/009 having two or more separate purifying devices arranged in series
• CPC Class Codes: F01N 2330/02 Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
• CPC Class Codes: F01N 2330/323 Corrugations of saw-tooth or triangular form
• CPC Class Codes: F01N 2330/42 made of three or more different sheets, foils or plates stacked one on the other
• CPC Class Codes: F01N 3/2026 directly electrifying the catalyst substrate, i.e. heating the electrically conductive catalyst substrate by joule effect
• CPC Class Codes: F01N 3/281 Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
• CPC Class Codes: F01N 3/2814 all sheets, plates or foils being corrugated
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

There is provided a core element for an electrically heatable catalytic converter, and an electrically heatable catalytic converter containing the same, the core element being characterized by a corrugated thin metal foil strip, preferably herringbone corrugated, and in laminar relationship therewith, a flat thin metal foil strip of either stainless steel or brazing metal, or a combination of both, the flat thin metal foil strip having a width less than the width of the corrugated thin metal foil strip. The strips are then spirally wound, or accordion folded to form a monolith, and suitably connected to a voltage source to supply electrical power to the unit.

Claims

1. A core member for an electrically heatable catalytic converter comprising (a) a nonnesting corrugated thin metal foil strip having a predetermined length and a predetermined width, the length being greater than the width, and (b) at least one flat thin metal foil strip having a width substantially less than said predetermined width and in contiguous relation therewith, one longitudinal marginal edge of said flat thin metal foil strip lying along a longitudinal marginal edge of said corrugated thin metal foil strip, and substantially coextensive therewith, said foils being spirally co-wound about an electrically conducting central post.

2. A core member as defined in claim 1 further comprising at least one of the foils (a) and (b) having a refractory metal oxide coating on a portion of at least one surface thereof, and a noble metal catalyst deposited on said refractory metal oxide surface.

3. A core member as defined in claim 2 wherein the refractory metal oxide coating comprises a major proportion of alumina.

4. A core member as defined in claim 3 wherein the alumina is gamma alumina.

5. A core member as defined in claim 1 wherein the flat thin metal foil strip is a stainless steel metal foil strip.

6. A core member as defined in claim 5 wherein the stainless steel metal foil is a ferritic stainless steel.

7. A core member as defined in claim 1 wherein the flat thin metal foil is a brazing metal foil.

8. A core member is defined in claim 7 wherein the brazing metal foil is a nickel/chromium/boron alloy.

9. A core member as defined in claim 5 wherein the stainless steel foil is corrugated with a herringbone, chevron, or truncated herringbone pattern.

10. A core member as defined in claim 1 wherein the thin stainless steel has corrugations parallel to each other and arrayed in a plurality of sequential repeating units, each of said repeating units including a plurality of pitches from peak to peak of the corrugations, the length of the repeating unit being no greater than the length of the smallest chord to be made, and the length of each pattern being constant within a repeating unit.

11. A core member as defined in claim 1 wherein the corrugations have a pitch of from about 0.02" to about 0.2" and an amplitude of from about 0.02" to about 0.25", and the cross-section of the corrugation is generally triangular with the apices rounded.

12. A core member as defined in claim 1 wherein the foils (a) and (b) each have a thickness of 0.001" to 0.005".

13. A core member as defined in claim 7 wherein the slope of the sides of the herringbone or chevron pattern is from 3 degrees to about 10 degrees to a line perpendicular to the edges of the foil.

14. A core for an electrically heatable catalytic converter including a core member comprising (a) nonnesting corrugated thin stainless steel foil strip having a predetermined length and a predetermined width, the length being greater than the width, and (b) at least one flat thin metal foil strip having a width less than said predetermined width, and in contiguous relation therewith, one longitudinal margin edge of said flat thin metal foil strip lying along a longitudinal margin edge of said corrugated thin metal foil strip, and substantially coextensive therewith, said foils being spirally co-wound about an electrically conducting central metal post, and including a retaining shell tightly surrounding said core and being electrically bonded thereto.

15. A core as defined in claim 14 wherein the geometric configuration of the shell is circular.

16. A core as defined in claim 14 wherein the geometric configuration of the shell is oval.

17. A core as defined in claim 14 wherein a line drawn from the intersection of orthogonally related axes passing through the center of symmetry of the geometric configuration of said housing to the periphery of said shell passes through foils arrayed in the order:

a) corrugated

b) flat stainless steel strip

c) corrugated

d) corrugated

e) flat stainless steel strip

f) corrugated, etc.

18. A core as defined in claim 14 wherein the foils are arrayed in the order:

a) corrugated

b) flat stainless steel strip

c) corrugated

flat stainless steel strip, etc.

19. A core as defined in claim 14 wherein the foils are arrayed in the order:

a) corrugated

b) flat brazing strip

c) corrugated

d) flat brazing strip, etc.

20. A core as defined in claim 14 wherein the foils are arrayed in the order:

a) corrugated

b) flat brazing strip

c) corrugated

d) corrugated

e) flat brazing strip

f) corrugated, etc.

21. A core as defined in claim 14 wherein the foils are arrayed in the order:

a) corrugated

b) flat brazing strip

c) corrugated

d) flat stainless steel strip

e) corrugated

f) flat brazing strip, etc.

22. A core as defined in claim 14 wherein the foils are arrayed in the order:

a) corrugated

b) flat brazing strip

c) flat stainless steel strip

d) flat brazing strip

e) corrugated, etc.

23. A core as defined in claim 14 wherein the foils are arrayed in the order:

a) corrugated

b) flat brazing strip

c) flat stainless steel strip

d) flat brazing strip, etc.

24. A core as defined in claim 14 wherein the foils are arrayed in the order:

a) corrugated

b) flat brazing strip

c) corrugated

d) flat brazing strip

e) flat stainless steel strip

f) flat brazing strip, etc.

25. A core as defined in claim 14 including means for connecting the central post to one pole of a direct current voltage source, and including means for connecting the housing to the other pole of said direct current voltage source.

26. A core as defined in claim 26 further including a direct current voltage source having a voltage rating of from 12 to 108 volts.

27. An electrically heatable catalytic converter for treating exhaust gas emanating from an internal combustion engine to remove pollutant materials therefrom, said converter including (1) an outer metallic shell, (2) means at each end of the shell for adapting the configuration of the outer metallic shell for insertion into a conventional exhaust system for said internal combustion engine, (3) an insulating liner for the inner walls of said outer shell, (4) a core for said converter within said insulating liner including a core member comprising (a) nonnesting corrugated thin stainless steel foil strip having a predetermined length and a predetermined width, the length being greater than the width, and (b) at least one flat thin metal foil strip having a width less than said predetermined width, and in contiguous relation therewith, one longitudinal marginal edge of said flat thin metal foil strip lying along a longitudinal marginal edge of said corrugated thin metal strip and substantially coextensive therewith, said foils being spirally co-wound about an electrically conducting central metal post, and including a retaining shell tightly surrounding said core and being electrically bonded thereto, (5) means for connecting said central post to one pole of a direct current voltage source, (6) means for connecting said retaining shell to the other pole of a direct current voltage source, and (7) a direct current voltage source rated at from 12 to 108 volts.