Biomass refining process

• US 5,171,592 A
• Filed: 12/19/1991
• Issued: 12/15/1992
• Est. Priority Date: 03/02/1990
• Status: Expired due to Fees

• Current Assignee: Afex Corporation
• Original Assignee: Afex Corporation
• Inventors: Davison, Richard R., Holtzapple, Mark, Stuart, Earnest D.
• Primary Examiner(s): Yeung, George
• Application Number:
  US07/810,818
• Time in Patent Office: 362 Days
• Field of Search: 426/447, 426/449, 426/69, 426/635, 426/636, 426/807
• US Class Current: 426/69
• CPC Class Codes: A23J 1/007 from leafy vegetables, e.g. alfalfa, clover, grass
• CPC Class Codes: C08B 1/00 Preparatory treatment of cellulose for making derivatives thereof , e.g. pre-treatment, pre-soaking, activation
• CPC Class Codes: Y10S 426/807 Poultry or ruminant feed

Abstract

An improved biomass refining process is disclosed which is considerably more efficient and cost effective than conventional refining processes. The apparatus and method of the present invention employs superheated steam to dry the solid components and uses the excess steam generated in the drying step to concentrate the liquid components, solidify soluble components and expel noncondensible components. The present invention further employs improved Ammonia Freeze Explosion technology to further enhance the food value of biomass and the solid fiber components separated from the biomass during refining.

Claims

1. A method for refining a biomass which comprises:

contacting the biomass or solid form component thereof with a volatile swelling agent in a pressure vessel for a period of time sufficient for said agent to swell the biomass or solid component thereof;

rapidly reducing the pressure of the biomass or solid form component to explode the biomass or solid component thereof and recovering an exploded biomass or solid component thereof; and

contacting the exploded biomass or solid component thereof with super-heated vapors of the swelling agent to vaporize and strip residual swelling agent from the exploded biomass, wherein the swelling agent vapors are contacted with the biomass at a first pressure sufficiently high such that the residual swelling agent can be condensed by ambient cooling media comprising air or water; and

recovering the stripped biomass.

2. The method of claim 1 wherein said swelling agent comprises liquid ammonia, a primary amine, a secondary amine, liquid nitrogen dioxide, liquid sulfur dioxide, or mixtures thereof.

3. The method of claim 2 in which the swelling agent comprises liquid ammonia.

4. The method of claim 3 wherein the superheated ammonia vapors have a temperature from about 35°

C. to about 200°

C.

5. The method of claim 1 wherein said superheated swelling agent vapors are contacted with the biomass at a second pressure reduced sufficiently relative to said first pressure such that residual water is removed from the biomass.

6. The method of claim 1 wherein said biomass is contacted with said swelling agent in a pressure vessel at a pressure from about 11 atm (absolute) to about 35 atm (absolute).

7. The method of claim 6 wherein the pressure is from about 14 atm (absolute) to about 21 atm (absolute).

8. The method of claim 1 wherein said biomass is contacted with said swelling agent for about 3 to about 30 minutes.

9. The method of claim 1 wherein the pressure is rapidly reduced in less than about 10 seconds.

10. The method of claim 1 wherein said pressure is rapidly reduced in less than about 2 seconds.

11. The method of claim 1 which further comprises:

contacting the biomass or solid component with superheated steam prior to contact with said volatile swelling agent under conditions to;

(1) vaporize and separate water, if any, from the biomass or component; and

(2) produce a dried, preheated prehydrolyzed biomass or component and steam.

12. The method of claim 1 which further comprises:

contacting the exploded biomass or solid component thereof with a volatile swelling agent in a pressure vessel for a period of time sufficient to further swell the exploded biomass or solid component thereof; and

rapidly reducing the pressure of the biomass or solid form component to further explode the exploded biomass or solid component thereof and recovering a further exploded biomass or solid component thereof.

13. The method of claim 12 which further comprises reheating the exploded biomass prior to contacting the exploded biomass or solid component thereof with a volatile swelling agent in a pressure vessel for a period of time sufficient to further swell the exploded biomass or solid component thereof.

14. A method of refining biomass comprising:

contacting the biomass or solid component thereof with a volatile swelling agent in a pressure vessel at a superatmospheric pressure for a period of time sufficient for said agent to swell the biomass or solid component thereof;

contacting the swollen biomass or solid component with superheated vapors of the swelling agent at said superatmospheric pressure in a pressure vessel to vaporize and strip at least a portion of the swelling agent from the swollen biomass and separate the vapors therefrom;

rapidly reducing the pressure of the biomass or solid form component to explode the biomass or solid component thereof and recovering an exploded biomass or solid component thereof.

15. The method of claim 14 wherein said swelling agent comprises liquid ammonia.

16. A method for refining a biomass comprising the steps

(a) contacting the biomass with a volatile swelling agent under pressure for a period of time sufficient to swell the biomass;

(b) rapidly reducing the pressure of the biomass in a manner sufficient to explode the biomass and recovering the exploded biomass containing residual swelling agent;

(c) contacting the exploded biomass with superheated vapors of the swelling agent at a first pressure to vaporize at least a portion of the residual swelling agent; and

(d) contacting the exploded biomass from step (a) with superheated vapors of the swelling agent at a second pressure which is lower than the pressure employed in step (c) to vaporize additional residual swelling agent.

17. The method of claim 16 wherein the exploded biomass recovered in step (b) is recycled to step (a) at least once to further explode and disrupt the biomass fiber.

18. The method of claim 17 wherein the exploded biomass is recycled twice to step (a).

19. A method for refining a biomass comprising:

(a) contacting the biomass with a volatile swelling agent at a first pressure for a period of time sufficient to swell the biomass and to produce a swollen biomass;

(b) recovering the swollen biomass produced in step (a);

(c) contacting the swollen biomass recovered in step (b) with superheated vapors of the swelling agent at said first pressure to vaporize at least a portion of the swelling agent from the swollen biomass;

(d) rapidly reducing said first pressure in a manner sufficient to explode the swollen biomass and to produce an exploded biomass containing residual swelling agent; and

optionally

(e) contacting the exploded biomass with superheated vapors of the swelling agent at a second lower pressure to vaporize the residual swelling agent from the exploded biomass.

20. The method of claim 19 wherein the exploded biomass recovered in step (b) is recycled to step (a) a plurality of times to further explode and disrupt the biomass fiber.

21. The method of claim 20 wherein the exploded biomass is recycled twice to step (a).