Multi-layered electrostrictive effect element

• US 5,173,162 A
• Filed: 01/04/1991
• Issued: 12/22/1992
• Est. Priority Date: 07/05/1989
• Status: Expired due to Fees

• Current Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals)
• Original Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals)
• Inventors: Hagimura, Atsushi, Inage, Ikuo, Nakajima, Mutsuo, Nishihara, Kunio
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): RYSER, DAVID
• Application Number:
  US07/637,554
• Time in Patent Office: 718 Days
• Field of Search: 204/180.2, 204/181.6, 204/180.9, 204/299 R
• US Class Current: 428/336
• CPC Class Codes: H05K 1/0254 High voltage adaptations; Electrical insulation details; Overvoltage or electrostatic discharge protection electrostatic discharge protection for electric apparatus in general H05K9/0067, H05K9/0079; Arrangements for regulating voltages or for using plural voltages
• CPC Class Codes: H05K 1/0298 Multilayer circuits
• CPC Class Codes: H05K 1/0306 Inorganic insulating substrates, e.g. ceramic, glass
• CPC Class Codes: H10N 30/063 Forming interconnections, e.g. connection electrodes of multilayered piezoelectric or electrostrictive parts
• CPC Class Codes: H10N 30/872 Connection electrodes of multilayer piezoelectric or electrostrictive devices, e.g. external electrodes
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]

Abstract

A multi-layered electrostrictive effect element comprises films or thin plates of an electrostrictive material and inner electrodes alternatively arranged in layers, the inner electrodes being formed on the entire surface of the films or thin plates of the electrostrictive material, wherein the insulating layer which insulates the inner electrodes exposed on the side end faces of the element comprises a polyimide resin having repeating units represented by the following general formula (I): ##STR1## (wherein X represents a tetravalent group selected from the group consisting of tetravalent phenyl groups; tetravalent biphenyl groups; and tetravalent polyphenyl groups in which at least one of either the phenyl or bipheny groups are bonded through at least one member selected from the group consisting of O, CO, S, CH₂, C(CH₃)₂ and C(CF₃)₂ and Y represents a bivalent groups selected from the group consisting of bivalent phenyl groups; bivalent biphenyl groups; bivalent polyphenyl groups in which at least one of either the phenyl or biphenyl groups are bonded through at least one member selected from the group consisting of O, CO, S, SO₂, CH₂, C(CH₃)₂ and C(CF₃)₂ ; alkylene groups; and xylylene groups) and an insulating filler. A process for making a multi-layered electrorestrictive effect element having a high dielectric strength is also disclosed.

Claims

1. A multi-layered electrostrictive effect element which comprises films or thin plates of an electrostrictive material and inner electrodes alternatively arranged in layers, the inner electrodes being formed on the entire surface of the films or thin plates of the electrostrictive material, wherein insulating layers which insulate the inner electrodes exposed on the side end faces of the element comprise m groups wherein m is an even number of not less than 4, the insulating layer which comprises the first group continuously extending over and insulating the inner electrodes other than the (m×

n+1)-th electrode wherein n is 0 or a positive integer, the insulating layer which comprises the second group continuously extending over and insulating the inner electrodes other than the (m×

n+2)-th electrode, the insulating layer which comprises the third group continuously extending over and insulating the inner electrodes other than the (m×

n+3)-th electrode and so forth, and the insulating layer which comprises the m-th group continuously extending over and insulating the inner electrodes other than the (m×

n+m)-th electrode; and

a plurality of external electrodes being electrically connected to every m layers of inner electrodes laminated is formed over the insulating layer of each group.

2. The multi-layered electrostrictive effect element of claim 1 wherein the insulating layers which insulate the inner electrodes exposed on the side end faces of the element comprise 4 groups, the insulating layer which comprises the first group continuously extending over and insulating the inner electrodes other than the (4n+1)-th electrode (n is 0 or a positive integer), the insulating layer which comprises the second group continuously extending over and insulating the inner electrodes other than the (4n+2)-th electrode, the insulating layer which comprises the third group continuously extending over and insulating the inner electrodes other than the (4n+3)-th electrode and the insulating layer which comprises the 4-th group continuously extending over and insulating the inner electrodes other than the (4n+4)-th electrode;

and an external electrode which is electrically connected to every 4 layers of the inner electrodes laminated is formed over the insulating layer of each group.

3. The multi-layered electrostrictive effect element of claim 1 wherein the insulating layer comprises an organic insulating material.

4. The multi-layered electrostrictive effect element of claim 3 wherein the organic material is a polyimide resin having repeating units represented by the following general formula (I):

##STR11## (wherein X represents a tetravalent group selected from the group consisting of tetravalent phenyl groups;

tetravalent biphenyl groups; and

tetravalent polyphenyl groups in which at least one of either the phenyl or biphenyl groups are bonded through at least one member selected from the group consisting of O, CO, S, CH₂, C(CH₃)₂ and C(CF₃)₂ and Y represents a bivalent groups selected from the group consisting of bivalent phenyl groups;

bivalent biphenyl groups;

bivalent polyphenyl groups in which at least one of either the phenyl or biphenyl groups are bonded through at least one member selected from the group consisting of O, CO, S, SO₂, CH₂, C(CH₃)₂ and C(CF₃)₂ ;

alkylene groups; and

xylylene groups.

5. The multi-layered electrostrictive effect element of claim 3 wherein the insulating layer comprises a polyimide resin having repeating units represented by the following general formula (I):

##STR12## (wherein X represents a tetravalent group selected from the group consisting of tetravalent phenyl groups;

tetravalent biphenyl groups; and

tetravalent polyphenyl groups in which at least one of either the phenyl or biphenyl groups are bonded through at least one member selected from the group consisting of O, CO, S, CH₂, C(CH₃)₂ and C(CF₃)₂ and Y represents a bivalent groups selected from the group consisting of bivalent phenyl groups;

bivalent biphenyl groups;

bivalent polyphenyl groups in which at least one of either the phenyl or biphenyl groups are bonded through at least one member selected from the group consisting of O, CO, S, SO₂, CH₂, C(CH₃)₂ ;

alkylene groups; and

xyxlylene groups and an insulating filler.

6. The multi-layered electrostrictive effect element of claim 1 wherein it is a multi-layered electrostrictive vertical effect element.