Apparatus for photocatalytic treatment of liquids

• US 5,174,877 A
• Filed: 12/15/1989
• Issued: 12/29/1992
• Est. Priority Date: 07/24/1986
• Status: Expired due to Fees

• Current Assignee: Photocatalytics Incorporated
• Original Assignee: Photocatalytics Incorporated
• Inventors: Cooper, Gerald, Ratcliff, Matthew A.
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): RYSER, DAVID
• Application Number:
  US07/451,375
• Time in Patent Office: 1,110 Days
• Field of Search: 204/157.15.157.4.157.6.193, 422/186.186.3
• US Class Current: 204/193
• CPC Class Codes: A62D 2101/24 containing heavy metals
• CPC Class Codes: A62D 2101/43 containing heavy metals, in the bonded or free state
• CPC Class Codes: A62D 2203/10 Apparatus specially adapted for treating harmful chemical agents; Details thereof
• CPC Class Codes: A62D 3/15 to particle radiation, e.g. electron beam radiation
• CPC Class Codes: A62D 3/17 to electromagnetic radiation, e.g. emitted by a laser
• CPC Class Codes: A62D 3/176 Ultraviolet radiations, i.e. radiation having a wavelength of about 3nm to 400nm
• CPC Class Codes: B01J 19/122 Incoherent waves gamma-radiation B01J19/082
• CPC Class Codes: B01J 19/123 Ultraviolet light
• CPC Class Codes: B01J 2208/00433 using electromagnetic heating
• CPC Class Codes: B01J 35/00 Catalysts, in general, characterised by their form or physical properties
• CPC Class Codes: B01J 35/58 Fabrics or filaments
• CPC Class Codes: B01J 8/02 with stationary particles, e.g. in fixed beds
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 2305/10 Photocatalysts

Abstract

Apparatus for decontaminating a contaminated fluid by using photocatalytic particles. The apparatus includes a reactor tank for holding a slurry of the contaminated fluid and the photocatalytic particles ultraviolet light irradiates the surface of the slurry, thereby activating the photocatalytic properties of the particles. Stirring blades for continuously agitate the irradiated fluid surface maintaining the particles in a suspended state within the fluid. A cross flow filter is used for separating the fluid from the semiconductor powder after the decomposition reaction is ended. The cross flow filter is occasionally back flushed to remove any caked semiconductor powder. The semiconductor powder may be recirculated back to the tank for reuse, or may be stored for future use. A series of reactor tanks may be used to gradually decompose a chemical in the fluid. The fluid may be pretreated to remove certain metal ions which interfere with the photocatalytic process. Such pretreatment may be accomplished by dispersing semiconductor particles within the fluid, which particles adsorb ions or photodeposit the metal as the free metal or its insoluble oxide or hydroxide, and then removing the semiconductor particles together with the adsorbed metal ions/oxides/hydroxide/free metal from the fluid.

Claims

1. Apparatus for decontaminating a contaminated fluid by using photocatalytic powder particles comprising:

a tank holding the contaminated fluid and the photocatalytic powder particles suspended in the contaminated fluid;

means for maintaining the photocatalytic particles in a suspended state substantially uniformly throughout the fluid;

a filter through which the fluid passes and through which the photocatalytic powder particles suspended therein are substantially prevented from passing such that the fluid substantially alone passes through said filter;

means for directing the fluid and the photocatalytic particles suspended therein from said tank to said filter; and

means for removing the photocatalytic powder particles away from said filter.

2. Apparatus as defined in claim 1 wherein said removing means includes means for changing the direction of fluid flow in the region adjacent to the filter.

3. Apparatus as defined in claim 2 wherein said fluid direction changing means includes means for selectively causing fluid that has passed through said filter to flow back through said filter whereby the photocatalytic powder particles are removed away from said filter.

4. Apparatus as defined in claim 2 wherein said fluid direction changing means includes:

a conduit through which said fluid directing means causes the fluid and the photocatalytic powder particle suspended therein to pass, said conduit having an inlet and an outlet, said filter being in communication with the interior of said conduit;

means defining an exit port in communication with the interior of said conduit, the fluid in said conduit passing into said exit port substantially only by passing through said filter;

a closed cylinder the interior or which is in communication with the interior of said conduit;

a piston slideably disposed within said cylinder; and

means for selectively sliding said piston within said cylinder whereby a pressurized pulse of fluid is created within said conduit.

5. Apparatus as defined in claim 4 wherein said fluid direction changing means further includes:

means for creating a back pressure of fluid within said conduit whereby the fluid pressure within said conduit is higher than the fluid pressure within said exit port; and

means for selectively prohibiting the low of fluid within said exit port whenever said piston slides within said cylinder to create a pressurized pulse of fluid within said conduit.

6. Apparatus as defined in claim 1 wherein said filter comprises a cross flow filter having a first surface and wherein said fluid directing means directs the fluid and the photocatalytic powder particles suspended therein substantially parallel to a filter surface.

7. A reactor for decontaminating a contaminated fluid by using photocatalytic particles, comprising:

a shallow tank containing a slurry of contaminated fluid and photocatalytic particles, said slurry having a fluid surface;

means for illuminating said fluid surface to activate said photocatalytic particles; and

agitator means at least partially submerged in said slurry for maintaining said photocatalytic particles in a suspended state substantially throughout the slurry, for creating turbulence and aerating the slurry in a photoactive zone extending from the fluid surface to a predetermined depth where the ultraviolet light is effective to activate said photocatalytic particles and decontaminate the fluid.

8. The reactor as defined in claim 7 wherein the illumination means comprises sunlight.

9. The reactor as defined in claim 7 wherein the illumination means comprises artificial light.

10. The reactor as defined in claim 7 wherein the agitator means comprises at least one moveable blade positioned within said zone.

11. Reactor as defined in claim 10 wherein said blade includes means for injecting a gas into the fluid within said tank.

12. Reactor as defined in claim 11 wherein said injecting means injects gas into the fluid substantially along the entire length of said blade.

13. Reactor as defined in claim 11 wherein said injecting means injects gas into the fluid so as to create a force tending to cause said blade to rotate in the fluid.

14. Reactor as defined in claim 10 wherein said blade has a hollow interior and defines a series of ports in fluid communication with said hollow interior and wherein said system further includes means for supplying a gas under pressure to said blade hollow interior whereby the pressurized gas exits said blade through said ports.

15. The reactor as defined in claim 10 wherein the blade comprises a polymeric material.

16. The reactor as defined in claim 10 wherein the blade is a rod possessing a thickness extending in a dimension transverse to the length of the rod, said thickness being between substantially one-fifth and one-half of an inch.

17. The reactor as defined in claim 10 wherein the blade is elongated and pivotably connected for movement within the tank about a pivot point, the blade further having a thickness extending in a dimension transverse to the length of the blade, the thickness of the blade decreasing along its length from the pivot point substantially in proportion to 1/L^x where L equals the distance away from the pivot point and where x is a number substantially in the range of from 0 to 2.

18. The reactor as defined in claim 10 wherein said blade is substantially conically shaped.

19. The reactor as defined in claim 10 wherein said blade is diametrically stepped along its length.

20. The reactor as defined in claim 10 wherein the blade is elongated and pivotably connected for movement within the tank about a pivot pint, the blade further being twisted and having a cross section extending in a dimension transverse to the length of the blade, said cross section being substantially rectangular and decreasing along the length of the blade away from the pivot point.

21. The reactor as defined in claim 10 wherein the blade is elongated and pivotably connected for movement within the tank about a pivot point, the blade having a plurality of apertures extending through said blade in a direction substantially parallel to the fluid surface.

22. The reactor as defined in claim 21 wherein the diameter of each aperture is larger than the diameters of apertures located farther away from the pivot point.

23. The reactor as defined in claim 10 wherein said blade is substantially rigid.

24. The reactor as defined in claim 10 wherein said blade is flexible.

25. The reactor as defined in claim 10 wherein the blade is disposed between substantially one millimeter to five millimeters below the fluid surface.

26. The reactor as defined in claim 10 wherein the blade possesses a blade edge which is substantially serrated.

27. The reactor as defined in claim 10 wherein a plurality of discs are spaced radially along said blade, said discs extending substantially orthogonally to the length of said blade.

28. The reactor as defined in claim 10 wherein a series of comb-like fingers depend from said blade.

29. The reactor as defined in claim 28 wherein said agitator means further comprises means for selectively adjusting the orientation of said blade to selectively vary the direction said comb-like fingers depend from said blade.

30. The reactor as defined in claim 10 wherein said blade includes means for injecting a gas into the slurry.

31. The reactor as defined in claim 30 wherein said blade is rotatable about a pivot point and the gas is injected into the slurry creating a force tending to cause said blade to rotate about said pivot point.

32. The reactor as defined in claim 30 wherein said blade has a hollow interior and defines a series of ports in fluid communication with said hollow interior and wherein said system further includes means for supplying a gas under pressure to said blade hollow interior whereby the pressurized gas exits said blade through said ports.

33. The reactor as defined in claim 7 wherein said agitating means includes at least two moveable blades, a first moveable blade disposed substantially near the fluid surface and a second moveable blade disposed below the first moveable blade.

34. The reactor as defined in claim 33 wherein said first moveable blade is at least fifty percent longer than said second moveable blade.

35. The reactor as defined in claim 33 wherein said first and second moveable blades are rotated and second moveable blade is rotated at a speed at least fifty percent faster than the speed at which said first moveable blade is rotated.

36. The reactor as defined in claim 33 wherein said first and second moveable blades are rotated, said first moveable blade rotated in one direction and said second moveable blade rotated in the opposite direction.

37. The reactor as defined in claim 7 wherein said tank is open on one side and wherein the fluid surface is exposed to the open tank side.

38. The reactor as defined in claim 7 wherein the ratio of the area of the fluid surface to the volume of the slurry is in the range of between substantially 1:

12 inches to 1;

1 inches.