Delivery system for agricultural chemicals

• US 5,176,736 A
• Filed: 11/04/1991
• Issued: 01/05/1993
• Est. Priority Date: 12/11/1989
• Status: Expired due to Term

• Current Assignee: ISP Capital, Inc. (Ashland Global Holdings, Inc.)
• Original Assignee: ISP Investments, Inc. (Ashland Global Holdings, Inc.)
• Inventors: Dahanayake, Manilal, Narayanan, Kolazi S., Chaudhuri, Ratan K.
• Primary Examiner(s): Raymond, Richard L.
• Assistant Examiner(s): BEMBENICK, BRIAN
• Application Number:
  US07/787,013
• Time in Patent Office: 428 Days
• Field of Search: 71/86, 71/88, 71/92, 71/93, 71/94, 71/95, 71/96, 71/107, 71/100, 71/105, 71/113, 71/114, 71/119, 71/118, 71/121, 71/DIG. 1, 71/117, 71/79
• US Class Current: 504/365
• CPC Class Codes: A01N 25/02 containing liquids as carriers, diluents or solvents
• CPC Class Codes: B65H 2557/242 involving a particular data profile or curve

Abstract

An emulsifiable concentrate comprising an agriculturally active chemical, a surfactant, an organic diluent and a solvent having first and second components, the first component being capable of solubilizing the agriculturally active chemical and the second component in conjunction with the surfactant being effective to disperse the agriculturally active chemical. The inventive concentrate allows for high concentrations of the active ingredient, exhibits excellent stability and produces highly stable compositions upon dilution with water.

Claims

1. A stable emulsifiable concentrate comprising an agriculturally active herbicide which is substantially insoluble in water, an organic diluent selected from the group consisting of soybean oil, rape seed oil, long-chain alcohols, long-chain ketones, long-chain esters, and ethers, and aromatic petroleum oils, a surfactant and a solvent composed of first and second components, said first component having a sufficiently high hydrophilic property and being present in an amount effective to solubilize the agriculturally active herbicide, and the second component being selected from the group consisting of octylpyrrolidone, dodecylpyrrolidone, N-2-ethylhexylpyrrolidone, and mixtures thereof, and being present in an amount, in conjunction with a surfactant, effective to disperse the agriculturally active herbicide.

2. The concentrate of claim 1 wherein the diluent is an aromatic petroleum oil comprising about 60% of heavy aromatic solvent naphtha and about 40% of middle distillate solvent extractant.

3. The concentrate of claim 1, wherein the agriculturally active chemical is a herbicide selected from the group consisting of phenoxy compounds, benzoic acid, acetic acid, phthalic acid, aniline derivatives, nitriles, amides, acetamides, anilides, carbamates, thiocarbamates, heterocyclic nitrogen derivatives, urea derivatives, and phosphates.

4. The concentrate of claim 1 wherein the amount of solvent is in the range from about 20 to 90%, and the amount of diluent is in the range from about 80 to 10%, each amount being based on the total weight of solvent and diluent in the concentrate.

5. The concentrate of claim 4 wherein the amount of the first component is from about 50 to 95% and the amount of the second component is from about 5 to 95% based on the weight of the solvent in the concentrate.

6. The concentrate of claim 5 wherein the amount of surfactant is from about 1 to 25% by weight based on the total weight of the concentrate.

7. The concentrate of claim 6 wherein the concentration of the herbicide is in excess of about 5 weight percent, based on the weight of the total concentrate.

8. The concentrate of claim 7 wherein the amount of the herbicide is from about 5% to 60% by weight based on the total weight of the concentrate.

9. A composition comprising the emulsifiable concentrate of claim 1 and water wherein the herbicide is present in an effective herbicidal amount.

10. A method for treatment of plants comprising applying to said plant or the soil surrounding said plant the composition of claim 9.